This document summarizes Alstom's circulating fluidized bed (CFB) technology for steam generation. CFB technology allows the combustion of a variety of fuels at lower temperatures, resulting in very low NOx and SO2 emissions without additional equipment. Alstom has three main CFB product types - single grate, cross pass, and dual grate arrangements - suitable for plant capacities from 50MW to over 400MW. Key design aspects include cyclone sizing and maintaining high bed density for effective heat transfer, desulfurization, and combustion.
This document summarizes Alstom's circulating fluidized bed (CFB) technology for steam generation. CFB technology allows the combustion of a variety of fuels at lower temperatures, resulting in very low NOx and SO2 emissions without additional equipment. Alstom has three main CFB product types - single grate, cross pass, and dual grate arrangements - suitable for plant capacities from 50MW to over 400MW. Key design aspects include cyclone sizing and maintaining high bed density for effective heat transfer, desulfurization, and combustion.
This document summarizes Alstom's circulating fluidized bed (CFB) technology for steam generation. CFB technology allows the combustion of a variety of fuels at lower temperatures, resulting in very low NOx and SO2 emissions without additional equipment. Alstom has three main CFB product types - single grate, cross pass, and dual grate arrangements - suitable for plant capacities from 50MW to over 400MW. Key design aspects include cyclone sizing and maintaining high bed density for effective heat transfer, desulfurization, and combustion.
This document summarizes Alstom's circulating fluidized bed (CFB) technology for steam generation. CFB technology allows the combustion of a variety of fuels at lower temperatures, resulting in very low NOx and SO2 emissions without additional equipment. Alstom has three main CFB product types - single grate, cross pass, and dual grate arrangements - suitable for plant capacities from 50MW to over 400MW. Key design aspects include cyclone sizing and maintaining high bed density for effective heat transfer, desulfurization, and combustion.
ALSTOM Power INTRODUCTION Steam generators with circulating fluidised bed combustion (CFB) have been utilized throughout the world over the last few years, in particular for the power generation, but also as industrial power plant and combined heat and power station. The reason for their success was on the one hand that they could meet the considerably stricter anti-pollution legislation even without additional add-on equipment, and on the other hand that fluidised bed combustion plants allow the use of a broad fuel range, which meanwhile also comprises various sludges and production residues besides different types of coal and biomasses. Today, more than 900 CFB steam generators are in operation or under construction for the capacity range from 50 up to over 400 MW el . Parallel to the capacity increase of CFB steam generator size the efficiency and the availability of conventional pulverised coal (PC) fired steam generators was further increased. Whereas the improvement of the efficiency of PC technology is mainly associated with the increase of the steam parameters, the availability was improved on account of the operating experience gathered from once- through steam generators according to the sliding pressure principle. CFB technology may directly benefit from these developments both in view of the application of materials for steam parameters of up to 270 bar and 600/620 C for the superheater and reheater outlet and for the design of a CFB steam generator according to the once-through technology. With CFB plants the nowadays usually demanded limit values for NO X and SO 2 are obtained without any complex supplementary equipment because of the low combustion temperature of approx. 850 C with staged air supply, intensive mixing inside the furnace and the addition of additives to the furnace. The desulphurisation takes place by the natural retention of SO 2 in the lime contained in the fuel ash and through the injection of dried and treated limestone into the furnace. The particle size of the limestone, the controlled furnace temperature as well as the high cyclone removal efficiency are the most important factors ensuring an efficient desulphurisation in the furnace. Thus, usually up to 95 % of the SO 2 produced in the combustion process can be retained within moderate quantities of added limestone. The dimensioning and the geometry of the cyclone and the associated inlet duct are decisive factors in order to maintain the bed density in the furnace and the circulation of the small, lime-rich particles. A high bed density leads to a more intensified heat exchange and a homogeneous temperature distribution inside the furnace and enables the fuel particles to remain sufficiently long in the high temperature range. The greatest challenge for the increase of capacity to 400 up to 600 MW el is to apply the excellent operating experience gained from the CFB plants of capacity class 250 