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APPLYING INTERNAL CIRCULATION ANAEROBIC REACTOR FOR

WASTEWATER TREATMENT: A CASE STUDY IN SAIGON PAPER MILL
WASTEWATER TREATMENT PLANT

Article · January 2019

DOI: 10.21307/ACEE-2019-045

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A R C H I T E C T U R E C I V I L E N G I N E E R I N G E N V I R O N M E N T
T h e S i l e s i a n U n i v e r s i t y o f Te c h n o l o g y N o. 3 / 2 0 1 9

doi: 10.21307/ACEE-2019-045

APPLYING INTERNAL CIRCULATION ANAEROBIC REACTOR

FOR WASTEWATER TREATMENT: A CASE STUDY IN SAIGON
PAPER MILL WASTEWATER TREATMENT PLANT

Nhat-Ha TRAN a and Manh-Ha BUI b*

a BSc; Department of Environmental Sciences, Saigon University, 273 An Duong Vuong Street, District 5,
Ho Chi Minh City 700000, Vietnam
b PhD; Department of Environmental Sciences, Saigon University, 273 An Duong Vuong Street, District 5,
Ho Chi Minh City 700000, Vietnam
*E-mail address: manhhakg@sgu.edu.vn

Received: 24.06.2019; Revised: 8.07.2019; Accepted: 8.07.2019

Abstract
Internal Circulation reactor (IC reactor) is an anaerobic digestive system with the capability to treat high-load Chemical
Oxygen Demand (COD) of industrial wastewater (e.g. brewery, potato starch, pulp and paper). IC reactor advantages
include of the following: only small areas required, shock load resistance, produces more biogas and uses less energy com-
pared to the Upflow Anaerobic Sludge Blanket (UASB) reactor. BIOPAQ@ICX is an upgrade to BIOPAQ@IC that has high-
er efficiency, lower volume, able to build from the current anaerobic reactor, and its trial has produced positive results in
many different countries and with various types of wastewater. A case study of the wastewater treatment plant at Saigon
Paper’s mills shows that the IC reactor COD removal rate is over 80% when the COD is not over 2300 mg/L; Volumetric
Load Rate (VLR) is 6–14 kgCOD/m3.day and the removal rate is higher with a higher load and could reach 80% at
14 kgCOD/m3.day; granular sludges settle very well, and the three-phase separator is efficient of preventing sludge from
washing out; pH, Total Suspended Solids (TSS), alkalinity, Volatile Fatty Acids (VFA), N-NH4+, P-PO43-, Ca2+, SO42- were
also analysed and indicated that the IC reactor is operating well.

K e y w o r d s : Internal Circulation reactor (IC reactor); Paper mill wastewater; Granular sludge; Organic compounds.

1. INTRODUCTION anaerobic processprevail due to its advantages over

aerobic:it requires no oxygen has a high load Chemical
Industrial wastewater containing high organic com- Oxygen Demand (COD), and minimizes sludge pro-
pounds and high flow rate has always been a problem duction Many types of industrial wastewater treatment
in developing and developed countries. To addressed systems could not operate well with the absence of
the issue, many possible treatments have been devel- anaerobic treatment. Currently, the most popular
oped through years of researches, some can be men- anaerobic treatment is the Up-flow Anaerobic Sludge
tion such as coagulation, [1] absorbance [2] and Blanket (UASB), which has been successfully applied
advanced oxidation process; [3; 4] however, biological in many types of wastewater [7]. However, industrial
treatments are favoured as they are environmental wastewater resulting from the manufacturing of pulp
friendly, high BOD, COD removal rate, able to treat and paper, alcohol, citric acid and sweet potato has a
N and P. Two of the most popular processes in biolog- very high COD, and the UASB is incapable of treating
ical treatments are aerobic and anaerobic, they use these types of wastewater due to its high Organic
microorganisms as a tool to treat organic industrial Loading Rate (OLR). As the average UASB OLR is
wastewater [5; 6]. Although both processes are neces- only about 1–2 kgCOD/m3.d, [7] it is necessary to
saries in most complete wastewater treating system,

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 N. Tran and M. Bui

apply a different method of biological treatment.

