The Feasibility Study of Using Oyster Shells As Substitute in Manufacturing Bricks
The Feasibility Study of Using Oyster Shells As Substitute in Manufacturing Bricks
The Feasibility Study of Using Oyster Shells As Substitute in Manufacturing Bricks
COLLEGE OF ENGINEERING
In Partial Fulfillment
Of the Requirements for Technical Communication
S.Y. 2016-2017
______________
By
Baylon, Jonalyn
Cala-or, Earlwin Jay
Figurasin, Jonesse Aerish
Garado, Lyra Kayle
Hamor, Venus Nicole
Jimenez, Joyce
Leuterio, Carleth Ann
Malicay, Kimberly
Rubante, Shaira
Silvestre, Patricia
Ting, Lalaine
Zacarias, Dimple Mae
BSIE 2-FS1N
1|Page
EXECUTIVE SUMMARY
In this line, we propose to use oysters and plastics as substitute to sand in making
concrete blocks to help our environment as well as our co-Filiipinos. We will recycle the waste
materials of many people. The concrete blocks that are made up from waste materials like plastic
bottles and oyster shells will not lessen the strength of the concrete blocks but probably adds
strength on it by the mineral compounds of oyster shells. In some study, it proves that nothing
will change if pulverized plastic bottles is often used with metal rods as a componentin making
construction materials.
Using oyster shell and plastic as substitutes sand in manufacturing bricks is the main
purpose of this study. The alternative in brick making is considered a solution to the increasing
prices of construction materials. This approach will lessen the problem in garbage disposal for
discarded oyster shells and non-biodegradable plastic waste. Furthermore, it promotes the use of
both waste and native materials in making cement blocks, which is low cost, compared to
When used as a cement replacement, the chemical compositionof burnt oyster shells
contains both calcium carbonate and calcium hydroxide compared to lime which are both highly
Therefore, oyster shells and plastics have comparably lower price comparedto sand or
other brick making product. Thus making it more economically and environmentally efficient as
2|Page
POLYTECHNIC UNIVERSITY OF THE PHILIPPINES
TABLE OF CONTENTS
TITLE PAGE 1
EXECUTIVE SUMMARY 2
TABLE OF CONTENTS 3
MAIN REPORT
INTRODUCTION 5
3|Page
OYSTER SHELL 15
PLASTIC 20
FINANCIAL FEASIBILITY 25
I. Cost Estimate 25
I. a. Sand 25
I. b. Oyster Shell 25
I. c. Plastic 25
II. Cost Comparison 26
CONCLUSION 27
4|Page
INTRODUCTION
demand. Many cement factories all over the world now use expensive and non-renewable
materials in making blocks. This makes the product costly. Through this project, an alternative
ingredient in making blocks will be justified together with finding ways on reusing oyster shells
and plastic through block making. This project could help lessen the problem in garbage disposal
for both discarded oyster shells and non-biodegradable plastic waste. Furthermore, it promotes
the use of native materials in making cement blocks which is cheaper, compared to synthetic or
The use of oyster shells and plastics as substitutes of sand in manufacturing bricks is the
main purpose of the feasibility study. Cement is the main ingredient in making bricks because of
its durability and hardness. But as the demand of cement increases, the price also increases. For
this reason, the group came up with the idea of using oyster shell and plastic as the aggregating
5|Page
The use of recycled materials is a trend right now, but using them as an aggregate in
making blocks is unique. The group came up with the idea of using oyster shells and plastic
wastes as substitutes and creating more sensible products. By mixing together ground-up plastics
and shells with soil, anyone can create a material just as strong as conventional concrete.
The use of shells (from oysters) from bivalve mollusks as both aggregate and
cementations substitute in Portland Cement has been investigated around the globe due to the
variety of shell wastes that can be utilized around coastal areas; oyster shell production in the
The chemical composition of burnt oyster shell contains similar calcium carbonate and
calcium hydroxide phases as compared to lime. Calcium carbonate does not take part in the
hydration process of cement to form structural components; calcination of oyster shells to drive
off the carbon reduces CaCO 3 to CaO which is preferential for the reaction of cementitious
Making a structure out of bottles reduces construction and material cost by 30%
compared to traditional building, and given that in Taiwan construction and materials account for
60% of a building’s cost, that means real savings (Reyes et al., 2012.) This means that using
recycled materials can really make the expense of the manufacturing bricks company lower as
possible.
