Atomic Structure - Short Notes - Arjuna NEET 2025
Atomic Structure - Short Notes - Arjuna NEET 2025
Atomic Structure - Short Notes - Arjuna NEET 2025
2 Atomic Structure
mv 2 Ke 2 Z nh
= mvr =
r r2 2π
n 2h 2 n2
r= rn = 0.529 × Å
4π2 mKZe 2 Z
2πZe 2 K Z
V= Vn = 2.18 × 106 × m/sec
nh n
2πr v
T= f=
v 2πr
2π2 me 4 k 2 z 2
T.E. = En = – 2 For H-atom
h2 n
Z2
En = – 13.6 eV / atom rn = 0.529 × n2
n2
1 V1
T.E. = P.E. Vn =
2 n
Z2
En = – 2.18 × 10–18 J/atom En = E1/n2
n2
n = orbit no.
T.E. = – K.E.
Emission Spectrum of Hydrogen & H-like species. Heisenberg's Uncertainty
hC h h
∆E = hν = ; h = Planck's Constant(h = 6.62 × 10–34 JS) ∆x . ∆p ≥ or ∆x . (m∆v) ≥
λ 4π 4π
C = Velocity of Light h
∆E.∆t ≥ ; Dx = change in position
l = Wavelength 4π
1 1 1 Dp = change in Momentum
= ν = RZ2 2 − 2 P = y2dv, P = probability of finding electron
λ n1 n 2
where, y = wave function
R = Rydberg constant = 1.09678 × 107 m–1
n = Lower energy level
1 Radial nodes = n – – 1,
n2 = Higher energy level
Angular nodes = ,
∆n (∆n + 1)
Number of different line produce = , where ∆n Total nodes = n – 1
2
= n2 – n1. Quantum Numbers
Number of subshell present in nth shell = n.
n2 = higher energy orbit, n1 = lower energy orbit. Number of orbitals present in nth shell = n2.
For single isolated atom maximum number of spectral lines The maximum number of electrons in a principal energy
observed = (n – 1). shell = 2n2.
nh
de-Broglie's Hypothesis Angular momentum of any orbit = .
2π
l = de-Broglie wavelength Number of orbitals in a subshell = 2 + 1
h = Planck's Constant Maximum number of electrons in particular subshell = 2 ×
m = mass of particle (2 + 1).
e = charge on particle h h
L
= ( +=
1) ( +1)=
2π .
V = Accelerated Potential 2π
h h Orbitals present in a main energy level is ‘n2’.
=
λ = , p = momentum
mv p
µ
= n (n + 2) B.M. , n = No. of unpaired electron.
h
λ= h
2emV =
Spin angular momentum s(s + 1) .
2π
12.3
λ= Å 1
V Maximum spin of atom = × No. of unpaired electron.
2
P
W Atomic Structure 5