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    Leonardo Sagnotti

    This data table contains rock-magnetic parameters and paleomagnetic data of a 1.2 Ma sediment core composite ICDP 5045-1 from Lake Ohrid. Measurements have been conducted on discrete cube samples using a cryogenic magnetometer.
    The bulk magnetic mineral record from Lake Ohrid, spanning the past 637 kyr, reflects large-scale shifts in hydrological conditions, and, superimposed, a strong signal of environmental conditions on glacial–interglacial and millennial... more
    The bulk magnetic mineral record from Lake Ohrid, spanning the past 637 kyr, reflects large-scale shifts in hydrological conditions, and, superimposed, a strong signal of environmental conditions on glacial–interglacial and millennial timescales. A shift in the formation of early diagenetic ferrimagnetic iron sulfides to siderites is observed around 320 ka. This change is probably associated with variable availability of sulfide in the pore water. We propose that sulfate concentrations were significantly higher before ~320 ka, due to either a higher sulfate flux or lower dilution of lake sulfate due to a smaller water volume. Diagenetic iron minerals appear more abundant during glacials, which are generally characterized by higher Fe/Ca ratios in the sediments.While in the lower part of the core the ferrimagnetic sulfide signal overprints the primary detrital magnetic signal, the upper part of the core is dominated by variable proportions of high- to low-coercivity iron oxides. Glacial sediments are characterized by high concentration of high-coercivity magnetic minerals (hematite, goethite), which relate to enhanced erosion of soils that had formed during preceding interglacials. Superimposed on the glacial–interglacial behavior are millennial-scale oscillations in the magnetic mineral composition that parallel variations in summer insolation. Like the processes on glacial–interglacial timescales, low summer insolation and a retreat in vegetation resulted in enhanced erosion of soil material. Our study highlights that rock-magnetic studies, in concert with geochemical and sedimentological investigations, provide a multi-level contribution to environmental reconstructions, since the magnetic properties can mirror both environmental conditions on land and intra-lake processes.
    We have undertaken a magnetic susceptibility (K) survey of various meteorite collections in Italy and Vatican, using a large coil (8 cm) Kappabridge instrument. This original database, merged with previous data from Finnish and Czech... more
    We have undertaken a magnetic susceptibility (K) survey of various meteorite collections in Italy and Vatican, using a large coil (8 cm) Kappabridge instrument. This original database, merged with previous data from Finnish and Czech collections [1], allows us to analyze about 650 different ordinary chondrites, equally distributed in 3 categories: falls, Antarctic and non-Antarctic finds (half from Sahara). For
    This paper provides new petrochemical and paleomagnetic data from obsidian sub-sources on the island of Pantelleria, exploited since the Neolithic. Data has been obtained from 14 obsidian samples from 4 locations: Fossa della Pernice (2... more
    This paper provides new petrochemical and paleomagnetic data from obsidian sub-sources on the island of Pantelleria, exploited since the Neolithic. Data has been obtained from 14 obsidian samples from 4 locations: Fossa della Pernice (2 sites), Salto la Vecchia and Balata dei Turchi. Here, we aim to better characterize these obsidians using a cross-disciplinary and multi-analytical approach, to further understand their archaeological significance. Major element analyses (EMP) have enabled two compositional super-groups to be distinguished: (i) Fossa della Pernice, less peralkaline and (ii) Balata dei Turchi–Salto la Vecchia, distinctly more peralkaline and having almost identical chemical patterns. Trace element analyses (LA-ICP-MS) corroborate major element groupings, with the Balata dei Turchi–Salto la Vecchia super-group being further characterized by a pronounced negative europium anomaly. Glass H2O contents (FT-IR) reveal an overlap among all the sub-sources (H2O = 0.1–0.3 wt. ...
