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REVISION TEST-2-PA-3

CHEMISTRY

CLASS XII - SOLUTIONS Max Marks : 30

Time : 1 Hr

1. The molecular masses of polymers are determined by osmotic pressure method and nor by 2
measuring other colligative properties. Give two reasons.

2. Define the following terms: 2


(i) Mole fraction
(ii) Isotonic solutions
(iii) van’t Hoff factor
(iv) Ideal solution

3. How is vapour pressure of solvent affected when a non volatile solute is dissolved in it? 2

4. A solution is prepared by dissolving 10 g of non-volatile solute in 200 g of water. It has a vapour 2


pressure of 31.84 mm Hg at 308 K. Calculate the molar mass of the solute. (Vapour pressure of
pure water at 308 K = 32 mm Hg)

5. 18 g of glucose, C6H12O6, is dissolved in 1 kg of water in a saucepan. At what temperature will 2


water boil at 1.103 bar? (Kb for H2O is 0.52 k kg mol–1)

6. Some ethylene glycol, HOCH2—CH2OH is added to your car’s cooling system along with 5 kg of 3
water. If the freezing point of water glycol solution is –15 °C, what is the boiling point of the
solution? [Kb = 0.52 K kg mol–1, Kf = 1.86 K kg mol–1]

7. What would be the molar mass of a compound if 6.21 g of it dissolved in 24.0 g of chloroform 3
forms a solution that has a boiling point of 68.04 °C. The boiling point of pure chloroform is 61.7 °C
and the boiling point elevation constant, Kb for chloroform is 3.63 °C/m.

8. 3.9 g of Benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 3
K. Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated).
(Given; Molar mass of benzoic acid = 122 g mol–1, Kf for benzene = 4.9 K kg mol–1)

9. What is the molality of ammonia in a solution containing 0.85 g of NH3 in 100 mL of a liquid of 3
density 0.85 g cm–3?

10. The Henry’s Law constant for oxygen dissolved in water is 4.34×104 atm at 25 °C. If the partial 3
pressure of oxygen in air is 0.2 atm, calculate the solubility of oxygen in water at 25 °C.

11. (a) Explain the following: 5


(i) Henry’s law about dissolution of a gas in a liquid.
(ii) Boiling point elevation constant for a solvent.
(b) A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of
water. This solution has a boiling point of 100.42 °C. What mass of glycerol was dissolved to make
this solution? (Kb for water = 0.512 K kg mol–1)

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