to 350 MW el to the larger plants and to accompany this capacity increase with the introduction of the supercritical technology. In the next sections Alstoms product portfolio and specific design features are presented and the required steps of design for a supercritical plant in the upper capacity range are discussed. ALSTOMS PRODUCT PORTFOLIO There are three main CFB product types within Alstoms portfolio. The application of each product type depends mainly on the capacity of the plant, but also on fuel, or operational requirements. Single grate, in line arrangement Figure 1 gives an overview of the arrangement. The CFB boiler comprises a single grate combustion chamber, which is fed from both front and rear walls with fuel, limestone and combustion air. The three major parts of the boiler combustion chamber, cyclone and second pass - are arranged in line. The combustion of the fuel and the primary desulphurisation of the flue gas takes place in the combustion chamber. In the lower part of the combustion chamber the bed is most dense, with its density decreasing with increasing height. Secondary air staging in order to keep the NO X emissions at low levels is typically applied. Flue gas carrying solids enters the cyclone, where the solids are separated and recirculated back to the furnace, while the flue gas enters the second pass, where the convective heating surfaces are arranged. The convective heating surfaces are followed by the air preheater. In Figure 1 a regenerative air preheater is shown; tubular air preheaters can also be applied. In the primary solids recirculation of the CFB boiler both internal within the furnace and external heat exchangers like fluidised bed heat exchangers (FBHE) can be included. In this arrangement the basic width of one combustion chamber cell can be multiplied in order to accommodate the arrangement of additional cyclones. This arrangement is suitable for capacities up to 350 MW el and Alstom has applied this arrangement with up to three cyclones. +55.4 m + 2.3 m
Figure 1: Single grate, in line arrangement Cross pass arrangement Figure 2 gives an overview of the arrangement. This arrangement represents a variant of the single grate, in line arrangement. The main distinguishing feature is the installation of part of the convective heating surfaces in a cross pass arranged on the top of the combustion chamber and after the cyclone. This allows a more compact design, while keeping all the features described above for the single grate, in line arrangement. This arrangement is suitable for capacities up to 150 MW el . +53.0 m 0.0 m
Figure 2: Cross pass arrangement Figure 4: Cyclone example Dual grate (pantleg) arrangement Figure 3 gives an overview of this arrangement, which is applied for capacities higher than 300 MW el . It comprises an even number of cyclones typically four, or six that are arranged on the furnace side walls. Compared with the arrangements in Figure 1 and 2 above not only the width, but also the length of one combustion chamber cell increases. In order to account for this and ensure a good mixing of the fuel, limestone and combustion air entering the lower part of the furnace, the latter is designed as a dual grate, allowing secondary air inlets at both sides of each leg. The flue gas leaving the cyclones is led through a common duct into the second pass, which is located behind the rear wall of the furnace.
Figure 3: Dual grate (pantleg) arrangement CFB DESIGN PRINCIPLES CFB references for the utilization of a big variety of fuels exist today. Coal and lignites with water content up to 60 %, ash content up to 40 % and sulphur up to 14 % (daf) have been utilized successfully. References exist also for the utilization of slurry, sewage sludge, petroleum coke and bark. Besides the ability to burn a wide range of fuels including difficult to burn fuels and opportunity fuels, CFBs have achieved impressive environmental performance, especially low NO X emissions and economic in-furnace desulfurization by limestone addition. The cyclone sizing and geometry, which includes the design of the inlet duct, is at the heart of Alstom CFB combustion technology: the capture efficiency of the separation system is the decisive factor in maintaining the bed density and retaining the fine calcium rich particles in the primary loop. A high bed density in turn ensures a high heat transfer and a uniform temperature in the furnace, a high contact between lime particles and SO 2 rich flue gas for optimum sulphur capture efficiency and of course the best possible combustion by keeping the fuel particles in the furnace for the longest possible time. It also has a beneficial impact on NO X emissions, due to the creation of isothermal conditions at the inlet of the primary loop. A lot of development effort is expended annually in order to continuously improve the cyclones separation efficiency and optimise its operational performance. Figure 4 gives an overview of the main feature of the Alstom cyclone. Such cyclones can be either refractory lined, or tubed and steam-cooled. The latter is advantageous, when targeting at supercritical conditions. While post-combustion control equipment can be used with CFB technology to meet special emissions requirements, the very low NO X emissions that CFB combustion achieves without any secondary measures can be attributed to the following reasons: relatively low and uniform furnace temperature of approx. 