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Coating Adhesion Testing

Pull-off adhesion testing is used to evaluate the bond strength between a coating and substrate. It involves gluing dollies to the coated surface and pulling them off to determine the strength of adhesion. There are standardized test methods for metal and concrete substrates. The test can identify if failure occurred between coating layers or the substrate, or within a coating layer. Proper equipment selection, surface preparation, adhesive application, and recording of failure modes are required to obtain accurate and reproducible results.

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Ravindra S. Jivani

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75% found this document useful (4 votes)

534 views

Coating Adhesion Testing

Uploaded by

Ravindra S. Jivani

Available Formats

Download as PPTX, PDF, TXT or read online on Scribd

You are on page 1/ 37

Pull-Off Adhesion Testing

Presented by: David Beamish,

DeFelsko Corporation

Pull-Off Adhesion Testing

Presented by: David Beamish,
DeFelsko Corporation

Learning Outcomes
At the end of this webinar you will be able to:

Define pull-off strength

Explain the difference between Adhesion and Cohesion
Describe several types of pull testers
Understand requirements of ASTM D4541, Standard Test Method for
Pull-Off Strength of Coatings Using Portable Adhesion Testers

Conduct a pull test

Understand differences when testing on
concrete
Analyze and report test results
List common pitfalls
4

Introduction
This webinar will discuss the
method for evaluating the
pull-off strength (commonly
referred to as adhesion) of a
coating system applied to a
metal substrate.

Adhesion
A complex phenomenon related to physical and
chemical forces
The ability of a coating to adhere to the substrate or
to a previous coating
There are many ways to evaluate degree of bonding.
But there is no single test to accurately and
quantitatively determine adhesion
Many factors should be taken into account.
Conservative evaluations are recommended

What is Being Measured?

Coating strength at different planes
Adhesion Strength - Bond strength between
the substrate and the coating and/or the coating
layer to one another

Cohesion Strength - Inner-strength of a

coating layer

Adhesion strength is highly variable

No industry wide adhesion acceptance value
Minimum adhesion values may be on a PDS or in
a specification
7

The Pull-Off Test

A loading fixture (dolly) is glued to the
coating, then pulled by a portable tester.
Determines:
greatest tensile force that a surface area can bear before
material is detached, or
whether the surface remains intact at a prescribed force
(pass/fail).

Scratch or knife adhesion results may not be

comparable

Pull-Off Strength Test Method

For metal substrates use:
ASTM D 4541, Standard Test Method
for Pull-Off Strength of Coatings
Using Portable Adhesion Testers

For concrete substrates use:

ASTM D 7234, Standard Test Method for
Pull-Off Strength of Coatings on Concrete
Using Portable Pull-Off Adhesion Testers

Portable Pull-off Adhesion

Testers
Mechanical (twist by hand)
Hydraulic (oil pressure)
Pneumatic (air pressure)

Widely used by coatings manufacturers,

specifiers, inspectors, coating specialists.

Testing Equipment
The following 5 devices are
described:
Method A: Discontinued
Method B: Fixed Alignment Type II
(Mechanical)
Method C: Self-Aligning Type III (Hydraulic)
Method D: Self-Aligning Type IV (Pneumatic)
Method E: Self-Aligning Type V (Hydraulic)
Method F: Self-Aligning Type VI (Hydraulic)

Results obtained by each test

Test Method B
Fixed Alignment Type II (Mechanical)

Test Method C
Self-Aligning Type III (Hydraulic)
Load is applied through the center of
the loading dolly by a hydraulic
piston and pin

Test Method D
Self-Aligning Type IV (Pneumatic)

Test Method E
Self-Aligning Type V (Hydraulic)

Test Method F
Self-Aligning Type VI (Hydraulic)

ASTM D 4541 Overview

1. Select and clean the test site
2. Prepare the test dollies
3. Apply adhesive to dolly and/or
surface and allow to cure
4. Score around the dolly through
to the substrate (optional)
5. Connect an adhesion tester
and pull to failure or to a specified max force
6. Record the final pulling force and qualify the
nature
of the failure
17

Apparatus
1. Adhesion Tester, commercially available,
examples are listed in Annex A1 - A5
a.
b.
c.
d.
e.
f.