The goal of this research is to find alternative ingredients in making construction blocks
that will be much cheaper than the usual synthetic and chemically manufactured materials. The
6|Page
properties of the block should also be of equal or greater capacities compared to commercially
The term brick refers to small units of building material, often made from fired clay and
secured with mortar, a bonding agent comprising of cement, sand, and water. Long a popular
material, brick retains heat, with-stands corrosion, and resists fire. Because each unit is small—
usually four inches wide and twice as long, brick is an ideal material for structures in confined
spaces, as well as for curved designs. Moreover, with minimal upkeep, brick buildings generally
For the above-cited practical reasons and because it is also an aesthetically pleasing
medium, brick has been used as a building material for at least 5,000 years. The first brick was
probably made in the Middle East, between the Tigris and Euphrates rivers in what is now Iraq.
Lacking the stone their contemporaries in other regions used for permanent structures, early
builders here relied on the abundant natural materials to make their sun-baked bricks. These,
however, were of limited use because they lacked durability and could not be used outdoors;
exposure to the elements caused them to disintegrate. The Babylonians, who later dominated
Mesopotamia, were the first to fire bricks, from which many of their tower-temples were
constructed.
7|Page
From the Middle East the art of brick making spread west to what is now Egypt and east
to Persia and India. Although the Greeks, having a plentiful supply of stone, did not use much
brick, evidence of brick kilns and structures remains throughout the Roman Empire. However,
with the decline and fall of Rome, brick making in Europe soon diminished. It did not resume
until the 1200s, when the Dutch made bricks that they seem to have exported to England. In the
Americas, people began to use brick during the sixteenth century. It was the Dutch, however,
Prior to the mid-1800s, people made bricks in small batches, relying on relatively
inefficient firing methods. One of the most widely used was an open clamp, in which bricks were
placed on a fire beneath a layer of dirt and used bricks. As the fire died down over the course of
several weeks, the bricks fired. Such methods gradually became obsolete after 1865, when the
Hoffmann kiln was invented in Germany. Better suited to the manufacture of large numbers of
bricks, this kiln contained a series of compartments through which stacked bricks were
Brick making improvements have continued into the twentieth century. Improvements
include rendering brick shape absolutely uniform, lessening weight, and speeding up the firing
process. For example, modern bricks are seldom solid. Some are pressed into shape, which
leaves a frog, or depression, on their top surface. Others are extruded with holes that will later
expedite the firing process by exposing a larger amount of surface area to heat. Both techniques
However, while the production process has definitely improved, the market for brick has
not. Brick does have the largest share of the opaque materials market for commercial building,
8|Page
and it continues to be used as a siding material in the housing industry. However, other siding
materials such as wood, stucco, aluminum, plaster, and vinyl are strong competitors because they
cost up to 50 percent less, and some (notably stucco and plaster) offer built-in insulation. Yet
these systems can cost up to 1.75 times that of brick, which also requires less maintenance. Other
materials that compete with brick despite their usually higher cost include precast concrete
panels, glass, stone, artificial stone, concrete masonry, and combinations of these materials,
because advances in manufacturing and design have made such materials more attractive to the
builder. According to the U.S. Industrial Outlook, the use of brick as a siding material for single-
(http://www.madehow.com/Volume-1/Brick.html#ixzz4JdNrNJfr)
As the world become modernized, different kinds of concrete blocks come out in the
market based on its composition. There are various types of concrete blocks such as Standard
concrete masonry unit (CMU), Split faced-block, Scored block, ribbed block, Honed block,
Glazed block, and Offset block. Standard Concrete Masonry unit (CMU) is the basic concrete
block used for masonry construction. This block is designed for use in structural areas that are
commonly unseen and it is the reason that they are made with plain faces. Split faced block is
used similarly to standard concrete block but the only difference is the natural stone –like
structure and appearance of the split face. It is popular block use on exterior walls as it is
aesthetically pleasing, and does not need further veneers. The scored block is made with one or
more vertical scores on its face to give the appearance of multiple mortar joints. It is similar to
ribbed blocks as both of them have vertical features. Glazed block are made with permanent
colored face, creating an appearance similar to that of a ceramic tile finish. Honed block are
9|Page
polished to create a smooth finish that can resemble polished stone. Last is the Offset block, this
kind of block creates a highly textured wall rich with different patterns of light and shadow.