850 C to 900 C; air staging in the lower furnace by primary air and secondary air introduction at appropriate levels, resulting in substoichiometric combustion conditions in the lower furnace hopper; equal distribution of fuel and air by the intense mixing inside the furnace; positive impact of high efficiency cyclones that result in isothermal conditions in the primary loop. NO X emissions can be further reduced via Selective Non-Catalytic Reduction (SNCR) wherein an ammonia- based reagent is injected into the flue gas at the appropriate location(s). The ammonia converts NO X to elemental nitrogen and water. Such systems have achieved NO X reductions of over 50 %. Alstom has experience with all types of SNCR reagents; anhydrous ammonia, aqueous ammonia and urea. Sulphur capture is achieved through inherent capture by the fuel bound lime and injection of prepared and dried limestone in the furnace. The crushed limestone is pneumatically fed into the CFB through adequate injection points. The particles size distribution (PSD) is an important factor in the sulphur capture process efficiency, together with carefully controlled temperature and high cyclone efficiency. When equipped with high efficiency cyclones, CFB boilers are typically able to capture up to 95 % of the SO 2 generated by the combustion of the fuel at moderate limestone addition rates. To simplify the process of preparing limestone for injection, Alstom developed and patented the Just-In- Time (JIT) limestone feed system. This system consists of a day silo containing raw limestone, a feeder, an air-wept crusher/dryer and piping to convey the sized and dried limestone directly to the furnace. Heat for drying is provided by hot air from the air preheater. The JIT systems is shown schematically in Figure 5. ROLLER MILL LIMESTONE SILO GRAVIMETRIC FEEDER SLIDE GATE HOT PA AIR TEMPERING AIR R A W
L I M E S T O N E FURNACE ISOLATION VALVE TO FUEL FEED
Figure 5: JIT System The heart of the JIT systems is the roller mill, which is an Alstom-supplied roller mill. Alstom has experience with the JIT system incorporating roller mills of CFBs up to 300 MW el capacity. TC ESP or bag filter Ash Recirculation Mixer Water Sorbent End product
Figure 6: NID Process Diagram In order to achieve lower SO 2 values for high sulphur fuels, the NID process [1] shown in Figure 6 (also known as FDA in the US) can be applied, which is based on the absorption of SO 2 by the available lime in the flyash. The key parameter to be controlled in any dry FGD process is the humidity of the flue gas in the reaction zone, i. e. the reactor and the subsequent dust collector. At a relative humidity of 40 50 %; the lime is activated and readily absorbs SO 2 . Water is added by moistening the ash, which is being recirculated from a dust collector. The water is distributed onto the surface of dust particles in a mixer, resulting in a water content of only a few percent. The recycle ash behaves like a dry powder and is still free flowing. Due to the high surface area available for the water, the added water flashes off immediately, once the moistened dust is brought into contact with the flue gas. This in turn results in a very small reactor size. A unique feature of the NID technology is the fact that all recycled absorbent is subject to wetting in the mixer which maximizes the utilization of the recycled absorbent. After the activation/drying step, the dried recycle dust is separated from the flue gas in a highly efficient dust collector. For a better utilisation of the heat release in the primary loop and for a more economic arrangement the CFB process offers the possibility to install additional heating surfaces in the primary loop, either as in furnace surfaces, or as external fluidised bed heat exchangers. Figure 7 shows an example of an in-furnace heating surface arranged as an omega panel and bringing the finishing superheat duty and Figure 8 shows an example of in-furnace surface arranged as a wingwall. On the other hand, when utilising more than two external heat exchangers additional possibility to control the furnace temperature is given, as well to control without reheat spray the finishing reheater temperature.
Figure 7: Omega Panels
Figure 8: Wingwall FURTHER SCALE-UP AND SUPERCRITICAL DESIGN Whereas most of the CFB plants in operation are designed as natural circulation or forced circulation plants, there is a great number of PC firing plants which are designed as once-through plants. Table 1 shows an extract from some Alstom references, which are designed for high steam parameters according to the once- through principle. The experience gained from the design and operation of these plants can be completely transferred to the CFB plants.
