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Atoms Wallch

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WALL CHART

atoms

Distance of closest approach : For an electron in nth orbit :


(K.E) α-particle = P.E. of nucleus and n2 h2 ε0
α-particle Radius , rn =
π m Z e2
Bohr’s postulates : Energy of electron in nth orbit :
Postulate # 1: m Z 2 e4
Orbital angular momentum, Energy , En = 
8 ε02 h2 n2
nh
L = 13.6 Z 2
2π =  eV
n2
Postulate # 2 : Ei  Ek = h υ , Speed of electron in orbit :
where υ is frequency of the emitted Z e2
vn =
radiation 2 ε0 hn
Lyman series : Condition for electron as a wave :
1 1 1 nh
= R ( 2  2 ) where, n = 2,3,4,... 2πr = n  =
λ 1 n mv
Balmer series : Rydberg’s constant :
1 1 1
= R ( 2  2 ) where, n = 3,4,5,... R = 1.097 x 107 m1
λ 2 n m e4
R =
8 ε02 c h3
Paschen series : Minimum wavelength in X-rays :
1 1 1 hc
= R ( 2  2 ) where, n = 4,5,6,...  min =
λ 3 n eV
where, V is accelerating voltage
Brackett series : Wavelength for K-series radiation :
1 1 1
= R ( 2  2 ) where, n = 5,6,7,... 1 m e 4 (Z  1)2  1 1 
λ =   
4 n λ 8ε02 c h3  12 n2 
Pfund series : The graph of f versus Z is a straight
1 1 1
= R ( 2  2 ) where, n = 6,7,8,... line. f = C( Z 1 ) = C Z C
λ 5 n

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