In addition, different manufacturers making different kinds of concrete blocks are almost
made up of chemical materials. Various chemicals are added like sodium chloride (salt) to make
the concrete blocks dry faster or sucrose (sugar) to make it dry more slowly than normal.
Pigments may also be added to give it color. These blocks that uses some chemicals like the
magnesium, iron oxide and so many more sometimes can cause pollution and disadvantages
when overused. These thoughts became the basis of the researchers to use plastics that are non –
biodegradable materials to test its ability to replace those chemicals and make use of it.
Concrete blocks made up from chemicals also have disadvantages. These disadvantages
include the following: chemical concrete blocks are expensive, because materials needed are
highly demand like sand, cement and bricks, they are also difficult to insulate, and lastly it may
II. Materials
Natural clay minerals, including kaolin and shale, make up the main body of brick. Small
amounts of manganese, barium, and other additives are blended with the clay to produce
different shades, and barium carbonate is used to improve brick's chemical resistance to the
elements. Many other additives have been used in brick, including byproducts from
papermaking, ammonium compounds, wetting agents, flocculents (which cause particles to form
loose clusters) and deflocculates (which disperse such clusters). Some clays require the addition
10 | P a g e
A wide variety of coating materials and methods are used to produce brick of a certain
color or surface texture. To create a typical coating, sand (the main component) is mechanically
mixed with some type of colorant. Sometimes a flux or frit (a glass containing colorants) is
added to produce surface textures. The flux lowers the melting temperature of the sand so it can
bond to the brick surface. Other materials including graded fired and unfired brick, nepheline
(http://www.madehow.com/Volume-1/Brick.html#ixzz4JdwaqKHX)
III. Sand
the decomposition of rocks. Sand particles consist of small grains of silica (SiO2). It forms a
It is defined by size, being finer than gravel and coarser than silt. Sand can also refer to
a textural class of soil or soil type; i.e. a soil containing more than 85% sand-sized particles by
mass. The composition of sand varies, depending on the local rock sources and conditions, but
the most common constituent of sand in inland continental settings and non-
tropical coastal settings is silica (silicon dioxide, or SiO2), usually in the form of quartz. The
second most common type of sand is calcium carbonate, for example aragonite, which has
mostly been created, over the past half billion years, by various forms of life,
like coral and shellfish. For example it is the primary form of sand apparent in areas where reefs
have dominated the ecosystem for millions of years like the Caribbean.
(https://en.wikipedia.org/wiki/Sand)
IV. Properties
11 | P a g e
IV. a. Strength
In the use of concrete blocks for the walls of buildings, the stress to which they
concrete does not differ greatly from ordinary building stone. It is difficult to find reliable
records of tests of sand and gravel concrete, 1 to 4 and 1 to 5, such as is used in making
blocks; the following figures show strength of concrete of approximately this richness,
also the average of several samples each of well-known building stones, as stated by the
authorities named:
Actual tests of compression strength of hollow concrete blocks are difficult to make, because it is
impossible to apply the load uniformly over the whole surface, and also because a block 16
inches long and 8 inches wide will bear a load of 150,000 to 200,000 pounds, or more than the
capacity of any but the largest testing machines. Three one-quarter blocks, 8 inches long, 8
inches wide, and 9 inches high, with hollow space equal to one-third of the surface, tested at the
Case School of Science, showed strengths of 1,805, 2,000, and 1,530 pounds per square inch,
12 | P a g e
Blocks with openings equal to only one-third the surface, as required in many city
regulations, are heavy to handle, especially for walls 12 inches and more in thickness,
and, as the above figures show, are enormously stronger than there is any need of. Blocks
with openings of 50 per cent would be far more acceptable to the building trade, and if
used in walls not over 44 feet high, with floors and roof calculated as above for 25 feet
span, would be loaded only to 56 pounds per square inch of actual surface. This would
give a factor of safety of 18, assuming minimum compression strength of 1,000 pounds.
