The compressibility factor Z is a dimensionless factor inde- Hence
pendent of the quantity of gas and determined by the char- acter of the gas, the temperature, and pressure (see Table for 1 Vg 1 dz 1 meaning of symbols): Vg p T z dp p Z = PV/NRT + MPV/mRT A knowledge of the compressibility factor means that the For gases at low pressures the second term is small density, ρ, is also known from the relationship: and the compressibility can be approximated by cg ≈ 1/p. ρ = PM/ZRT Equation 2 is not particularly convenient for determining the gas compressibility because z is not actually a function The isothermal gas compressibility, which is given the of p but of pr. However, equation 2 can be made convenient symbol cg, is a useful concept which will be used extensively in terms of a dimensionless pseudo-reduced gas compress- in determining the compressible properties of the reser- ibility defined as: voir. The isothermal compressibility is also called the bulk modulus of elasticity. Gas usually is the most compressible cr = cgppc medium in the reservoir. However, care should be taken so Multiplying equation 2 through by the pseudo-critical that it not be confused with the gas deviation factor, z, which pressure, is sometimes called the super-compressibility factor. The isothermal gas compressibility is defined as: 1 1 z cr c g p pc pr z pr Tr 1 Vg cg Vg p T The expression for calculating the pseudo-reduced com- pressibility is: An expression in terms of z and p for the compressibility can be derived from the real gas law: 1 0.27 ( z/ r )Tr cr Vg nRT z znRT ’ znR T 1 dz ’ znR T 1 pr z 2Tr r z 1 p T p p T p2 p z dp p p z r Tr
There is also a close relationship between the formation
From the real gas equation of state: volume factor of gas and the isothermal gas compressibility. It can be easily shown that: 1 p 1 Bg cg Vg znRT Bg p T
151 152 Rules of Thumb for Petroleum Engineers
Table symbols used in determining the compressibility factor.
Field units SI units P = absolute pressure psia kPa V = volume ft3 m3 n = moles m/M m/M m = mass lb kg M = molecular mass lb/lb mole kg/kmole T = absolute temperature °R K R = universal gas constant 10 73 [psia ft /°R • lb mole mole] 3 8.3145 [kPa m3/kmol • K] ρ = density slug/ft3 kg/m3