Internal Circulation Reactor (IC reactor) is an anaer-
obic treatment with a high removal rate of industrial
wastewater that has a very high COD (up to
35000 mg/l) and organic load [8–10]. Despite its
potential, the IC reactor has not been recognised by
many investors, and there are only a few studies on it.
Therefore, this study will focus on the assessment of
the IC reactor applied to wastewater treatment by
introducing a case study of one of Saigon Paper’s
mills to investigate its performance.

Development of IC reactor
In the mid 1990s, the second generation of anaerobic Figure 1.
treatment (with the first being UASB) was intro- Internal circulation reactor[12]
duced with the name BIOPAQ@IC. The
BIOPAQ@IC reactor’s height is 12–30 m, whereas
well with the influent; external circulation is optional
the UASB is 5–7 m. Many investors then took notice
as internal circulation occurs, saving energy needed
of the reactor due to its size and thus BIOPAQ@IC
for external circulation; internal circulation also
has gradually begun replacing the UASB. Currently,
helps dilute the influent, so the IC reactor has a high-
there are around 280 wastewater treatment systems
er shock loading [9].
designed and built by BIOPAQ, with 200 of these
being BIOPAQ@IC [9; 11].
IC reactor inhibitors
IC reactor processes As an anaerobic system, many factors should be con-
sidered while operating an IC reactor. The first factor
IC wastewater treatment is an anaerobic process;
is temperature as the effect of temperature on anaer-
therefore, the IC reactor is capable of treating
obic microorganisms is particularly significant as
biodegradable organic compounds, and this is usual-
methanogens produces more methane in high tem-
ly done before the aerobic process. The IC process is
peratures, indicating a better COD removal process.
as follows: An IC reactor is composed of three com-
The second and most important inhibition factor in
ponents; wastewater is pumped into the first compo-
anaerobic digestion is pH depending on how sensitive
nent of the reactor which has a bed of granular
methanogens are to pH changes. The optimum pH
sludge. Due to the production of biogas, the mixture
should be 6.8–7.2, and alkalinity is the factor that
of wastewater and sludge goes up to the riser and
maintains the pH of the reactor, and so it is also very
flows to the third component where gas and liquid
important to have sufficient alkalinity concentration.
are separated. After the separation, the mixture of
Toxic substances, such as oxygen, ammonia, cations
wastewater and sludge is directed through a downer
and heavy metals are the third factor that must be
and back to the bottom of the first part; the higher
considered when applying an anaerobic digestion sys-
the COD load, the more biogas will be produced,
tem [13] as it could potentially damage bacteria need-
leading to more circulation. The second component
ed for the anaerobic digestion process. The last
of the IC reactor is responsible for treating the waste-
inhibitor is Volatile Fatty Acids (VFA), a study by
water with a lower organic load from the first com-
Zhu, et al. (2018) [14] has shown VFA effects on
ponent, and the treated wastewater then flows out for
anaerobic digestion whereby the higher the level of
the next treating process.[8]
VFA, the lower the COD removal rate.
Due to its unique mechanics, the IC reactor has many
advantages over the UASB: investment cost is lower IC reactor wastewater treatment plants
as the IC reactor volume is smaller but treats the
same type of wastewater; it is taller, therefore saving Table 1 shows that the IC reactor is able to treat varieties
the ground space usually required; OLR is higher but of wastewater with high COD loads. The removal rate
with lower hydraulic retention because internal circu- varies depending on which type of wastewater is being
lation is occurring inside the reactor and mixes very treated, with most of it being over 75% while many

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 APPLYING INTERNAL CIRCULATION ANAEROBIC REACTOR FOR WASTEWATER TREATMENT: A CASE STUDY IN SAIGON PAPER MILL...
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E N V I R O N M E N T
Figure 2.
VFA and COD removal rate correlation[14]
Table 1.
IC reactor treatment plants[8; 14]
COD load Removal
Wastewater Company COD(mg/l)
(kgCOD/m3.d) rate (%)
Brewery Harbin brewing (Shenyang) Co.,Ltd 2000–2800 - 80
Sweet potato
in Zhengzhou 10865 21.9 84
starch
Fujian Nanping Paper - 12–15 65
Pulp and
paper YueYang Paper Co.,Ltd and Gaungxi Bossco Environment
- 20–26 > 75
protection Technology Co.,Ltd

