Heat Treatment Rumus
Heat Treatment Rumus
Heat Treatment Rumus
DISCLAIMER:
The formulas and information compiled in this text are provided without warranty of any kind.
Use them at your own risk!
A Non-Stop Work.
First Release: 04 April 2002
This Version: 15 April 2008
Gorni Steel Forming and Heat Treating Handbook 1
. Grange
Ae1 = 1333 − 25 Mn + 40 Si + 42 Cr − 26 Ni
Notation:
Ae1: Equilibrium Temperature for Austenitization Start [°F]
Alloy Content: [weight %]
Notation:
Ae3: Equilibrium Temperature for End of Austenitization [°F]
Alloy Content: [weight %]
. Andrews
Notation:
Ae1: Equilibrium Temperature of Austenitization Start [°C]
Alloy Content: [weight %]
Ae3 = 910 − 203 C + 44.7 Si − 15.2 Ni + 31.5 Mo + 104 V + 13,1 W − 30.0 Mn + 11.0 Cr + 20.0 Cu − 700 P − 400 Al −120 As −
− 400 Ti
Gorni Steel Forming and Heat Treating Handbook 2
Notation:
Ae3: Equilibrium Temperature for Austenitization End [°C]
Alloy Content: [weight %]
Notes:
- Both formulas are valid for low alloy steels with less than 0.6%C.
Source: ANDREWS, K.W. Empirical Formulae for the Calculation of Some Transformation Temperatures. Journal of the
Iron and Steel Institute, 203, Part 7, July 1965, 721-727.
. Roberts
Notation:
Ae3: Equilibrium Temperature for End of Austenitization [°C]
Alloy Content: [weight %]
Fn: value defined according to the table below:
C Fn
0.05 24
0.10 48
0.15 64
0.20 80
0.25 93
0.30 106
0.35 117
0.40 128
Gorni Steel Forming and Heat Treating Handbook 3
Source: ROBERTS, W.L.: Flat Processing of Steel; Marcel Dekker Inc., New York, 1988.
. Eldis
Notation:
Ae1: Equilibrium Temperature of Austenitization Start [°C]
Alloy Content: [weight %]
Notation:
Ac3: Equilibrium Temperature for End of Austenitization [°C]
Alloy Content: [weight %]
Notes:
- Both formulas were proposed by ELDIS for low alloy steels with less than 0.6%C.
Source: BARRALIS, J. & MAEDER, G. Métallurgie Tome I: Métallurgie Physique. Collection Scientifique ENSAM, 1982,
270 p.
. Park
Notation:
Gorni Steel Forming and Heat Treating Handbook 4
Notes:
- Formula specifically developed for TRIP steels.
Source: PARK, S.H. et al. Development of Ductile Ultra-High Strength Hot Rolled Steels. Posco Technical Report, 1996,
50-128.
Acm = 224.4 + 992.4 C − 465.1 C 2 + 46.7 Cr + 19.0 C Cr − 6.1 Cr 2 + 7.6 Mn + 10.0 Mo − 6.8 Cr Mo − 6.9 Ni + 3.7 C Ni − 2.7 Cr Ni +
+ 0.8 Ni 2 + 16.7 Si
Notation:
Acm: Austenitization Start Temperature [°C]
Alloy Content: [weight %]
Notes:
- Equation valid for the following alloy range: 0.2% ≤ C ≤ 0.7; Mn ≤ 1.5%; Si ≤ 0.3%; Ni ≤ 2.8%; Cr ≤ 1.5%; Mo ≤
0.6%.
Source: LEE, S.J. & LEE, Y.K. Thermodynamic Formula for the Acm Temperature of Low Alloy Steels. ISIJ International,
47:5, May 2007, 769-774.
Gorni Steel Forming and Heat Treating Handbook 5
. Boratto et al.
Tnr = 887 + 464 C + (6445 Nb − 644 Nb ) + (732 V − 230 V ) + 890 Ti + 363 Al − 357 Si
Notation:
Tnr: Temperature of No-Recrystallization [°C]
Alloy Content: [weight %]
Notes:
- Equation valid under the following alloy range: 0.04% ≤ C ≤ 0.17%; 0.41% ≤ Mn ≤ 1.90; 0.15% ≤ Si ≤ 0.50%;
0.002% ≤ Al ≤ 0.650; Nb ≤ 0.060%; V ≤ 0.120%; Ti ≤ 0.110%; Cr ≤ 0.67%; Ni ≤ 0.45.
Source: BORATTO, F. et al.: Effect of Chemical Composition on Critical Temperatures of Microalloyed Steels. In:
THERMEC ‘88. Proceedings. Iron and Steel Institute of Japan, Tokyo, 1988, p. 383-390.
Gorni Steel Forming and Heat Treating Handbook 6
. General
(a A ) m (a B ) n A
log =− +B
a Am Bn T
Notation:
AmBn: Precipitate Considered for Calculation
ax: Alloy Content [weight %]
T: Temperature [K]
A, B: Constants of the Solubility Product, given in the table below:
Precipitate A B Source
AlN 7060 1.55 Narita
AlN 6770 1.03
BN 13970 5.24 Fountain
Mo2C 7375 5.00
NbC 7900 3.42 Narita
NbC 7290 3.04 Meyer
NbC0.87 7520 3.11
NbC0.87 7700 3.18 Mori
NbN 8500 2.80 Narita
NbN 10230 4.04
Gorni Steel Forming and Heat Treating Handbook 7
Notes:
- aAmBn is equal to one if the precipitate is pure.
- aAmBn ≤ 1 if there is co-precipitation with another element.
Sources:
- IRVINE, K.J. et al. Grain-Refined C-Mn Steels. Journal of the Iron and Steel Institute, 205:2, Feb. 1967,
161-182.
- NARITA, K.et al. Physical Chemistry of Ti/Zr, V/Nb/Ta and Rare Elements in Steel. Transactions of the ISIJ,
15:5, May 1975, 145-51.
- FOUNTAIN, R. & CHIPMAN, J. Solubility and Precipitation of Vanadium Nitride in Alpha and Gamma Iron.
Transactions of the AIME, Dec. 1958, 737-739
- Values compiled by Rajindra Clement Ratnapuli or Fúlvio Siciliano from assorted references when not
specified above.
. Irvine
⎡ 12 ⎤ 6770
log[ Nb] ⎢C + N ⎥ = 2.26 −
⎣ 14 ⎦ T
Notation:
T: Temperature [K]
Gorni Steel Forming and Heat Treating Handbook 8
Source: IRVINE, K.J. et al. Grain-Refined C-Mn Steels. Journal of the Iron and Steel Institute, 205:2, Feb. 1967,
161-182.
. Mori
10400
log [ Nb] [ N ]0.65 [C ]0.24 = 4.09 −
T
Notation:
T: Temperature [K]
Alloy Content: [weight %]
. Siciliano
Notation:
T: Temperature [K]
Alloy Content: [weight %]
Source: SICILIANO JR., F..: Mathematical Modeling of the Hot Strip Rolling of Nb Microalloyed Steels. Ph.D. Thesis,
McGill University, February 1999, 165 p.
Gorni Steel Forming and Heat Treating Handbook 9
. Dong
Notation:
T: Temperature [K]
Alloy Content: [weight %]
Source: DONG, J.X. et al.: Effect of Silicon on the Kinetics of Nb(C,N) Precipitation during the Hot Working of Nb-bearing
Steels. ISIJ International, 40:6, June 2000, 613-618.