    This dataset presents the chronological framework, (bio-)geochemical, mineralogic stable isotope, pollen, and tephrochronologic data of the upper 448 m of the DEEP site (5045-1) sediment sequence recovered from the central part of Lake... more
    This dataset presents the chronological framework, (bio-)geochemical, mineralogic stable isotope, pollen, and tephrochronologic data of the upper 448 m of the DEEP site (5045-1) sediment sequence recovered from the central part of Lake Ohrid (Macedonia, Albania) under the umbrella of the International Continental Scientific Drilling Program (ICDP) and the project Scientific Collaboration on Past Speciation Conditions in Lake Ohrid (SCOPSCO). The investigated interval comprises fine-grained muds with intercalated tephra layers and mass movement deposits of mostly less than 5 cm thickness. Two tephra layers of thicknesses more than 5 cm were excluded prior to age-depth modelling, which is based on tephrostratigraphy, tephrochronology, magnetostratigraphy, and tuning of biogeochemical proxy data versus local orbital parameters. (Bio-)geochemical analyses comprise X-Ray fluorescence scanning at 2.5 mm resolution (Potassium and Calcium intensities), and total inorganic carbon (TOC) and total organic carbon (TOC) determinations at 16 cm resolution. The relative abundance of quartz minerals (Quartz peak area, 16 cm resolution) was detected by means of Fourier Transform Infrared Spectrometry (FTIRS). Oxygen and carbon stable isotope were analysed on (interglacial) sediments where endogenic calcite crystals were found to be abundant. Pollen data presented herein at 64 cm resolution comprise a sub-dataset of the total pollen counts and presents relative percentages of arboreal taxa minus pine (AP-pine), and of deciduous oaks, respectively. Tephrochronologic data comprises geochemical fingerprint analyses of individual glass shards found in the sediments of Lake Ohrid, and a new Ar/Ar age for tephra V5 from the Montalbano Jonico section.Climate time series data are derived from a transient 784 ka simulation using the earth system model LOVECLIM as well as NOAA reanalysis precipitation data of the Lake Ohrid region for the tim period 1979-2017.
    This study reviews and synthesises existing information generated within the SCOPSCO ("Scientific Collaboration on Past Speciation Conditions in Lake Ohrid") deep drilling project. The four main aims of the project are to infer... more
    This study reviews and synthesises existing information generated within the SCOPSCO ("Scientific Collaboration on Past Speciation Conditions in Lake Ohrid") deep drilling project. The four main aims of the project are to infer (i) the age and origin of Lake Ohrid (Former Yugoslav Republic of Macedonia/Republic of Albania), (ii) its regional seismotectonic history, (iii) volcanic activity and climate change in the central northern Mediterranean region, and (iv) the drivers of biodiversity and endemism. The Ohrid basin formed by transtension during the Miocene, opened during the Pliocene and Pleistocene, and the lake established de novo in the still relatively narrow valley between 1.9 and 1.3 Myr ago. The lake history is recorded in a 584 m long sediment sequence, which was recovered within the framework of the International Continental Scientific Drilling Program (ICDP) from the central part (DEEP site) of the lake in spring 2013. To date, 50 tephra and cryp...
    Abstract Reconstruction of Paleomagnetic Secular Variation (PSV) of the geomagnetic field is fundamental both to assess geodynamo models and to obtain age constraints for rocks, sediments and archaeological material. We present refined... more
    Abstract Reconstruction of Paleomagnetic Secular Variation (PSV) of the geomagnetic field is fundamental both to assess geodynamo models and to obtain age constraints for rocks, sediments and archaeological material. We present refined age-calibrated Holocene PSV and relative paleointensity (RPI) stack curves derived from Arctic marine sediments (Northwestern Barents Sea). The Holocene sections of four sedimentary cores were correlated on the basis of paleomagnetic trends and age models, and stacked. The resultant composite PSV and RPI Holocene records (NBS stack) and the reconstructed Holocene Virtual Geomagnetic Pole (VGP) path were evaluated in comparison with the most recent paleomagnetic stack curves and geomagnetic field models. The data indicate that during the Holocene time, the VGPs moved within the superficial projection of the inner core tangent cylinder, with the exception of short time intervals around 5600 and 3200 cal yr BP when VGPs extended to lower latitudes. These deviations might reflect regional geomagnetic features, such as persistent geomagnetic flux lobes at core-mantle boundary. Our data confirm that the large VGP shift observed around 5600 cal yr BP is the result of an increased radial magnetic field at the core-mantle boundary over North America, whilst the VGP shift around 3200 cal yr BP represents a major swing to middle latitudes toward the Middle East and might be associated to a regional high paleointensity peak, known as Levantine Iron Age Anomaly (LIAA).
