Sediments

The European beaver Castor fiber is well-known as an ecosystem engineer that greatly affects landscape structure, biodiversity as well as physical and chemical properties of surface water bodies. Beaver ponds alter surface water bodies by raising water elevation, decreasing flow velocity and altering the morphology of streams or drainage ditches, which can reduce the concentrations of organic carbon (OC) and nutrients (N, P). Recent studies indicated that mercury transforms into hazardous and neurotoxic methylmercury (MeHg) in beaver impoundments by biological processes in anaerobic conditions. However, the knowledge about nutrients and MeHg levels in impounded forest waterbodies is scarce in Lithuania. We aimed to ascertain the alteration in concentrations and stocks of OC, nutrients and MeHg in water and sediments from upstream and downstream, as well as within beaver dams and ponds during the growing seasons of 2016–2018. Results showed higher concentrations of dissolved organic carbon (DOC) and nutrients (P and N) in upstream water samples compared to those of downstream from beaver dams. Meanwhile, in sediments mean stocks of OC, P and N were the highest in the middle part of the ponds and in beaver dams. Moreover, the concentrations and stocks of MeHg in sediments were higher in beaver dams than in any other parts of beaver impoundments (upstream, mid-pond, pond periphery and downstream). We conclude that dam bottom sediments were rich in OC, N and P, and at the same time, contained toxic MeHg. Therefore, beaver dams could act as a trickle filter by improving water quality, in our case, DOC, N and P leaching, from riparian forests and soils, but may also act as hotspots of mercury methylation.

Slit-check dams are widely employed in mountain river control. However an analysis of their performance in the field is still lacking. In the present work a field verification to evaluate the interaction between solid discharge regime and four slit-check dams built in two subcatchments of ...

Two high performance flow atomic absorption (HPF-AAS) related techniques were chosen to assess their suitability for the determination of several trace elements in complex environmental and biological samples. The technique selected were the Hydraulic High Pressure Nebulization Atomic Absorption Spectrometry (HHPN-AAS), and the Hydraulic High Pressure Nebulization Flame Furnace Atomic Absorption Spectrometry (HHPN-FF-AAS), which were applied directly, or after using off line liquid-liquid separation-preconcentration-back extraction procedures. Analytical methodologies were developed for Be, Sr, Ba, V, Cr, Mn, Fe, Co, Ni, Cu, Mo, Cd, Ag, Al, Tl, Pb, and Bi, for a variety of samples such as river and seawater, river and marine sediments, soft tissue of mussels, tunicate siphons, aquatic plants, and human samples of clinical interest such as placentas, umbilical cords, and cardiovascular tissues from surgical procedures. The analytical efficiency of the techniques was also proved in a proposed trace metal fractionation approach for river and seawater samples. All samples collected in this work were obtained from the North of Chile, where the most important economic activity is the mining industry.

Résumé Le fjord du Saguenay est un laboratoire géoscientifique naturel exceptionnel. Sa physiographie et ses caractéristiques géomorphologiques, révélées par les levés multifaisceaux et de sismique-réflexion ainsi qu’une série de carottages, nous fournissent un éclairage nouveau sur l’évolution du fjord du Saguenay à partir du début de la déglaciation du fjord, il y a environ 11 000 ans, ainsi que sur l’enregistrement des différentes catastrophes naturelles majeures qui se sont produites dans la région. De plus, à cause de sa morphologie, le fjord du Saguenay est aussi un endroit de prédilection pour l’analyse des changements climatiques dans cette région du continent nord-américain. À partir de l’analyse morpho-sédimentologique du fjord du Saguenay, nous proposons de le subdiviser en trois parties : le supérieur, le moyen et l’inférieur. Le Saguenay inférieur correspond à la zone comprise entre Tadoussac (kilomètre zéro), à une profondeur d’environ 20 m, et jusqu’à environ 42 km en...

Although weakly hydrophobic chemicals such as volatile organic compounds (VOCs) tend not to persist in sediments, they may nevertheless be present in some sediments because of recent or ongoing releases. Standard methods are not available for assessing risks to benthic invertebrates due to VOCs in sediment. More strongly hydrophobic organic chemicals are frequently assessed by using the equilibrium partitioning (EqP) approach, which predicts the bioavailable fraction of chemical (the concentration dissolved in pore water) from the sediment-sorbed fraction, assuming that partitioning is at equilibrium. As typically applied, the EqP approach is ineffective for assessing VOCs in sediment, because the standard EqP equation fails to account for the contribution of dissolved chemical to the total chemical concentration in sediment. For chemicals with low organic carbon-water partition coefficients (KOCs), this results in nonsensical sediment-quality benchmarks that are more conservative (i.e., lower) than benchmarks calculated by assuming 100% bioavailability. A modified EqP equation is presented that accounts for the dissolved fraction of total chemical concentrations in sediment. Results of the standard and modified EqP equations converge with increasing KOC and are essentially identical at log KOC values exceeding approximately 3.5.

A large number of hazardous compounds can be expected to be present in landfill leachates, many of which have not yet been identified. Thus this study screened samples from 12 Swedish municipal landfill sites for 400 parameters and compounds. More than 90 organic and metal organic compounds and 50 inorganic elements were detected, some of which seem to have not been detected before. Compounds detected include halogenated aliphatic compounds, benzene and alkylated benzenes, phenol and alkylated phenols, ethoxylates, polycyclic aromatic compounds, phthalic esters, chlorinated benzenes, chlorinated phenols, PCB, chlorinated dioxins and chlorinated furans, bromated flame-retardants, pesticides, organic tin, methyl mercury and heavy metals. The presence of this large number of hazardous compounds in landfill leachates should have a significant impact on future landfill risk assessments and the development of leachate treatment methods. We propose that future research should pay more atte...