IV.b. Flexurity
resist deformation under load. Design of concrete hollow block masonry subjected to
respect to bed joints, either normal or parallel to the bed joints, depending upon the
direction in which the wall spans. There are wide variations between code provisions and
many parameters have not been accounted for adequately, revealing the need for
systematic investigation. As a first step, tests for flexural strength normal to bed joints of
concrete hollow block masonry prisms in running bond have been carried out. The
influences of full mortar bedding using conventional mortar mixes, the influence of
plastering and grouting were investigated by using a bond wrench apparatus. Results
show that the flexural bond strength increases with the richness of the bedding mortar
mix proportion adopted, and observed to be higher than those specified by IS 1905. The
plastering and grouting have significant effect in contributing to the flexural strength of
masonry, and hence, these aspects need to be included in the design provisions.
13 | P a g e
IV. c. Porosity
Porosity is a measure of how much of a rock is open space. This space can be
between grains or within cracks or cavities of the rock. Consolidated rocks (e.g.
sandstone, shale, granite or limestone) potentially have more complex "dual" porosities,
as compared with alluvial sediment. This can be split into connected and unconnected
porosity. Connected porosity is more easily measured through the volume of gas or liquid
that can flow into the rock, whereas fluids cannot access unconnected pores.
history and composition. Porosity is not controlled by grain size, as the volume of
between-grain space is related only to the method of grain packing. Blocks normally
decrease in porosity with age and depth of burial. Tertiary age Gulf Coast sandstones are
in general more porous than Cambrian age sandstones. There are exceptions to this rule,
usually because of the depth of burial and thermal history. The porosity of blocks, and
their permeability and absorption are very important factors in influencing properties of
bricks such as the bond between them and mortar, the resistance of blocks to freezing and
thawing, and their chemical stability. This paper suggests new tests for calculating the
porosity and water absorption values of clay bricks, which involve the testing of 20-mm
V. Cost
Concrete blocks are an affordable building material that can be used for a number of
construction projects, and are suited very well for construction walls for foundations or utility
buildings. Concrete blocks typically have holes in the center to reduce the weight, material
14 | P a g e
needed, and cost. The average concrete block is composed of cement and coal ash, which is why
they are often called cinder blocks. Concrete blocks are actually concrete masonry units, or
OYSTER SHELL
Being an island, Taiwan is very rich in marine resources. Along the west coast of Taiwan,
oyster farming is one of the most important production activities for the country’s economy. In
general, most of the oyster shells are discarded with no further use once the flesh is stripped off;
except that a small amount is used for art creation [1, 2]. As a result, oyster shell piles are
common in areas of oyster production with no further utilization. Chemical and microstructure
analyses reveal that oyster shells are predominantly composed of CaO [3, 4], similar to that of
lime, which has been used for soil stabilization [5]. In addition, oyster shells can be utilized for
producing medium- and high-quality cement [6]. The expandable nature of clay is reduced by the
ion exchange from the interaction between calcium ions and clay. Quicklime creates coagulation
if added with water. Thus, calcium ions are used generally as the primary component in the clay
stabilization. There is no known chemical reaction between soil and lime except the ion
exchange. In other studies for potential use, the shells are mostly used as additive or replacement
of part of the cement in concrete. For example, construction material mixed with crushed oyster
shell and sand was used for sand compaction piles to improve soft soils underneath a breakwater
port in Japan [7]. However, the lime contained in the shells does not provide improvement of
15 | P a g e
concrete strength as the Pozzolanic products of concrete already contain lime, and therefore no
positive effect is detected for concrete strength. According to [8], a pozzolan is defined as a
siliceous and aluminous material, which in itself possesses little or no cementitious value but
will, in finely divided form in the presence of moisture, chemically react with calcium hydroxide
No concrete strength increase was found by adding sintered and pulverized oyster shells
to concrete [9]. As a result, the use of pulverized oyster shells as concrete additive or cement
replacement often needs to be combined with other bonding materials, such as fly ash or slag [8].