Table 2.
BIOPAQ@ICX performance of Allard Emballages, France and Hamburger, Hungary compared to UASB average performance[15]
Treatment specification of BIOPAQ@ICX UASB average performance
Country France Hungary Country UK
COD load (kgCOD/m3.day) 6000–7000 7000 COD load (kgCOD/m3.day) 0.8–5.68
Flow rate (m3/h) 70–80 400–500 Flow rate (m3/h) 46–326
Biogas produce (m3/day) 2400–3000 15000 – 25000 Biogas produce (Nm3/day) 439–5992
Biogas quality (% CH4) 70 - Biogas quality (% CH4) 43.7–69.1
Removal rate (%) 80–90 74–90 Removal rate (%) 70–80

effects could have lowered its efficiency, such as systems new anaerobic digestive system called
operation, adaptation of the reactor microorganisms to @
BIOPAQ ICX, an upgraded reactor from
the following influent and increasing toxicity. BIOPAQ@IC. Compared with BIOPAQ@IC,
BIOPAQ@ICX has a different construct: instead of
having a three-phase separator, BIOPAQ@ICX sepa-
IC reactor upgrade
rates gas on the top level while biomass separation
To meet the requirements of treating different types occurs in the bottom of the reactor, which enhances
of industrial wastewater, PAQUES has introduced a efficiency and prevents sludge wash out. Spare vol-

3/2019 ARCHITECTURE CIVIL ENGINEERING ENVIRONMENT 147

 N. Tran and M. Bui

Table 3. tor to treat wastewater produced in the process of

Saigon Paper mill IC reactor operating design making paper products, but due to its low perfor-
IC VLR Sludge mance, the mill decided to change the technology to
Diameter Height HRT
volume v (m/h) (kgCOD/ volume
(m) (m) (h) meet the requirements of the wastewater effluent.
(m3) m3.d) (m3)
1395 9.5 20 4 45 m/h 6–14 650–750 Two IC reactors were invested in to treat wastewater,
but only one is currently being used with a flow rated
approximately measuring 8400 m3/day and the
Volumetric loading rate (VLR) is 6–14 kg/m3.day.
The IC reactor is 20 m high and 9.5 m in diameter,
making a total volume of 1395 m3. This study will
focus on the performance of the IC reactor through
its removal rate, granular sludge settleability and
other parameters.

2. MATERIAL AND METHODS

Figure 3.
Saigon Paper mill IC reactor
Influent and effluent samples were taken to measure
IC reactor parameters by applying Standard Methods
for the Examination of Water and Wastewater to
ume in the reactor will be used at its full potential, COD (5220 C.4), TSS (2540 D.3), Alkalinity (2320
therefore decreasing the volume of BIOPAQ@ICX B.5), N-NH4+ (4500-NO3 C.4)., P-PO43-(4500-P C.4),
[11]. In 2013 and 2014, BIOPAQ@ICX was tested in Ca2+ (2340 C.3), SO42-(4500-SO42- D.4). pH was
the Netherlands and after its success, the system was
measured on site by means of HACH HQ 11d pH
applied to a brewery, a sugar processing plant and
meter. VFA measurements were conducted following
two paper plants in France and Hungary.
Buchauer (1998) [16] titration method. A 50 mL sam-
ple was taken and filtered. 0.1 N HCl and 0.1 N
Case study NaOH were used as titrants, and the VFA concentra-
Saigon Paper mill in My Xuan A Industrial Park, Tan tion was calculated with the use of the following
Thanh District, Ba Ria-Vung Tau had a UASB reac- equation:

Figure 4.
Effect of COD concentration on COD removal

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 APPLYING INTERNAL CIRCULATION ANAEROBIC REACTOR FOR WASTEWATER TREATMENT: A CASE STUDY IN SAIGON PAPER MILL...
e
( volH2SO4pH5 to 5 x 0.1 x 131340
) 3. RESULTS AND DISCUSSUON