Gorni Steel Forming and Heat Treating Handbook 10
A
Td ( 0 C ) = − 273
B − Log (a A ) m (a B ) n
Notation:
AmBn: Precipitate Considered for Calculation
Td: Solubilization Temperature [K]
ax: Alloy Content [weight %]
A, B: Constants of the Solubility Product, given in the table at the topic Austenite Solubilization Products.
Gorni Steel Forming and Heat Treating Handbook 11
. Blás
Notation:
Ar3: Start Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Amount: [weight %]
v: Cooling Rate [°C/s]
Notes:
- This formula was determined using temperature data got from samples cooled directly from hot rolling
experiments. Thus it includes the effects of hot forming over austenite decomposition.
- Useful range: 0.024-0.068% C, 0.27-0.39% Mn, 0.004-0.054% Al, 0.000-0.094% Nb, 0.0019-0.0072% N, 1.0-
35°C/s
- r = 0.934; Standard Error of Deviation = 5°C
Source: BLÁS, J.G. et al.: Influência da Composição Química e da Velocidade de Resfriamento sobre o Ponto Ar3 em Aços
de Baixo C Microligados ao Nb. In: Congresso Anual da Associação Brasileira de Metais, ABM, São Paulo,
Out. 1989, vol. 1, p 11-29.
. Choquet
Notation:
Ar3: Start Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Amount: [weight %]
Gorni Steel Forming and Heat Treating Handbook 12
Notes:
- This formula was determined using data got from samples cooled directly from hot rolling experiments. Thus it
includes the effects of hot forming over austenite decomposition.
Source: CHOQUET, P. et al.: Mathematical Model for Predictions of Austenite and Ferrite Microstructures in Hot Rolling
Processes. IRSID Report, St. Germain-en-Laye, 1985. 7 p.
. Unknown #1
Notation:
Ar3: Start Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Content: [weight %]
Notation:
Ar1: Final Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Content: [weight %]
Notes:
- It is unknown the previous conditioning of the steel samples that supplied data for the deduction of this
formula.
- Samples cooled at 20°C/s.
Source: Unknown.
Gorni Steel Forming and Heat Treating Handbook 13
. Unknown #2
Notation:
Ar3: Start Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Content: [weight %]
Notes:
- It is unknown the previous conditioning of the steel samples that supplied data for the deduction of this
formula.
Source: Unknown.
. Ouchi
Notation:
Ar3: Start Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Content: [weight %]
h: Plate Thickness [mm]
Notes:
- This formula was determined using temperature data got from samples cooled directly from hot rolling
experiments. Thus it includes the effects of hot forming over austenite decomposition.
Source: OUCHI, C. et al. The Effect of Hot Rolling Condition and Chemical Composition on the Onset Temperature of
Gamma-Alpha Transformation After Hot Rolling. Transactions of the ISIJ, March 1982, 214-222.
Gorni Steel Forming and Heat Treating Handbook 14
. Shiga
Notation:
Ar3: Start Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Content: [weight %]
Notes:
- This formula was determined using temperature data got from samples cooled directly from hot rolling
experiments. Thus it includes the effects of hot forming over austenite decomposition.
Source: SHIGA, C. et al.: Development of Large Diameter High Strength Line Pipes for Low Temperature Use. Kawasaki
Steel Technical Report, Dec. 1981, 97-109.
. Pickering
Notation:
Ar3: Start Temperature of the Transformation Austenite → Ferrite [°C]
Alloy Content: [weight %]
Notes:
- Applicable to Plain C Steels.
Gorni Steel Forming and Heat Treating Handbook 15
Source: PICKERING, F.B.: Steels: Metallurgical Principles. In: Encyclopedia of Materials Science and Engineering,
vol. 6, The MIT Press, Cambridge, 1986.
Bs = 830 − 270 C − 90 Mn − 37 Ni − 70 Cr − 83 Mo
B50 = Bs − 50
B100 = Bs − 120
Notation:
Bs: Start Temperature of the Bainitic Transformation [°C]
Alloy Amount: [% em peso]
Bx: Temperature Required for the Formation of x% of Bainite [°C]
Source: STEVEN, W. & HAYNES, A.G. The Temperature of Formation of Martensite and
Bainite in Low Alloy Steels. Journal of the Iron and Steel Institute, 183, 1956, 349-359.
. Suehiro
Notation:
Bs: Start Temperature of the Bainitic Transformation [°F]
Alloy Amount: [weight %]
Gorni Steel Forming and Heat Treating Handbook 16
Source: SUEHIRO, M. et al. Kinetic Model for Phase Transformation of Low C Steel during Continuous Cooling. Tetsu-to-
Hagané, 73, 1987, 1026-1033.
. Kirkaldy
Bs = 656 − 58 C − 35 Mn − 75 Si − 15 Ni − 34 Cr − 41 Mo
Notation:
Bs: Start Temperature of the Bainitic Transformation [°F]
Alloy Amount: [weight %]
Source: KIRKALDY, J.S. et al. Prediction of Microstructure and Hardenability in Low Alloy Steels. In: Phase
Transformations in Ferrous Alloys, AIME, Warrendale, 1983, 125-148.
. Lee
Notation:
Bs: Start Temperature of the Bainitic Transformation [K]
Alloy Amount: [weight %]
Notes:
- Formula specifically developed for TRIP steels.
Source: LEE, J.K. et al. Prediction of Tensile Deformation Behaviour of Formable Hot Rolled Steels. Posco Technical
Research Laboratories Report, Pohang, 1999.
Gorni Steel Forming and Heat Treating Handbook 17
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Amount: [% em peso]
M s = 561 − 474 C − 33 Mn − 17 Cr − 17 Ni − 21 Mo
M 10 = Ms − 18
M 50 = Ms − 85
M 90 = Ms − 185
M 100 = Ms − 387
Notation:
Mx: Temperature Required for the Formation of x% of Martensite [°F]
Source: STEVEN, W. & HAYNES, A.G. The Temperature of Formation of Martensite and
Bainite in Low Alloy Steels. Journal of the Iron and Steel Institute, 183, 1956, 349-359.
Gorni Steel Forming and Heat Treating Handbook 18
. Andrews
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Content: [weight %]
Notes:
- Formula valid for low alloy steels with less than 0.6%C, 4.9% Mn, 5.0% Cr, 5.0% Ni and 5.4% Mo.
Source: ANDREWS, K.W. Empirical Formulae for the Calculation of Some Transformation Temperatures. Journal of the
Iron and Steel Institute, 203, Part 7, July 1965, 721-727.
. Eldis
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Content: [weight %]
Notes:
- Equation valid for steels with chemical composition between the following limits: 0.1~0.8% C; 0.35~1.80% Mn;
<1.50% Si; <0.90% Mo; <1.50% Cr; <4.50% Ni .
Gorni Steel Forming and Heat Treating Handbook 19
Source: BARRALIS, J. & MAEDER, G. Métallurgie Tome I: Métallurgie Physique. Collection Scientifique ENSAM, 1982,
270 p.
. Krauss
M s = 561 − 474 C − 33 Mn − 17 Cr − 17 Ni − 21 Mo
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Amount: [weight %]
Source: KRAUSS, G. Principles of Heat Treatment and Processing of Steels, ASM International, 1990, p. 43-87.