    A high-resolution paleomagnetic and rock magnetic study has been carried out on sediment cores collected in glaciomarine silty-clay sequences from the continental shelf and slope of the southern Storfjorden trough-mouth fan, on the... more
    A high-resolution paleomagnetic and rock magnetic study has been carried out on sediment cores collected in glaciomarine silty-clay sequences from the continental shelf and slope of the southern Storfjorden trough-mouth fan, on the northwestern Barents Sea continental margin. The Storfjorden sedimentary system was investigated during the SVAIS and EGLACOM cruises, when 10 gravity cores, with a variable length from 1.03 m to 6.41 m, were retrieved. Accelerator mass spectrometry (AMS) 14C analyses on 24 samples indicate that the cores span a time interval that includes the Holocene, the last deglaciation phase and in some cores the last glacial maximum. The sediments carry a well-defined characteristic remanent magnetization and have a valuable potential to reconstruct the paleosecular variation (PSV) of the geomagnetic field, including relative paleointensity (RPI) variations. The paleomagnetic data allow reconstruction of past dynamics and amplitude of the geomagnetic field variations at high northern latitudes (75°-76° N). At the same time, the rock magnetic and paleomagnetic data allow a high-resolution correlation of the sedimentary sequences and a refinement of their preliminary age models. The Holocene PSV and RPI records appear particularly sound, since they are consistent between cores and they can be correlated to the closest regional stacking curves (UK PSV, FENNOSTACK and FENNORPIS) and global geomagnetic model for the last 7 ka (CALS7k.2). The computed amplitude of secular variation is lower than that outlined by some geomagnetic field models, suggesting that it has been almost independent from latitude during the Holocene.
    The 624.15 m glaciomarine sedimentary succession recovered in the CRP-2/2A drillcore comprises lower Oligocene (1000 m/m.y.). Between 306.65 mbsf and the bottom of the drillcore (624.15 mbsf), fewer datums are available to constrain the... more
    The 624.15 m glaciomarine sedimentary succession recovered in the CRP-2/2A drillcore comprises lower Oligocene (1000 m/m.y.). Between 306.65 mbsf and the bottom of the drillcore (624.15 mbsf), fewer datums are available to constrain the age model and unique correlation with the MPTS is not possible, although high average sediment accumulation rates are likely. A significant unconformity is identified at 306.65 mbsf, which may represent as much as 5 m.y. of missing time. Additional unconformities at 25.92 and 130.27 mbsf account for c. 16 and 2.5 m.y. of missing time, respectively. The Oligocene-lower Miocene interval documented in the CRP-2/2A drillcore spans about 13 million years, however, it is possible that more time is missing in sequence-bounding unconformities than is represented in the stratigraphic record recovered in the CRP-2/2A drillcore.
    Bohaty, SM, Fielding, CR, Florindo, F., Hannah, M., Harwood, DM, McIntosh, WC, Naish, TR, Roberts, AP, Sagnotti, RP, Scherer, CP, Strong, CKL, Verosub, KL, Villa, G., Watkins, DK, Webb, P., Wilson, GS and Woolfe, KJ (2000)... more
    Bohaty, SM, Fielding, CR, Florindo, F., Hannah, M., Harwood, DM, McIntosh, WC, Naish, TR, Roberts, AP, Sagnotti, RP, Scherer, CP, Strong, CKL, Verosub, KL, Villa, G., Watkins, DK, Webb, P., Wilson, GS and Woolfe, KJ (2000) Chronostratigraphy of the CRP-2/2A Drillcore, Ross Sea, Antarctica. Terra Antartica. An Antarctic Earth Sciences Journal, 7 4: 647-657.
