Solutions QP
Solutions QP
Solutions QP
CHEMISTRY
Time : 1 Hr
1. The molecular masses of polymers are determined by osmotic pressure method and nor by 2
measuring other colligative properties. Give two reasons.
3. How is vapour pressure of solvent affected when a non volatile solute is dissolved in it? 2
6. Some ethylene glycol, HOCH2—CH2OH is added to your car’s cooling system along with 5 kg of 3
water. If the freezing point of water glycol solution is –15 °C, what is the boiling point of the
solution? [Kb = 0.52 K kg mol–1, Kf = 1.86 K kg mol–1]
7. What would be the molar mass of a compound if 6.21 g of it dissolved in 24.0 g of chloroform 3
forms a solution that has a boiling point of 68.04 °C. The boiling point of pure chloroform is 61.7 °C
and the boiling point elevation constant, Kb for chloroform is 3.63 °C/m.
8. 3.9 g of Benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 3
K. Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated).
(Given; Molar mass of benzoic acid = 122 g mol–1, Kf for benzene = 4.9 K kg mol–1)
9. What is the molality of ammonia in a solution containing 0.85 g of NH3 in 100 mL of a liquid of 3
density 0.85 g cm–3?
10. The Henry’s Law constant for oxygen dissolved in water is 4.34×104 atm at 25 °C. If the partial 3
pressure of oxygen in air is 0.2 atm, calculate the solubility of oxygen in water at 25 °C.
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