. Sverdlin-Ness
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Amount: [weight %]
Source: SVERDLIN, A.V. & NESS, A.R. The Effects of Alloying Elements on the Heat Treatment of Steel. In: Steel Heat
Treatment Handbook, Marcel Dekker, New York, 1997, p. 45-91.
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Amount: [weight %]
Source: PAYSON, P. & SAVAGE, C.H. Transactions A.S.M., 33, 1944, 261.
. Carapella
M s = 496 (1 − 0.62 C ) (1 − 0.092 Mn) (1 − 0.033 Si ) (1 − 0.045 Ni ) (1 − 0.07 Cr ) (1 − 0.029 Mo) (1 − 0.018 W ) (1 − 0.012 Co)
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Amount: [weight %]
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Amount: [weight %]
Source: GRANGE, R.A. & STEWART, H.M. Transactions of the AIME, 167, 1946, 467.
Gorni Steel Forming and Heat Treating Handbook 21
. Nehrenberg
Notation:
Ms: Start Temperature of the Martensitic Transformation [°C]
Alloy Amount: [weight %]
⎡ ⎛ Mn Mo Cr Si Ni ⎞ ⎤
Di = 6 × exp ⎢7.1 × ⎜ C + + + + + ⎟
⎣ ⎝ 5.87 3.13 6.28 18 15 ⎠ ⎥⎦
Notation:
Di: Critical Diameter [mm]
Alloy Content: [weight %]
Source: DEARDEN, J & O’NEIL, H.: A Guide to the Selection and Welding of Low Alloy Structural Steels. Transactions
of the Institute of Welding, 3, Oct. 1940, 203-214.
Gorni Steel Forming and Heat Treating Handbook 23
- Density
. Austenitic Steels
1
ργ =
(1.231 Fe + 3.178 C sol + 1.307 Mn + 2.436 Si + 1.431 Cr + 1.205 Cu + 1.018 Mo + 1.137 Ni + 1.890 Ti + 1.111 Co + 2.186 N + 2.032 TiC ) . 10 − 6
Notation:
ργ: Austenite Density [kg/m³]
Alloy/TiC Content: [weight %]
Notes:
- Csol is the content of this element not bound in TiC.
- Density calculated at 20°C.
Source: BOHNENKAMP, U. et al.: Evaluation of the Density of Steels. Steel Research, 71:3, March 2000, 88-93.
. Ferritic Steels
1
ρα =
(1.270 Fe + 1.380 C + 1.524 Mn + 2.381 Si + 1.384 Cr + 0.8477 Cu + 1.076 Mo + 1.370 Ni + 2.012 V + 4.046 S ) . 10 −6
Notation:
ρα: Steel Density [kg/m³]
Alloy Content: [weight %]
Notes:
- C is considered insoluble in ferrite (that is, all C has gone to cementite).
- The solubilities of the other alloy elements in cementite are zero.
Gorni Steel Forming and Heat Treating Handbook 24
Source: BOHNENKAMP, U. et al.: Evaluation of the Density of Steels. Steel Research, 71:3, March 2000, 88-93.
. Liquid Iron
0.7
⎛ T ⎞
−⎜ 1 − ⎟
ρ Liquid Iron = 1.99446 × 0.22457 ⎝ 9340 ⎠
Notation:
ρLiquid Iron: Liquid Iron Density [g/ml]
T: Absolute Temperature, [K]
Source: YAWS, C.L.: Liquid Density of the Elements. Chemical Engineering, November 2007, 44-46.
Source: THELNING, K.E.: Steel and its Heat Treatment – Bofors Handbook. Butterworths, London, 1981, 570 p.
. Temperature Effect
ρ γT = ρ γ20°C − 0.47 T
Notation:
ραT: Ferrite Density at Temperature T [kg/m³]
ρα20°C: Ferrite Density at 20°C [kg/m³]
ργT: Austenite Density at Temperature T [kg/m³]
ργ20°C: Austenite Density at 20°C [kg/m³]
T: Temperature[°C]
Source: FINK, K. et al.: Physikalische Eigenschaften von Stählen, insbesondere von warmfesten Stählen.
Thyssenforschung, 2:2, 1970, 65-80.
Gorni Steel Forming and Heat Treating Handbook 26
Transformation ∆V ∆l
[%] [mm/mm]
Spheroidized Pearlite → Austenite -4.64 + 2.21 C -0.0155 + 0.0074 C
Austenite → Martensite 4.64 – 0.53 C 0.0155 – 0.0018 C
Spheroidized Pearlite → Martensite 1.68 C 0.0056 C
Austenite → Lower Bainite 4.64 – 1.43 C 0.0155 – 0.0048 C
Spheroidized Pearlite → Lower Bainite 0.78 C 0.0026 C
Austenite → Upper Bainite 4.14 – 2.21 C 0.0155 – 0.0074 C
Spheroidized Pearlite → Upper Bainite 0 (Zero) 0
Notation:
- C: Carbon Content [weight %].
Sources:
- THELNING, K.E.: Steel and its Heat Treatment – Bofors Handbook. Butterworths, London, 1981, 570 p.
- KRAUSS, G. Steel: Processing, Structure and Performance. ASM International, Metals Park, 2005, 420 p.
. After Quenching
∆V ⎛ 100 − VC − V A ⎞ V
=⎜ ⎟ 1.68 C M + A (−4.64 + 2.21 C A )
V ⎝ 100 ⎠ 100
Notation:
- ∆V/V: Volumetric Change after Quenching [%]
Gorni Steel Forming and Heat Treating Handbook 27
Source: THELNING, K.E.: Steel and its Heat Treatment – Bofors Handbook. Butterworths, London, 1981, 570 p.
Gorni Steel Forming and Heat Treating Handbook 28
Mn Mo Cr +V Cu Ni P
C EQ _ Dearden = C + + + + + +
6 4 5 13 15 2
Notation:
CEQ_Dearden: Equivalent Carbon (Dearden) [%]
Alloy Content: [weight %]
Source: DEARDEN, J & O’NEIL, H.: A Guide to the Selection and Welding of Low Alloy Structural Steels. Transactions
of the Institute of Welding, 3, Oct. 1940, 203-214.
Mn Cr + Mo+V Cu + Ni
C EQ _ IIW = C + + +
6 5 15
Notation:
CEQ_IIW: Equivalent Carbon (IIW) [%]
Alloy Content: [weight %]
Source: HEISTERKAMP, F. et al.: Metallurgical Concept And Full-Scale Testing of High Toughness, H2S Resistant 0.03%C
- 0.10%Nb Steel. C.B.M.M. Report, São Paulo, February 1993.
. Bastien
Gorni Steel Forming and Heat Treating Handbook 29
Mn Mo Cr Ni
C EQ _ Bastien = C + + + +
4,4 7,7 15,4 10,3
Notation:
CEQ_Bastien: Equivalent Carbon (Bastien) [%]
Alloy Content: [weight %]
CRm: Critical Cooling Rate at 700°C [°C/s], that is, minimum cooling rate that produces a fully martensitic
structure)
Source: BASTIEN, P.G.: Met. Constr. British Weld. J., 49, 1970, 9.
. Yurioka et al.
Mn Mo Cr Ni Si Cu
C EQ _ Yurioka = C + + + + + +
6 4 8 12 24 15
Notation:
CEQ_Yurioka: Equivalent Carbon (Yurioka) [%]
Alloy Content: [weight %]
tm: Critical Cooling Time from 800 to 500°C [s] (that is, maximum cooling time that produces a fully martensitic
structure)
. Kihara et al.