    The AND-1B drill core recovered a 13.57 million year Miocene through Pleistocene record from beneath the McMurdo Ice Shelf in Antarctica (77.9°S, 167.1°E). Varying sedimentary facies in the 1285 m core indicate glacial-interglacial... more
    The AND-1B drill core recovered a 13.57 million year Miocene through Pleistocene record from beneath the McMurdo Ice Shelf in Antarctica (77.9°S, 167.1°E). Varying sedimentary facies in the 1285 m core indicate glacial-interglacial cyclicity with the proximity of ice at the site ranging from grounding of ice in 917 m of water to ice free marine conditions. Broader interpretation of climatic conditions of the wider Ross Sea Embayment is deduced from provenance studies. Here we present an analysis of the iron oxide assemblages in the AND-1B core and interpret their variability with respect to wider paleoclimatic conditions. The core is naturally divided into an upper and lower succession by an expanded 170 m thick volcanic interval between 590 and 760 m. Above 590 m the Plio-Pleistocene glacial cycles are diatom rich and below 760 m late Miocene glacial cycles are terrigenous. Electron microscopy and rock magnetic parameters confirm the subdivision with biogenic silica diluting the te...
    Thirty years after oxygen isotope records from microfossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth's orbital geometry control the ice ages (Hays et al., 1976,... more
    Thirty years after oxygen isotope records from microfossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth's orbital geometry control the ice ages (Hays et al., 1976, doi:10.1126/science.194.4270.1121), fundamental questions remain over the response of the Antarctic ice sheets to orbital cycles (Raymo and Huybers, 2008, doi:10.1038/nature06589). Furthermore, an understanding of the behaviour of the marine-based West Antarctic ice sheet (WAIS) during the 'warmer-than-present' early-Pliocene epoch (~5-3 Myr ago) is needed to better constrain the possible range of ice-sheet behaviour in the context of future global warming (Solomon et al., 2007). Here we present a marine glacial record from the upper 600 m of the AND-1B sediment core recovered from beneath the northwest part of the Ross ice shelf by the ANDRILL programme and demonstrate well-dated, ~40-kyr cyclic variations in ice-sheet extent linked to cycles in insolation influenced by changes in the Earth's axial tilt (obliquity) during the Pliocene. Our data provide direct evidence for orbitally induced oscillations in the WAIS, which periodically collapsed, resulting in a switch from grounded ice, or ice shelves, to open waters in the Ross embayment when planetary temperatures were up to ~3° C warmer than today ( Kim and Crowley, 2000, doi:10.1029/1999PA000459) and atmospheric CO2 concentration was as high as ~400 p.p.m.v. (van der Burgh et al., 1993, doi:10.1126/science.260.5115.1788, Raymo et al., 1996, doi:10.1016/0377-8398(95)00048-8). The evidence is consistent with a new ice-sheet/ice-shelf model (Pollard and DeConto, 2009, doi:10.1038/nature07809) that simulates fluctuations in Antarctic ice volume of up to +7 m in equivalent sea level associated with the loss of the WAIS and up to +3 m in equivalent sea level from the East Antarctic ice sheet, in response to ocean-induced melting paced by obliquity. During interglacial times, diatomaceous sediments indicate high surface-water productivity, minimal summer sea ice and a [...]