E N V I R O N M E N T
VFA(mgL) = –
sample volume
Figure 4 shows that the COD removal percentage
–
( 0.0616 x ( volH2SO4pH4.3 x N H2SO4 x 50000
sample volume )) – 10.9
changes depending on the COD concentration.
While for the COD concentration ranged from
1500–2500 mg/l, COD removal efficiency was above
80% and stable with the COD load up to 2300 mg/l.
When introduced with COD concentration over 2300
Table 4. mg/l, the removal rate drops to 72% as a result of
Saigon Paper mill IC reactor influent and effluent tests
overload and therefore we can determine the maxi-
result
mum COD load of the reactor.
Value *QCVN
Parameters Unit The VLR of the IC reactor at the Saigon Paper mill
12:2015/BTNMT
Influent Effluent is 6–14 kg/m3.d, and as Figure 5 shows, the higher the
pH - 5.9–6.5 6.9–7.1 5.5–9 VLR rate the higher the COD removal efficiency.
This has been proven by a study conducted by Zhang,
TSS mg/l 250–400 200–450 100
et al. (2015) [8]. But a paper mill’s VLR could reach
COD mg/l 1500–2500 300–600 150
20–25 kgCOD/m3.d as in the case of Guangxi
Alkalinity mg/l 250–400 851–1000 - Nanning Sugar Industry Co., Ltd. [8] Unfortunately,
VFA mg/l 420–630 85–110 - Saigon Paper’s IC reactor has never shown a VLR
N-NH4 mg/l 20–30 20–30 - higher than 14 kg/m3.d, and only one reactor is cur-
P-PO4 mg/l 4–6 7–9 - rently running so it is not possible to see its maximum
VLR load.
Ca2+ mg/l 300–350 - -
SO42- mg/l 50–100 1–5 - The IC reactor at the Saigon Paper mill’s wastewater
plant is using granular sludge with a volume of
*Vietnamese national technical regulations on pulp and
paper industry wastewater
650–750 m3, which is 53% of the total volume of the
reactor. Using the Imhoff test, results show the granu-
lar settleability works well; sludge was taken from five
points (P1, P2, P3, P4, P5) high at 1.6 m, 5.4 m, 9.2 m,
14 m, 17 m, respectively. The test results are as follows:

Figure 5.
Saigon Paper mill IC reactor Imhoff test results

3/2019 ARCHITECTURE CIVIL ENGINEERING ENVIRONMENT 149

 N. Tran and M. Bui

Table 5. 4. CONCLUSION
Saigon Paper mill IC reactor Imhoff test results
P1 (mL/L) P2 (mL/L) P3 (mL/L) P4(mL/L) P5(mL/L) Treating industrial wastewater without causing sec-
830 800 750 0.8 0.2 ondary pollution and recycling clean energy with high
900 770 840 1.2 0.2
efficiency is in demand, and anaerobic treatment can
900 850 810 0.5 0.5
930 850 880 0.2 0.1
meet these expectations. The IC reactor is capable of
900 870 890 0.3 0.4 treating industrial wastewater with high COD load
950 920 950 0.2 0.5 and can adapt to many types of wastewater to
increase its efficiency over time while only small
P1, P2 and P3 has a high concentration of sludge, ground areas are required and there is a lower reten-
which implies how well the sludge settles; P4 and P5 tion time compared with the current UASB reactor;
almost has no sludge available which is mostly due to therefore, it needed more attention from researchers
the three-phase separator, which helps to prevent the and investors by its superior advantages. The upgrad-
sludge from washing out of the reactor. ed BIOPAQ@ICX from BIOPAQ@IC has also shown
positive results from its trial with many types of
Influent and effluent parameter differences could be wastewater, especially paper industry wastewater.
explained: pH maintaining at 7.0 due to the presence Although it is still a new design, its potential will con-
of carbonate or bicarbonate as the IC reactor is a tinue to be researched in the future. A study of the
buffer system [13]. Higher TSS from the effluent Saigon Paper mill’s IC reactor has also been evaluat-
indicated high turbulence inside the IC reactor due ed in this paper, which has shown the removal rate is
to high water velocity influent and water mixing from stable at the COD concentration of 1500–2300 mg/l
the circulation. The three-phrase separators are and is considered as an inhibitor above 2300 mg/l.
designed to hold the granular sludge and so smaller VLR has also affected the removal rate, showing that
sludge could still be washed out along with the efflu- the higher the VLR, the higher the removal rate.
ent. The increase in alkalinity is due to the addition Granular sludge used in the reactor accounted for
CaCO3 to ensure the stable pH of the system and the 53% of its volume and has a good settleability, and by
production of HCO3- by methanogens. During the testing the effluent parameters, the IC reactor is con-
anaerobic processes, VFA levels will certainly drop as cluded to be well operated and fully capable of treat-
these are the material needed to produce biogas by ing pulp and paper wastewater.
methanogens. Microorganisms need to consume N
and P as nutrients to exist, so NH4- and PO4- were
added to feed the microorganisms. The residue of
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