Mn Mo Cr V Ni Si
C EQ _ Kihara = C + + + + + +
6 4 5 14 40 24
Notation:
CEQ_Kihara: Equivalent Carbon (Kihara) [%]
Alloy Content: [weight %]
. Shinozaki et al.
Mn Si Cr V (50 C − 1) Mo (1 − 6 C )
C EQ _ FBW = C + + + + 7 Nb (1 − 10C ) + + 1.3 Ti (1 − 5 C ) + + 29 B (11 C − 1)
5 15 9 3 2
Notation:
CEQ_FBW: Equivalent Carbon Designed Specifically for Flash Butt Welding [%]
Alloy Content: [weight %]
Source: SHINOZAKI, M. et al.: Effects of Chemical Composition and Structure of Hot Rolled High Strength Steel Sheets on
the Formability of Flash Butt Welded Joints. Kawasaki Steel Technical Report, 6, Sept. 1982, 21-30.
. Stout et al.
⎛ Mn Cr + Mo Ni Cu ⎞
C EQ _ Stout = 1000 C ⎜ + + + ⎟
⎝ 6 10 20 40 ⎠
Gorni Steel Forming and Heat Treating Handbook 31
Notation:
CEQ_Stout: Equivalent Carbon (Kihara) [%]
Alloy Content: [weight %]
Source: STOUT, R.D. et al. Welding Journal Research Supplement, 55, 1976, 89s-94s.
Gorni Steel Forming and Heat Treating Handbook 32
. DNV
Mn Si Ni + Cu Cr V Mo
C EQ _ DNV = C + + + + + +
10 24 40 5 10 4
Notation:
CEQ_DNV: Equivalent Carbon (DNV) [%]
Alloy Content: [weight %]
Source: HANNERZ, N.E.: The Influence of Si on the Weldability of Mild and High Tensile Structural Steels. IIW
Document IX-1169-80, 1980.
Mn Cu Ni Cr Mo
C EQ _ Uwer = C + + + + +
10 20 40 20 10
Notation:
CEQ_Uwer: Equivalent Carbon (Uwer & Hohne) [%]
Alloy Content: [weight %]
Source: UWER, D. & HOHNE, H.: Determination of Suitable Minimum Preheating Temperature for the Cold-Crack-Free
Welding of Steels. IIW Document IX-1631-91, 1991.
. Mannesmann
Gorni Steel Forming and Heat Treating Handbook 33
Si Mn+Cu Cr Ni Mo V
C EQ _ PLS = C + + + + + +
25 16 20 60 40 15
Notation:
CEQ_PLS: Equivalent Carbon for Pipeline Steels [%]
Alloy Content: [weight %]
Notes:
- Formula deduced for pipeline steels
- A version of this formula divides V by 10
Sources:
- DUREN, C. & NIEDEROFF, K.: In: Proc. on Welding and Performance of Pipeline, TWI, London, 1986.
- HEISTERKAMP, F. et al.: Metallurgical Concept And Full-Scale Testing of High Toughness, H2S Resistant
0.03%C - 0.10%Nb Steel. C.B.M.M. Report, São Paulo, February 1993.
. Graville
Mn Ni Cr Mo Nb V
C EQ _ HSLA = C + − + + + +
16 50 23 7 5 9
Notation:
CEQ_HSLA: Equivalent Carbon (Uwer & Graville) [%]
Alloy Content: [weight %]
Notes:
- Formula deduced for pipeline steels
Source: GRAVILLE, B.A.: In: Proc. Conf. on Welding of HSLA Structural Steels, ASM, Materials Park, 1976.
Gorni Steel Forming and Heat Treating Handbook 34
Mn + Si + Cr + Mo + V + Cu + Ni
C EQ _ Bersch = C +
20
Notation:
CEQ_Bersch: Equivalent Carbon for Pipeline Steels [%]
Alloy Content: [weight %]
Notes:
- Formula deduced for pipeline steels
Source:
- BERSCH, B. et al. Weldability of Pipe Steels for Low Operating Temperatures. 3R International, 1, 1977.
- PATCHETT, B.M. et al.: Casti Metals Blue Book: Welding Filler Metals. Casti Publishing Corp., Edmonton,
February 1993, 608 p. (CD Edition).
Si Mn + Cu + Cr Ni Mo V
Pcm = C + + + + + +5B
30 20 60 15 10
Notation:
Pcm: Cracking Parameter [%]
Alloy Content: [weight %]
Notes:
- Formula deduced for pipeline steels with C < 0.15%
Gorni Steel Forming and Heat Treating Handbook 35
Source:
- ITO, Y. et al.: Journal of the Japan Welding Society., 37, 1968, 983.
- ITO, Y. & BESSYO, K. Weldability Formula of High Strength Steels Related to Heat-Affected-Zone Cracking. The
Sumitomo Search, 1, 1969, 59-70.
Si Mn + Cu + Cr Mo V d H
Pc = C + + + + + +
30 20 15 10 600 60
Notation:
Pc: Cracking Parameter [%]
Alloy Content: [weight %], except
H: Hydrogen amount in the weld metal, [cm³/100 g]
d: Plate Thickness, [mm]
Source: ITO, Y. & BESSYO, K.: Weldability Formula of High Strength Steels. I.I.W. Document IX-576-68.
. Yurioka
⎛ Mn Si Cr + Mo + V Cu Ni Nb ⎞
C EQ _ Yurioka = C + A(C ) ⎜ + + + + + + 5 B⎟
⎝ 6 24 5 15 20 5 ⎠
Gorni Steel Forming and Heat Treating Handbook 36
Notation:
CEQ_Yurioka: Equivalent Carbon for Pipeline Steels [%]
Alloy Content: [weight %]
Notes:
- Formula for C-Mn and microalloyed pipeline steels
- This formula combines Carbon Equivalent equations from IIW and Pcm
Sources:
- YURIOKA, N.: Physical Metallurgy of Steel Weldability. ISIJ International, 41:6, June 2001, 566-570.
- PATCHETT, B.M. et al.: Casti Metals Blue Book: Welding Filler Metals. Casti Publishing Corp., Edmonton,
February 1993, 608 p. (CD Edition).
Gorni Steel Forming and Heat Treating Handbook 37
- Fe-C Diagram
. General
(a A ) m (a B ) n A
log10 =− +B
a Am Bn T
Notation:
AmBn: Precipitate Considered for Calculation
ax: Alloy Content [weight %]
T: Temperature [K]
A, B: Constants of the Solubility Product, given in the table below:
Precipitate A B Source
AlN 9595 2.65 Kunze & Reichert
BN 13560 4.53 Fountain & Chipman
MnS 8400 2.77 Ivanov
NbC 10990 4.62 Kunze
NbN 10650 3.87 Kunze
TiN 17640 6.17 Kunze
VC 12265 8.05 Taylor
VN 7830 2.45 Froberg
VN 8120 2.48 Roberts & Sandbert
ZrN 18160 5.24 Kunze
Gorni Steel Forming and Heat Treating Handbook 39
Notes:
- aAmBn is equal to one if the precipitate is pure.
- aAmBn ≤ 1 if there is co-precipitation with another element.
Source:
- TAYLOR, K.A. et al. Scripta Metallurgica, 32, 1995, 7.