    In order to understand the growth and retreat of glaciers in response to the glacial-interglacial changes, subglacial marine sedimentary sequences have been studied extensively in the continental shelf areas of the Ross Sea. The purpose... more
    In order to understand the growth and retreat of glaciers in response to the glacial-interglacial changes, subglacial marine sedimentary sequences have been studied extensively in the continental shelf areas of the Ross Sea. The purpose is to comprehend the glaciomarine sedimentation change on the continental slope of eastern Pennell-Iselin Bank in the Ross Sea, using three gravity cores (C1, C2, C3) and three box cores (BC1, BC2, BC3) collected from sites (RS14-1, 2, 3), respectively, across the continental slope to the eastern side of the Pennell-Iselin Bank during XXIX° (2014) PNRA expedition (Rosslope Ⅱ project). Several sedimentological (grain size, magnetic susceptibility), elemental (XRF), geochemical (biogenic opal, total organic carbon, total nitrogen, C/N ratios, CaCO3), and isotopic (δ13C and δ15N of organic matter) parameters were measured along sediment cores with AMS 14C dating of bulk sediments. Core-sediments consist mostly of hemipelagic sandy clay or silty clay wit...
    The Contessa Section is a reference section for the early Miocene in the Mediterranean. Along this 36 m thick section 115 samples were collected and analysed for an integrated bio-magnetostratigraphic study through the Scaglia Cinerea and... more
    The Contessa Section is a reference section for the early Miocene in the Mediterranean. Along this 36 m thick section 115 samples were collected and analysed for an integrated bio-magnetostratigraphic study through the Scaglia Cinerea and Bisciaro formations. Planktonic foraminifera were analysed semi-quantitatively, while calcareous nannofossils were examined using the standard quantitative method. A reliable biozonation for both fossil groups was then accomplished. The paleomagnetic analyses identified a sequence of magnetozones, then correlated with the ATNTS using the calcareous plankton bioevents. The investigated interval extends from foraminiferal Zone P22 (Chattian) to MMi2c (Burdigalian) and from calcareous nannofossils Zone MNP25a to MNN3a, thus from Chron C7An to C5En. Therefore, the section chronologically spans from 24.80 Ma to18.10 Ma. Three hiatuses were recognised along the section: H1 at 0.63 m from the base (comprising a minimum time interval from 24.36 Ma to 23.38 Ma), H2 at 12.33 m (between 21.80 Ma and 21.35 Ma) and H3 at 34.03 (between 19.21 Ma and 18.40 Ma). All three hiatuses were correlated with regional megahiatuses identified in the North Atlantic Ocean and in the Paratethys area. Furthermore, the First Occurrenceof the calcareous nannofossil Helicosphera ampliaperta is recognised within Chron C6An.2n at 19.77 m from the base (6 m above the volcaniclastic Raffaello Level). This event provisionally defines the Aquitanian/Burdigalian boundary according to the literature. Thus, the Contessa Section is a possible candidate for the definition of theBurdigalian Global Stratigraphic Section and Point. Finally, the age of the Raffaello Level (a regional marker horizon for the early Miocene) is discussed in this new integrated stratigraphic framework, falling in Chron C6AAn and dated between 21.09 Ma and 21.08 Ma.
    We present a paleomagnetic and rock magnetic data set from two long sediment cores collected from Bellsund and Isfjorden contourite drifts located on the eastern side of the Fram Strait (western Spitsbergen margin). The data set gave the... more
    We present a paleomagnetic and rock magnetic data set from two long sediment cores collected from Bellsund and Isfjorden contourite drifts located on the eastern side of the Fram Strait (western Spitsbergen margin). The data set gave the opportunity to define the behavior of the past geomagnetic field at high latitude and to constrain the palaeoclimatic events that occurred in a time framework spanning marine isotope stage 3 to the Holocene. A high‐resolution age model was reconstructed by coupling 26 radiocarbon ages and high‐resolution relative paleointensity and paleosecular variation of the geomagnetic field records for the last 60 kyr. We show the variation of the geomagnetic field at high latitudes, pointing out variability during periods of regular paleosecular variation (normal polarity) as well as during the most recent geomagnetic excursions, and we provide a high‐resolution record of the Laschamps excursion. Cross‐cores correlation allowed us to outline major, climate‐rel...

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