Copyright © 2015 Khoshravan and Jabbari, This is an open access article published under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Preferred citation for this article:

River restoration practices aiming to sustain wild salmonid populations have received considerable attention in the Unites States and abroad, as cumulative anthropogenic impacts have caused fish population declines. An accurate representation of local depth and velocity in designs of spatially complex riffle-pool units is paramount for evaluating such practices, because these two variables constitute key instream habitat requirements and they can be used to predict channel stability. In this study, three models for predicting channel hydraulics—1D analytical, 1D numerical and 2D numerical—were compared for two theoretical spawning habitat rehabilitation (SHR) designs at two discharges to constrain the utility of these models for use in river restoration design evaluation. Hydraulic predictions from each method were used in the same physical habitat quality and sediment transport regime equations to determine how deviations propagated through those highly nonlinear functions to influence site assessments. The results showed that riffle-pool hydraulics, sediment transport regime and physical habitat quality were very poorly estimated using the 1D analytical method. The 1D and 2D numerical models did capture characteristic longitudinal profiles in cross-sectionally averaged variables. The deviation of both 1D approaches from the spatially distributed 2D model was found to be greatest at the low discharge for an oblique riffle crest with converging cross-stream flow vectors. As decision making for river rehabilitation is dependent on methods used to evaluate designs, this analysis provides managers with an awareness of the limitations used in developing designs and recommendations using the tested methods. Copyright © 2008 John Wiley & Sons, Ltd.

A review of the levels of polycyclic aromatic hydrocarbons (PAH) and tributyltin (TBT) in sediments from Mobile Bay, Alabama, shows that overall levels of PAH decrease from the upper bay (RI) to the lower bay (RIV). Analysis of PAH ratios indicate that pyrogenic sources such as fossil fuel combustion are dominant. There are so few data on TBT in sediments that spatial trends cannot be identified.Levels of PAHs in oyster tissues decrease from the upper bay (RI) to the lower bay (RIII). Although there is no significant temporal trend for PAH levels in bivalves for the US; in the bay, levels in Region II (RII) have decreased significantly and are currently below the national median. There is no trend in Region III (RIII), where levels remain below RII and the national median. RI and RIV had too few data for trend analysis.Mean levels of TBT in oyster tissues decrease from the upper bay (RI) to the lower bay (RIII). Temporal trend analysis indicates a significant decreasing trend for TBT in the US but no significant trend was detected for RII and RIII in Mobile Bay. TBT levels in RII are consistently higher than levels in the US and RIII, which are similar. Data from RI are too limited for analysis and there are no data for RIV.

The present study deals with quantification of accumulated toxic heavy metals in sediments of Mithi River of Mumbai. The study was performed at three different sampling locations along the flow of Mithi River for two years from 2009-12. The different heavy metals studied were Al, As, Cd, Cr, Hg, Ni, Pb, Sr and Mn. The results of our study indicate that the concentration level of these toxic heavy metals for the two assessment years increases by the factor of 1.2-5.8 µg/g. The result is a clear indication of day by day increasing pollution level of the Mithi River, which is creating negative environmental impact on biological life of the river. The results emphasises the need of regular scientific monitoring of different pollutants adversely affecting the environment and to reframe the pollution control strategies already in existence.

Oxygen and total dissolved inorganic carbon (DIC) fluxes at the water–sediment interface were measured using benthic chambers to assess the short-term variations of community respiration (CR) in the back reef sediments of Reunion Island (Indian Ocean). Benthic CR had a daily cycle of minimal (6:00 AM) and maximal values (6:00 PM), showing increases of oxygen and DIC fluxes of 2.8- and 3.8-fold, respectively. Average CR values were observed at midday and midnight. The evolution of fluxes was positively related to oxygen concentration in ambient water, but not to temperature changes. In the study area, high daytime primary production augments the amount of energy available for community metabolism and increases benthic respiration. The benthic communities are therefore subjected to short-term variable environmental conditions with oxygen supersaturation during the day, and moderately hypoxic conditions at the end of the night.

Emissions from combined sewer overflows have detrimental impact on water quality (Verbanck, 1990). Sewer sediments forming regularly increase emitting loads. One alternative to high pressure jetting, the mostly used method for sewer cleansing, is flushing. Many case studies and numerical investigations have already shown that flushing is able to erase sewer sediments if certain boundary conditions are respected. However, critics keep reminding that during the storage phase suspended solids will settle and form additive layers of sediments. In order to verify observations that such sediments will not last, measurements of velocity profiles were conducted. These profiles were transformed with the log-wall law into a times series of shear stress. This procedure was conducted with six different storage heights. Subsequently, these time series of bottom shear stress were applied to two different transport models. One transport model by Zanke (1999) bases on a probabilistic approach while the other by Torfs (1995) uses deterministic methods. The calculated transport rates and the probably distribution clearly show that the solids built up during the storage phase will not last. Also, it was demonstrated that the sunk wave generates sufficient shear stresses to remobilize these solids.