- FROBERG, M.G. & GRAF, H. Stahl und Eisen, 80, 1960, 539.
- KUNZE, J. Nitrogen and Carbon in Iron and Steels – Thermodynamics. Akademie Verlag, Berlin, 1991, p.
192.
- FOUNTAIN, R.W. & CHIPMAN, J. In: Transactions of the Metallurgical Society of AIME, 224, 1964, 599.
- ROBERTS, W. & SANDBERG, A. Report IM 1489. Institute for Metallurgical Research, Stockholm, 1990.
. Lorenz et al.
⎡ ⎛ Si Mn Cu Cr Ni Mo V ⎞⎤
HV = 2019 ⎢ C (1 − 0.5 log t 8 / 5 ) + 0.3 ⎜ + + + + + + ⎟⎥ + 66 (1 − 0.8 log t 8 / 5 )
⎣ ⎝ 11 8 9 5 17 6 3 ⎠⎦
Source: LORENZ, K. et al.: Evaluation of Large Diameter Pipe Steel Weldability by Means of the Carbon Equivalent. In:
International Conference on Steels for Linepipe and Fittings, Metals Society, London, Oct. 1981, 322-332.
Notation:
HV: Maximum Hardness for a Martensitic-Bainitic HAZ Microstructure [Vickers, 10 kg Load]
Alloy Content: [weight %]
t8/5: Cooling Time Between 800°C and 500°C [s]
Gorni Steel Forming and Heat Treating Handbook 41
. Spies
Notation:
HB: Brinell Hardness After Hardening and Tempering
HRC: Rockwell Hardness (C Scale) After Hardening
Alloy Content: [weight %]
T: Tempering Temperature [°C]
Notes:
- This equation is valid within the following ranges: HRC: 20~65; C: 0.20~0.54%; Mn: 0.50~1,90%; Si:
0.17~1.40%; Cr: 0.03~1.20%; T: 500~650°C.
Source: SPIES, H.J. et al.: Möglichkeiten der Optimierung der Auswahl vergütbarer Baustähle durch
Berechnung der Härt-und-vergütbarkeit. Neue Hütte, 8:22, 1977, 443-445.
Gorni Steel Forming and Heat Treating Handbook 42
Mn Mo Cr +V Cu Ni P
C EQ _ Dearden = C + + + + + +
6 4 5 13 15 2
Notation:
CEQ_Dearden: Equivalent Carbon (Dearden) [%]
Alloy Content: [weight %]
HVmax = Maximum Hardness [Vickers]
Notes:
- This equation calculates maximum hardness after welding.
Source: DEARDEN, J & O’NEIL, H.: Trans. Int. Weld., 3, 1940, 203.
. Shinozaki et al.
HV = 78 + 331 C EQ _ FBW
Mn Si Cr V (50 C − 1) Mo (1 − 6 C )
C EQ _ FBW = C + + + + 7 Nb (1 − 10C ) + + 1.3 Ti (1 − 5 C ) + + 29 B (11 C − 1)
5 15 9 3 2
Notation:
CEQ_FBW: Equivalent Carbon Designed Specifically for Flash Butt Welding [%]
Alloy Content: [weight %]
Gorni Steel Forming and Heat Treating Handbook 43
Source: SHINOZAKI, M. et al.: Effects of Chemical Composition and Structure of Hot Rolled High Strength Steel Sheets on
the Formability of Flash Butt Welded Joints. Kawasaki Steel Technical Report, 6, Sept. 1982, 21-30.
Gorni Steel Forming and Heat Treating Handbook 44
. Tselikov
Notation:
E: Young Modulus [kgf/cm²]
C: C content [weight %]
Mn: Mn content [weight %]
Si: Si content [weight %]
P: P content [weight %]
S: S content [weight %]
T: Temperature [°C]
Note:
- Valid for carbon, alloy and stainless steels between 20 and 900°C.
Source: ROYZMAN, S.E. Thermal Stresses in Slab Solidification. Asia Steel, 1996, 158-162.
. Misaka
⎡
σ = exp ⎢0.126 − 1.75 C + 0.594 C 2 +
( )
2851 + 2968 C − 1120 C 2 ⎤ 0, 21 ⎛ dε ⎞
0 ,13
⎥ε ⎜ ⎟
⎣ T ⎦ ⎝ dt ⎠
Notation:
σ: Steel Hot Strength [kgf/mm²]
C: C content [weight %]
T: Absolute Temperature [K]
Gorni Steel Forming and Heat Treating Handbook 45
ε: True Strain
t: Time [s]
Source: MISAKA, Y. et al. Formulatization of Mean Resistance to Deformation of Plain C Steels at Elevated Temperature.
Journal of the Japan Society for the Technology of Plasticity, 8, 79, 1967-1968, 414-422.
. Shida
End Function
Notation:
σ: Steel Hot Strength [kgf/mm²]
C: C content [weight %]
T: Temperature [°C]
Def: True Strain
VelDef: Strain Rate [s-1]
Source: SHIDA, S. Empirical Formula of Flow Stress of C Steels - Resistance to Deformation of C Steels at Elevated
Temperature. Journal of the Japan Society for Technology of Plasticity, 10:103, 1969, 610-7.
Gorni Steel Forming and Heat Treating Handbook 47
. General
(a A ) m (a B ) n A
log =− +B
a Am Bn T
Notation:
AmBn: Precipitate Considered for Calculation
ax: Alloy Content [weight %]
T: Temperature [K]
A, B: Constants of the Solubility Product, given in the table below:
Precipitate A B Source
MnS 8236 5.03
TiN 16586 5.90
TiS 8000 4.00
ZrN 17000 6.38
Notes:
- aAmBn is equal to one if the precipitate is pure.
- aAmBn ≤ 1 if there is co-precipitation with another element.
Sources:
- Values compiled by Rajindra Clement Ratnapuli from assorted references.
Gorni Steel Forming and Heat Treating Handbook 48
Notation:
TLíq: Steel Melting Temperature [°C]
Alloy Content: [weight %]
Source: GUTHMANN, K. Günstige Giesstemperatur im Vergleich zum Erstarrungspunkt von Eisen- und Stahlschmelzen.
Stahl und Eisen, 71(1951), 8, 399-402.
Gorni Steel Forming and Heat Treating Handbook 49
- Poisson Ratio
E = 2 G (1 + υ )
Notation:
E: Young Modulus
G: Shear Modulus
υ: Poisson Ratio
. Elastic Range: 0.3
. Plastic Range: 0.5
Sources:
- WILSON, A.D. Guidelines for Fabricating and Processing Plate Steel. Bethlehem-Lukens Plate Report, Burns
Harbor, 2000, 97 p.
Gorni Steel Forming and Heat Treating Handbook 50
r02
t=
2c D
Notation:
AmBn: Spheric Precipitate Considered for Calculation
r0: radius of the precipitate [m], [cm] or [mm]
Ci − C m Ci
c= ≅
C p − Ci C p
⎛ −A ⎞
⎜ + B⎟
⎝ T ⎠
10
Ci =
aB
T: Temperature [K]
A, B: Constants of the Solubility Product, given in the table at the topic Austenite Solubilization Products.
AB: Alloy content [weight percent]
Cp: Solute content in the precipitate [%]
m MA
Cp =
m MA + n MB
Notes:
- R = 1.981 cal/mol.K
- R1 = 8.314 J/mol.K
Source: Formulas and values compiled by Rajindra Clement Ratnapuli from assorted references.