Only the Pozzolanic reaction between SiO2 in the fly ash or slag and CaO in the pulverized
oyster shells, along with the addition of water reducer or super plasticizer, can improve the
research for other alternatives to meet future demands. Our research involves two major parts:
first, the Pozzolanic reaction between F-type fly ash and the pulverized oyster shell and secondly,
the improvement of soil strength, if the combination of pulverized oyster shells, clay, and sand
can effectively improve the physical properties of soil such as strength [5, 6]. However, most of
soil stabilization is done by in situ mixing, paving, and compacting. It is unlikely to obtain good
control as it does in concrete mixing. (Copyright © 2013 Chou-Fu Liang and Hung-Yu Wang,
Creative Commons Attribution License, Received 9 November 2012; Revised 27 February 2013;
16 | P a g e
II. Properties
Physical properties such as texture, porosity, specific surface, and apparent density are
different even in an oyster-shell. To reduce the variability, oyster-shells are crushed into small
Shows the physica lproperties of oyster-shell powders with a mean diameter of 1.65
mm.Microstructure of oyster-shell can be divided into twoparts, sheet phase layer and porous
bulky layer. Sheetphase layer is oriented to the growth direction of oystershell and porous bulky
The abrasiveness test showed that the commercial CaCO3, mussel and oyster shells were
32, 28, 32 g.cm–2 respectively, showing no significant variation in this property under the
conditions tested.
The objective of this paper is to demonstrate that oyster shells can be reused as
construction materials, based on their chemical and mechanical properties. Analyses for
investigate whether materials like oyster-shells are adequate for calcareous raw materials. As for
mechanical properties, uniformly crushed oyster-shells are blended with cement and sand to
make soil mortar specimens. Compressive strength characteristics of the soil mortar specimens
are examined in terms of varying blending ratio of sand and oyster-shell dosage to suggest a
critical dosage of oyster-shell where the compressive strength of mortar mixture soil is
The MEV photomicrographs for commercial CaCO3, mussel and oyster shell are shown
17 | P a g e
in Figure 2. It is observed that both the oyster and mussel shells (Figure 2a,b, respectively)
contain higher concentration of fine particles and there is also some presence of larger particles
which lead to more heterogeneous distribution compared to the commercial CaCO3 (Figure 2c).
These results are also being observed in particle size distribution curves of Figure 1. The shape
of the oyster and mussel shells particles is more irregular than commercial CaCO3.
Oyster shell is chemically consist of 95% calcium carbonate,3.5% silicate and a trace of
other elements like aspartic Acid, Glycine, Calcium Phosphate, Zinc, Manganese, Aluminum etc.
Chemical and microstructure analyses showed that oyster-shells are predominantly composed of
Compressive strength tests for soil mortar specimens with varying blending ratio of cement,
water, sand, and oyster-shell were compared with normal cement mortar. There was no
sand. The experimental results demonstrate that oyster-shells can be resources ofpure calcareous
III. Limitation
The mussel and oyster shells are discarded into the environment. The improper disposal
of solid waste from shellfish cultivation decreases water oxygen and microalgae that are
responsible for the nutrition of mussels and oysters, thus hindering the growth of these shellfish.
Concern about the destination of oyster and mussel waste is not only observed in Brazil.
In Korea, for example about 300,000 t of oyster shells are generated annually. The Korean
18 | P a g e
government, concerned with public health, financed a project to increase recycling of this waste,
because if this waste has been left untreated for a long time, it can be a source of nasty smell as a
consequence of the decay of flesh remnants attached to the oyster or the microbial decomposition
However, the efficiency of waste disposal compared to a large expenditure on the plant
construction comes into question so that it is an urgent need to seek for another
methodeliminating massive oyster-shell waste (Yoon et al., 2001; Yoon and Kim, 2001).
19 | P a g e
PLASTIC
In developing nations like the Philippines, the population increases the garbage and wastes. The
programs led by the government and different organizations to ease the dilemma, the problem
Plastic is the primary cause of the garbage congestion in the country. Although using
plastic is now part of the modern life, people don’t realize the harm it does to the environment
and how it negatively affects the human health. Because plastics never break down, some
A researcher named Peter Lewis created an innovative machine that transforms discarded
plastic bottles and bags into building blocks. The rock-hard bricks could be used for garden
retaining, landscaping walls, and other interesting uses such as shock absorbers behind crash
barriers. The researchers came up with the idea to use waste materials in making concrete blocks
II. Properties
Plastic is innovative and adaptable. It provides solutions to design problems. Also, plastic
20 | P a g e
would not be possible without plastic. Plastic can take on many shapes. Its applications are
nearly infinite. To make plastics with specific applications, additives are used such as pigments,
impact modifiers, antistatic agents, etc. Because of its characteristics, plastic has allowed
innovation that improves existing products and creates new ones that optimize the quality of life
Plastics are synthetic organic high polymers. It is important to know the general properties
of plastics to make use of this an engineering material. It must be noted that each plastic material
has its own peculiar properties to suit the various uses. Hence, the success of plastic as an
engineering material for a particular purpose depends upon the correct choice of the variety.