Loading Fixtures
Detaching Assembly
Base (if needed by the adhesion tester)
Means of pulling the loading fixtures vertically
Timer to maintain 150 psi/s in 100s
Force indicator

Apparatus
2.
3.
4.
5.
6.
7.

Solvent
Sandpaper
Adhesive
Clamps
Cotton Swabs
Circular Hole Saw (optional)

1 Select and Clean Test Site

A flat surface large enough to accommodate the
specified number of replicate test dollies
For statistical purposes 3 test sites within a
specified area are typically required

A rigid surface that can support the counter

force
Steel substrates less than 3.2 mm () thickness
usually reduce pull-off strength

1 Select and Clean Test Site

The surface should be lightly abraded to
promote adhesion of the adhesive
Lightly roughen with fine sandpaper (400 grit or finer)
or abrasive pad, especially smooth or glossy surfaces
Care must be taken to prevent damage or significant
loss of coating thickness

Perform a SSPC-SP 1, Solvent Cleaning

Remove residual dust with a solvent that does not
degrade the coating
21

Loading Fixture Design

Fixed
Alignment
Type II

Self-Aligning
Type VI

SelfAligning
Type III

Self-Aligning
Type IV

Known as: -Loading

Fixtures, or
-Dollies, or
-Studs, or
-Pull Stubs

SelfAligning
Type V

2 - Prepare the Loading

Fixtures
Follow the manufacturers instructions

Failures at the dolly-adhesive interface may be

avoided by treating the dolly surface in accordance
with ASTM Guide D2651, Standard Guide for
Preparation of Metal Surface for Adhesive Bonding

3 - Apply Adhesive
Identify a suitable glue:
Cyanoacrylates (super glues) cure quickly and are
commonly used on some coatings with low bond
strengths
2-part epoxies when stronger bonds are required

3 - Apply Adhesive
Prepare and apply the adhesive according to the
manufacturers instructions
Note: Adding about 1% of #5 glass beads to the
adhesive helps with test dolly alignment

Apply adhesive over the entire surface area of the

dolly
Place dolly onto the surface
Remove excess adhesive
from around the dolly with
a Q-Tip without moving
the dolly
25

3 - Apply Adhesive
While curing, a constant pressure should be
maintained on the dolly using:
Magnetic or mechanical clamping systems
Masking tape

4 - Score around the dolly

Scoring is a method of cutting around the

perimeter of the dolly down to the substrate
Should only be done for:
coatings greater than
500 m (20 mils) thick
reinforced coatings
elastomeric coatings

Avoid twisting or torquing the test area

A template made out of plywood with a hole is an
effective method to avoid cutting tool movement

5 Pull the Dolly

Attach the apparatus and set the force indicator to zero
Increase the load to the dolly in a smooth, continuous
manner

Not faster than 1 MPa/s (150

psi/s)
Not longer than 100 seconds

6 Record the Results

General test description
Temperature and Humidity
Equipment selected
Scoring if performed
Date, time, operator
Record the maximum pull force
At failure, or
The maximum force applied
29

6 Record the Results

Report the Type and Location of the Break
Adhesion Break: A break between coating layers or
between the substrate and first coating layer

Cohesion Break: A break within a single coating layer

Glue Break: Coating adhesion and/or cohesion strength
exceeds bonding strength of the adhesive

If multiple locations of break occur, estimate the % of

each
e.g., 75% cohesion within primer; 25% adhesion between
primer and intermediate coats

Types of Breaks

5
31

What is Acceptable?

ASTM D 7234
Concrete Test Differences
Larger 2 (50 mm) diameter
loading fixtures
Scoring is generally performed
Slower loading rate
Failure is typically within the
concrete itself
SSPC SP13/NACE No. 6, Appendix A1.6 describes
procedures for testing concrete coating adhesion
33

Cautions
1.
2.
3.
4.
5.
6.
7.

Use D 4541 charts to select a test device

Verify test device has current calibration
The substrate must be rigid
Adhesive should not damage the coating
Prepare the contact surfaces
Mix and apply the adhesive carefully
Perform testing in triplicate

Summary
Pull-off adhesion testing is an
excellent method for verification that
the coating has created a mechanical
bond with the substrate

Acknowledgements
-SSPC www.sspc.org Market Place
-ASTM www.astm.org Standards
-Bill Corbett, KTA,