Gorni Steel Forming and Heat Treating Handbook 53
TSol = 1536 − [415,5 C + 12,3 Si + 6,8 Mn + 124,5 P + 183,9 S + 4,3 Ni + 1,4 Cr + 4,1 Al ]
Notation:
TSol: Steel Solidus Temperature [°C]
Alloy Content: [weight %]
Source: TAKEUCHI, E. & BRIMACOMBE, J.K. Effect of Oscillation-Mark Formation on the Surface Quality of
Continuously Cast Steel Slabs. Metallurgical Transactions B, 16B, 9, 1985, 605-25.
Gorni Steel Forming and Heat Treating Handbook 54
17.4
YS = 53.9 + 32.3 Mn + 83.2 Si + 354.2 N sol +
d
7.7
TS = 294.1 + 27.7 Mn + 83.2 Si + 2.85 Pearl +
d
dσ 15.4
= 370 + 120 C + 23.1 Mn + 116 Si + 554 P + 143 Sn + 1509 N sol +
dε d
0.017
ε tot = 1.40 − 2.90 C + 0.20 Mn + 0.16 Si − 2.2 S − 3.9 P + 0.25 Sn +
d
11.5
50% ITT = − 19 + 44 Si + 700 N sol + 2.2 Pearl −
d
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
TS: Tensile Strength [MPa]
dσ/dε: Strain Hardening Coefficient at 0.2% Real Strain [1/MPa]
εunif: Uniform Elongation, Expressed as Real (Logarithmic) Strain
Gorni Steel Forming and Heat Treating Handbook 55
Source: PICKERING, F.B.: Physical Metallurgy and the Design of Steels. Allied Science Publishers, London, 1978,
275 p.
d = 11.5 − 2.2 (6 C + Mn + 30 P + 35 S + 23 Al + 0.01 (723 − Tcoil ) + 0.01 etot − 0.002 T fin − 100 N sol )
C eq − 0.06
Pearl = α 100
0.78
0.1
S0 =
723 − Tcoil
0.12
ε = 100 (0.000096 Pearl S 0 − 0.05 Mn − 4.23 P − 4.36 S + 2.37 Sn − 1.16 N sol + + 0.0006 T fin )
d
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
TS: Tensile Strength [MPa]
ε: Total Elongation [%]
d: Ferrite Grain Size [µm]
Alloy Content: [weight %]
Tcoil: Coiling Temperature [°C]
etot: Total Hot Rolling Conventional Strain [%]
Tfin: Finishing Temperature [°C]
Nsol: Solubilized (Free) Nitrogen [%]
Pearl: Pearlite Fraction Present in Microstructure [%]
S0: Pearlite Lamelar Spacing [mm]
Mn Si
C eq = C + + −S
6 24
T fin − Tcoil
α =
T fin
Notes:
- These equations are valid under the following conditions: Slab Reheating Temperature: 1250°C; Tfin:
850~880°C; Tcoil: 615~650°C; Final Thickness: 1.8~4.0 mm; C: 0.08~0.18%; Mn: 0.40~1.00%; P < 0.020%; S
< 0.020%; Si < 0.030%; Al: 0.020~0.050%; N: 0.0030~0.0090%.
Source: ARTIGAS, A. et al.: Prediction de Propiedades Mecánicas y Microestructurales em Aceros Laminados em Caliente.
Revista Metalurgica CENIM, 38, 2002, 339-347.
Gorni Steel Forming and Heat Treating Handbook 57
2.72
YS = 3.37 + YS = 28.16 − 154 d HR
d CR
0.01
n = 0.33 −
d CR
Notation:
dCR: Grain Size of Cold Rolled Strip [mm]
dHR: Grain Size of Hot Rolled Strip [mm]
YS: Yield Strength at 0.2% Real Strain [MPa]
εyield: Yield Elongation [%]
n: Strain Hardening Coefficient Measured during Tension Test
Notes:
- These equations are valid under the following conditions: C: 0.005~0,10%; Mn: 0.40%; P < 0.016%; S <
0.026%; Si < 0.010%; Al: < 0.040%; N: 0.0020~0.0040%.
- Cold rolled steel was box annealed at 700°C; the time of treatment, including heating of the samples, was
equal to 32 hours, being followed by furnace cooling.
Gorni Steel Forming and Heat Treating Handbook 58
Source: LANGENSCHEID, G. et al.: Untersuchungen über den Einfluβ der Korngröβe des Warmbandes auf die
Kaltbandeigenschaften. Hoesch Berichte aus Forschung und Entwicklung unserer Werke, 2, 1971, 64-70.
5
n=
1
10 +
d
Notation:
n: Strain Hardening Coefficient Measured during Tension Test
d: Grain Size [mm]
Source: MORRISON, W.: The Effect of Grain Size on the Stress-Strain-Relationship in Low-Carbon Steel. Transactions of
the ASM, 59, 1966, 824-845.
14.9
YS = 246 + 4.15 Pearl + 44.6 Mn + 138 Si + 923 P + 169 Sn + 3754 N sol +
d
44.6
TS = 492 − 3.38 Pearl + 246 Mn + 277 Si − 2616 S + 723 P + 246 Cr + 6616 N sol +
d
dσ 15.4
= 385 + 1.39 Pearl + 111 Si + 462 P + 152 Sn + 1369 N sol +
dε d
Gorni Steel Forming and Heat Treating Handbook 59
0.015
ε tot = 1,30 − 0.020 Pearl + 0.30 Mn + 0.20 Si − 3.4 S − 4.4 P + 0.29 Sn +
d
6.2
Ttrans = 43 + 1.5 Pearl − 37 Mn −
d
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
TS: Tensile Strength [MPa]
dσ/dε: Strain Hardening Coefficient at 0.2% Real Strain [1/MPa]
εunif: Uniform Elongation, Expressed as Real (Logarithmic) Strain
εtot: Total Elongation, Expressed as Real (Logarithmic) Strain
Pearl: Pearlite Fraction in Microstructure [%]
Ttrans: Fracture Appearance Transition Temperature [°C]
Alloy Content: [weight %]
d: Grain Size [mm]
Source: PICKERING, F.B.: The Effect of Composition and Microstructure on Ductility and Toughness; in: Towards
Improved Ductility and Toughness, Climax Molybdenum Company, Tokyo, 1971, p. 9-32
15.1
YS = σ 0 + 37 Mn + 83 Si + 2918 N sol + + ∆σ ppt
d
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
Gorni Steel Forming and Heat Treating Handbook 60
Notes:
- The Friction Stress σ0 value depends on the previous treatment of the material and can be found in the table
below:
Condition σ0
[MPa]
Mean 70
Air Cooled 88
Overaged 62
- The effect of solid solution strengthening from another alloy elements solubilized in ferrite can be included in
this equation, using the following linear coefficients:
Element MPa/weight %
Ni 33
Cr -30
P 680
Cu 38
Mo 11
Sn 120
C 5000
N 5000
5.9 f ⎛ x ⎞
∆σ ppt = ln ⎜⎜ ⎟
−4 ⎟
x ⎝ 2.5 × 10 ⎠
Notation:
∆σppt: Precipitation Strengthening According to the Ashby-Orowan Model [MPa]
f: Volume Fraction of the Precipitate
x: Mean Planar Intercept Diameter of the Precipitate [µm]
Notes:
- Relationship adequate for the calculation of the precipitation strengthening of quench-aged carbides and
precipitate carbonitrides in Nb, V and Ti steels.