II.a. Strength
Plastics are sufficiently strong and can be used for load bearing
Most plastic products are prepared from phenolic resins which are only
ultraviolet light.
21 | P a g e
II.d. Chemical Resistance
III. Limitation
Today, one can hardly look around and not spot an item that is made entirely of plastic or
has plastic ingredient. This only proves that from its inception up to now, plastic has managed to
become a popular building material of millions of useful items. Still, plastic has several
disadvantages that prevent it from becoming a universal building block of modern human
civilization. Because of that, the government strictly controls its use and creates laws that govern
III.a. Durability
Plastic is light, moldable, sturdy, and can have countless forms, but
nature is able to degrade it (some degrade into basic ingredients and some
22 | P a g e
only divide into very small pieces). This troublesome ability of plastic
continuous dumping into seas and land will eventually create problems for
future generations. Even with all this durability, plastic products are not
everything we need.
the world with waste plastic product that can cause big effects on our
can happen waste plastic will continue to clog our waterways, oceans,
forests, and other natural habitats that are filled with animals who mistake
dangerous plastic for food. Chemical dangers are also high, because both
Not only that creation and recycling of plastic can cause serious
environmental risk, but some of the additives that are infused in plastic
phthalates and BPA are widely used as an additive that prevents degrading
of plastic structure, but they also interfere with our natural hormone levels
23 | P a g e
which can cause serious problems to both male and female (lower
Plastic is one of the most popular building materials for small items.
This is most evident in toy industry, where vast majority of children toys is
manufactured with plastic. These toys and small plastic objects of many uses can
easily get into children’s hands (especially babies and toddlers) that
to clearly label their plastic products and warn users of the possible chocking
potential. Another problematic plastic product that can cause serious injuries or
death are plastic bags (grocery or trash bags)who can sometimes end up wrapped
24 | P a g e
FINANCIAL FEASIBILITY
I. a. Sand
A sack of sand costs estimate 350-800 Php, depending on the properties it possesses. The
price may differ in stores but haggling could further decrease the price. Sometimes being too
parsimonious have its downsides like buying the cheapest kind just because of how low the price
is. The average price of a sack of sand is 500php. This kind already has the properties needed to
make bricks.
I. b. Oyster Shell
A kilogram of oyster shell costs 15Php. The price is a lot cheaper than buying a sack of
sand and it has some of the properties present in sand. The price is low because the consumers of
oysters usually treat the shells as trash. Even though these shells are considered as waste, you can
I. c. Plastic
A kilogram of plastic costs 18Php. The oyster shells and plastics in any form are also
treated as garbage after some time. This causes its cheap price. Also, plastic has a disadvantage
25 | P a g e
speaking, plastic could harm our ecosystem in a superlative way. But this project will utilize this
As clearly stated on the cost estimates, oyster shells and plastics have lower
prices than sand. With this in mind, it would be more economical to use oyster shells and plastic
26 | P a g e
CONCLUSION
The use of oyster shell and plastic as substitutes of sand in manufacturing bricks is the
main purpose of this study. This alternative in brick making is considered a solution to the
increasing prices of construction materials. Also, it lessens the problem in garbage disposal for
discarded oyster shells and non-biodegradable plastic waste. Furthermore, it promotes the use of
native materials in making cement blocks, which is low cost,compared to synthetic or chemically
manufactured ingredients.
When used as a cement replacement, the chemical composition of burnt oyster shell
contains similar calcium carbonate and calcium hydroxide phases as compared to lime. Calcium
carbonate does not take part in the hydration process of cement to form structural components;
calcination of oyster shells to drive off the carbon reduces CaCO 3 to CaO which is preferential
As clearly stated on the cost estimates, oyster shells and plastic have lower prices than
sand. With this in mind, it would be more economical and environmental to use oyster shells and
27 | P a g e