Table 1 Pulverised fuel firing plants according to the once-through principle Plant Start-up Fuel Capacity
[MW] Steam mass flow [t/h] Design pressure [bar] Temperature SH/RH steam [C] Bechatw 2008 Lignite 833 2,424 284 554/582 Neurath F/G 2008 Lignite 1,122 2,959 295 600/605 Ptnw 2004 Lignite 460 1,345 290 544/568 Wai Gao Qiao, II 2003 Bituminous coal 2 x 900 (980) 2,789 279 542/568 Yonghung 2003 Bituminous coal 2 x 800 2,415 271 569/569 Niederaussem K 2002 Lignite 1,012 2,662 290 580/600 Florina 2002 Lignite 330 1,017 262 543/542 Mai Liao 2000 Bituminous coal 2 x 600 1,950 279 540/569 Schwarze Pumpe 1997 Lignite 2 x 800 2,420 285 547/565 Poryong 3 & 4 1993 Bituminous coal 2 x 500 1,720 265 541/541 Vestkraft, Unit 3 1992 Bituminous coal 400 1,080 276 560/560 Shidongkou II 1992 Bituminous coal 2 x 600 1,897 268 541/569 GKM Mannheim, 18 1982 Bituminous coal 475 1,370 275 530/540/530 Scholven, Unit F 1979 Bituminous coal 4 x 750 2,200 230 535/535
The two most important considerations for the design of the evaporator of a once-through steam generator are: a sufficient cooling of the evaporator tubes in any operating condition and the reduction of the temperature differences between the evaporator tubes to a minimum. The temperature differences at the evaporator outlet are the result of a non-uniform heat absorption of the evaporator tubes and the differences in length and pressure loss. Whereas the water mass flow in natural circulation steam generators is slightly increased in case of a load reduction, the mass flow with once- through steam generators is linearly dependent on the load. Therefore, a detailed analysis is to be performed in such systems for cooling the evaporator tubes over the entire load range as well as for the determination of the minimum once-through load. Then, the tube dimensions are to be selected accordingly. Tube diameters from 51 mm to 63.5 mm just as for natural circulation boilers do not lead to suitable mass flow densities for once-through systems. Whereas the mass flow density required for cooling is ensured for PC plants by means of the spiral-tubed evaporator wall, this alternative cannot be adapted for CFB plants owing to potential problems of erosion of the enclosing walls. The enclosing wall is vertically tubed. A possibility of avoiding high metal temperatures is the installation of internally finned tubes instead of plain tubes. In principle, the dryout point is shifted towards higher steam contents due to the interior finning, thus improving the cooling of the tubes in the area of the high heat flux densities. Detailed heat transfer calculations have shown, however, that the interior finning hardly involves any advantages for CFB plants. As the highest heat flow density for fluidised bed combustion plants is lower than for PC plants and occurs inside the furnace at low levels, hardly any differences in cooling can be discovered between internally finned tubes and plain tubes. In addition, the heat transfer to the enclosing walls of CFB plants is not influenced by slagging and fouling. The evaporator walls remain clean, on the one hand owing to the low furnace temperatures lower than the ash softening point and due to the cleaning effect of an ash layer moving downwards along the wall. This leads to a more homogeneous heat absorption of the evaporator walls in comparison with PC plants. Therefore, a lower mass flow density of the evaporator walls is also sufficient for cooling. The height of the furnace is only insignificantly increased with the capacity of the plant. It may occur in the upper capacity range that the enclosing walls alone cannot offer a sufficient evaporator heating surface. The necessary additional heating surface can be arranged either parallel to the enclosing wall in the furnace or in series in a fluidised bed heat exchanger. In the latter case, attention should be paid to the distribution of the water/steam mixture. [2] SUMMARY The fluidised bed technology can contribute towards an efficient, environmentally compatible and economic electrification using coal and other fuels. Alstoms recent projects have demonstrated important benefits of the CFB technology. These benefits include: Achieving over 95 % availability during commercial operation Achieving 95 % desulphurisation with in-furnace desulphurisation only or > 98 % desulphurisation with combination of in-furnace desulphurisation and secondary measures No addition of sorbents for secondary measures in case of NID process A significant contribution to the good desulphurisation is the high efficiency of the cyclone separators. Alstom has continuously optimised separator design and improved the limestone utilization. A second milestone is the combination with the NID process with allows to achieve highest desulphurisation rates with limestone quantities which are close to the limestone consumption of wet FGD plants. The success of the CFB technology in countries with a high share of coal in the electricity generation underlines the high market potential of CFB plants. In recent years, the fluidised bed plant has become established in the capacity range from 250 to 350 MW el . A further capacity increase up to 600 MW el is possible and remains to be realized. The introduction of supercritical parameters even further improves the economic efficiency and additionally allows the reduction of CO 2 emissions. In this connection, the fluidised bed technology takes advantage of the design and operating experience of PC plants. Particularly in the area of the materials and once-through technology the experience from PC plants can be directly applied to the fluidised bed. REFERENCES [1] Gabriel, C.; Seeber, J.; Ahman, S.; Seluk, N.: Operational Experience with High Sulphur Fuels in Combination with CFB and Secondary Desulphurisation Measures. VGB CFB Workshop, September 2004, Germany [2] Stamatelopoulos, G.-N.; Seeber, J.; Semedard, J.-C.; Skowyra, R. S.: Advancement in CFB Technology: A Combination of Excellent Environmental Performance and High Efficiency. Power-Gen Europe 2004, 25. - 27. May 2004, Barcelona, Spain