- ∆σppt can be calculated using a more simplified approach, multiplying the total content of the precipitating
alloy by the factor B shown in the table below:
Source: PICKERING, F.B. Some Aspects of the Relationships between the Mechanical Properties of Steels and their
Microstructures. TISCO. Silver Jubilee Volume, Jan-Oct 1980, 105-132.
19.7
YS = 62.6 + 26.1 Mn + 60.2 Si + 759.0 P + 212.9 Cu + 3286.0 N sol + + ∆σ ppt
d
Gorni Steel Forming and Heat Treating Handbook 62
11.0
TS = 164.9 + 634.7 C + 53.6 Mn + 99.7 Si + 651.9 P + 472.6 Ni + 3339.4 N sol + + ∆σ ppt
d
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
TS: Tensile Strength [MPa]
Alloy Content: [weight %]
d: Grain Size [mm]
∆σppt: Precipitation Strengthening [MPa], only for steels with V [MPa]
CR: Cooling Rate [°C/s]
Source: HODGSON, P.D. & GIBBS, R.K. A Mathematical Model to Predict the Mechanical Properties of Hot Rolled C-Mn
and Microalloyed Steels. ISIJ International, 32:12, December 1992, 1329-1338.
419.5
YS = 41,4 + 575.20 C eq + (27401 N ef − 2) V +
hf
181.5
TS = 74.1 + 985.1 C eq + (31125 N ef − 39) V +
hf
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
TS: Tensile Strength [MPa]
Alloy Content: [weight %]
Gorni Steel Forming and Heat Treating Handbook 63
Mn Cr + Mo Ni + Cu
Ceq = C + + +
6 5 15
Ti
N ef = N tot −
3.42
Notes:
- Formula Derived for Steels with Al Content over 0.010% and Si Content between 0.25 and 0.35%.
- Precision of the Formulas: ± 40 MPa.
Source: MITCHELL, P.S. et al.: Effect of Vanadium on Mechanical Properties and Weldability of Structural Steels. In: Low
Carbon Steels for the 90’s. Proceedings. American Society for Metals/The Metallurgical Society, Pittsburgh,
Oct. 1993.
1
YS = 203 + 855
Lαα
1 fβ
TS = 266 + 548 + 1741
Lαα dβ
dσ 1 fβ
= 266 + 548 + 1741
dε Lαα dβ
Gorni Steel Forming and Heat Treating Handbook 64
1
ε unif = 32 − 64
Lαα
Notation:
LE: Yield Strength [MPa]
LR: Tensile Strength [MPa]
dσ/dε: Strain Hardening Coefficient at Uniform Elongation [1/MPa]
aunif: Uniform Elongation [%]
Lαα: Mean Ferritic Free Path [µm]
dβ: Mean Diameter of Martensite Islands [µm]
Sources:
- GORNI, A.A. & BRANCHINI, O.L.G. Análise da Evolução do Encruamento de um Aço Bifásico. In: 4° Simpósio
de Conformação Mecânica, EPUSP/UNICAMP/ABAL, São Paulo, Nov. 1990, 23-42.
- GORNI, A.A. & BRANCHINI, O.L.G. Relações Microestrutura-Propriedades Mecânicas em um Aço Bifásico
Laminado a Quente. In: 1º Seminário sobre Chapas Metálicas para a Indústria Automobilística, ABM/AEA,
São Paulo, Set. 1992, 127-145.
15.1
YS = 88 + 37 Mn + 83 Si + 2900 N sol + + σ disc + σ ppt
dL
11.5
ITT = − 19 + 44 Si + 700 N sol + 0.26 (σ disc + σ ppt ) −
d
Gorni Steel Forming and Heat Treating Handbook 65
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
TS: Tensile Strength [MPa]
ITT: Impact Transition Temperature for 50% Tough Fracture [°C]
Alloy Content: [weight %]
Nsol: Solubilized (Free) Nitrogen [%]
dL: BainiteFerrite Lath Size [mm]
σdisc: Strength Due to Dislocations [MPa]
σppt: Precipitation Strengthening According to the Ashby-Orowan Model [MPa]
Nsol: Solubilized (Free) Nitrogen [%]
d: Mean Spacing between High Angle Boundaries (“Packet” or Prior Austenite Grain Boundaries)
5.9 f ⎛ x ⎞
∆σ ppt = ln ⎜⎜ ⎟
−4 ⎟
x ⎝ 2.5 × 10 ⎠
Notation:
α: Empirical Constant
µ: Shear Modulus [MPa]
b: Burger’s Vector [cm]
ρ: Dislocation Density [lines/cm²]
f: Volume Fraction of the Precipitate
x: Mean Planar Intercept Diameter of the Precipitate [µm]
Sources:
- PICKERING, F.B. Some Aspects of the Relationships between the Mechanical Properties of Steels and their
Microstructures. TISCO. Silver Jubilee Volume, Jan-Oct 1980, 105-132.
Gorni Steel Forming and Heat Treating Handbook 66
- KEH, A.S., Work Hardening and Deformation Sub-Structure in Iron Single Crystals in Tension at 298K,
Philosophical Magazine, 12:115, 1965, 9-30.
. Medium C Steels
⎛ ⎞
⎛
YS = 3 f α ⎜⎜ 35 + 58 Mn +
17.4 ⎞
⎟⎟ + 1 − ( 3 )
f α ⎜178 +
⎜
3.8 ⎟ + 63 Si + 42 N sol
⎟
⎝ d ⎠ ⎝ S0 ⎠
⎛ ⎞
⎛
TS = 3 f α ⎜⎜ 246 + 1140 N sol +
18.2 ⎞
⎟⎟ + 1 − ( 3 )
f α ⎜ 720 +
⎜
3.5 ⎟ + 97 Si
⎟
⎝ d ⎠ ⎝ S0 ⎠
⎛ 11.5 ⎞ ⎡ ⎤
⎟⎟ + (1 − f α )
5.6 13.3
ITT = f α ⎜⎜ − 46 − ⎢− 335 + − + 3.48 × 10 6 t ⎥ + 48.7 Si + 762 N sol
⎝ d ⎠ ⎢⎣ S0 p ⎥⎦
Notation:
YS: Yield Strength at 0.2% Real Strain [MPa]
TS: Tensile Strength [MPa]
ITT: Impact Transition Temperature for 50% Tough Fracture [°C]
f: Volume Fraction of Ferrite
d: Ferrite Grain Size [mm]
Alloy Content: [weight %]
Nsol: Solubilized (Free) Nitrogen [%]
S0: Pearlite Lamelar Spacing [mm]
p: Pearlite Colony Size [mm]
t: Pearlitic Carbide Lamellar Thickness [mm]
Sources:
Gorni Steel Forming and Heat Treating Handbook 67
- GLADMAN, T. e outros. Some Aspects of the Structure-Property Relationships in High Carbon Ferrite-Pearlite
Steels. Journal of the Iron and Steel Institute, 210, Dec. 1972, 916-930.
- PICKERING, F.B. Some Aspects of the Relationships between the Mechanical Properties of Steels and their
Microstructures. TISCO. Silver Jubilee Volume, Jan-Oct 1980, 105-132.
22.0
YS = 34.3 + + 258 P + 34.2 Mn + 52.8 Si
d
11.2
TS = 183 + + 506 P + 48.7 Mn + 109 Si + 48.8 Al + 2450 B
d
0.0412
YR = 0.424 + − 0.078 Si − 0.170 Al
d
Notation:
YS: Lower Yield Strength [MPa]
TS: Tensile Strength [MPa]
YR: Yield Ratio
d: Ferrite Grain Size [mm]
Alloy Content: [weight %]
Notes:
- These equations are valid under the following conditions: ULC Steel; Mn: 0.075~0.578%; P < 0.109%; S:
0.003~0.004%; Si < 0.34%; Al: < 0.432%; N: 0.0014~0.0020%; B < 0.0030%.
- Cold rolled steel was box annealed at 700°C; the time of treatment, including heating of the samples, was
equal to 32 hours, being followed by furnace cooling.
Gorni Steel Forming and Heat Treating Handbook 68
Source: PINOY, L et al. Influence of Composition and Hot Rolling Parameters on the Magnetic and Mechanical Properties of
Fully Processed Non-Oriented Low-Si Electrical Steels. J. Phys. IV France, 8, 1998, Pr2-487/Pr2-490.
PT = 0.658 − 0.474 Si − 2.311 Al − 25.99 O + 12.51 C + 123.7 S init + 130.2 ∆S − 137.5 N + 5.266 h
Notation:
PT: Core Loss [W/kg]
Alloy Content: [weight %]
h: Thickness [mm]
Notes:
- This equation ise valid under the following conditions: C: 0.002~0.040%; S: 0.004~0.015%; N:
0.003~0.007%.
- Negative effects of O and N are in direct contradiction with specific experimental results.
- Adjusted Squared Multiple Correlation: 0.823; Residual Mean Square: 0.082 W²/kg²
h2
PT = 4.29 + 66.4 C + 0.0282 GBI + 16.2
ρr
Notation:
PT: Total Core Loss at 15 KG [W/kg]
Alloy Content: [weight %]
GBI: Number of Grain Boundary Intercepts per mm
h: Thickness [mm]
ρ: Density [g/mm³]
r: Resistivity [µΩ.mm]
Gorni Steel Forming and Heat Treating Handbook 69
Source: LYUDKOVSKY, G. et al. Non-Oriented Electrical Steels. Journal of Metals, January 1986, 18-26.
-
Gorni Steel Forming and Heat Treating Handbook 70
- Schaeffler Diagram
. Ferrite
⎡ (T − 300) ⎤
µ = 64000 ⎢1 − (-273°C < T < 300°C)
⎣ 2235 ⎥⎦
⎡ (T − 300) ⎤
µ = 64000 ⎢1 − ⎥ − 0.032 (T − 573) 2 (300°C ≤ T < 700°C)
⎣ 2235 ⎦
⎡ (T − 300) ⎤
µ = 64000 ⎢1 − ⎥ − 0.032 (T − 573) 2 − 0.024 (T − 923) 2 (700°C ≤ T < 770°C)
⎣ 2235 ⎦
⎡ (T − 300) ⎤
µ = 69200 ⎢1 − (770°C ≤ T < 911°C)
⎣ 1382 ⎥⎦
. Austenite
⎡ (T − 300) ⎤
µ = 81000 ⎢1 − (911°C ≤ T < 1392°C)
⎣ 1989 ⎥⎦
. Delta Ferrite
⎡ (T − 300) ⎤
µ = 39000 ⎢1 − (1392°C ≤ T < 1537°C)
⎣ 2514 ⎥⎦
Gorni Steel Forming and Heat Treating Handbook 72
Notation:
µ: Shear Modulus [MPa]
T: Temperature [K]
Source: FROST, H.J. & ASHBY, M.F.: Pure Iron and Ferrous Alloys. In: Deformation-Mechanism Maps, The Plasticity
and Creep of Metals and Ceramics. Pergamon Press, Cambridge, 1982.
Gorni Steel Forming and Heat Treating Handbook 73
. Seredynski
Notation:
k: Conductivity [J/m.°C.s]
T: Temperature [°C]
Notation:
D: Diffusivity [m²/s]
T: Temperature [°C]
T ⎛ T ⎞
ε= ⎜ 0.12491 − 0.38012 ⎟ + 1.0948
1000 ⎝ 1000 ⎠
Notation:
ε: Emissivity
T: Temperature [°C]
Note:
Gorni Steel Forming and Heat Treating Handbook 74
Source: SEREDYNSKI, F.: Performance Analysis and Optimization of the Plate-Rolling Process. In: Mathematical
Process Models in Iron and Steelmaking. Proceedings. Iron and Steel Institute, Amsterdam, 1973.
. Touloukian
0,85
ε =
[1 + exp(42.68 − 0,02682 Tsup ) 0,0115 ]
Notation:
ε: Emissivity
Tsup: Superficial Temperature [K]
Source: HARDIN, R.A. et al.: A Transient Simulation and Dynamic Spray Cooling Control Model for Continuous Steel
Casting. Metallurgical and Materials Transactions B, 34B:6, June 2003, 297-306.
Gorni Steel Forming and Heat Treating Handbook 75
Source: Requirements Concerning Materials and Welding. IACS – International Association of Classification
Societies Requirement 1975, Revision 2, 2004, 228 p.
Gorni Steel Forming and Heat Treating Handbook 77
. Anisothermal Austenitizing
In this case the Austenitization Time-Temperature Equivalence Parameter in Terms of Grain Size, Pa, is the period of
heating/cooling time between Tmax and Tmin, where
2
R Tmax
Tmin = Tmax −
∆H a
Notation:
R: Molar Gas Constant, 8.314 JK-1mol-1
∆Ha: Activation Energy of Austenitic Grain Coarsening, 460 kJmol-1 for low alloy steels
Source: BARRALIS, J. & MAEDER, G. Métallurgie Tome I: Métallurgie Physique. Collection Scientifique ENSAM, 1982,
270 p.
. Isothermal Austenitizing
1
Pa =
⎡ 1 2,3 R ⎤
⎢ − log t a ⎥
⎣ Ta ∆H a ⎦
Notation:
Pa: Austenitization Time-Temperature Equivalence Parameter in Terms of Grain Size [K]
Gorni Steel Forming and Heat Treating Handbook 78
Source: BARRALIS, J. & MAEDER, G. Métallurgie Tome I: Métallurgie Physique. Collection Scientifique ENSAM, 1982,
270 p.
0.3 l 2
t 0.05 = −Q
RT
D0 e
Notation:
t0.05: Treatment Time Necessary to Achieve 5% Microstructure Banding [min]
l: Mean Spacing between Bands [mm]
Do: Diffusion Constant for the Alloy Element being Considered [cm²/s]:
- P: 0.01 cm²/s
- Mn: 0.16 cm²/s
Q: Activation Energy for the Alloy Element Being Considered [cal/mol]:
- P: 43700 cal/mol
- Mn: 62500 cal/mol
R: Molar Gas Constant, 1.987 JK-1mol-1
T: Austenitization Temperature [K]
Source: YIMING, X. et al.: A Metallographic Investigation of Banding and Diffusion of Phosphorus in Steels.
Microstructural Science, 20, 1993, 457-470.
Gorni Steel Forming and Heat Treating Handbook 79
. Tempering (Hollomon-Jaffe)
P = T (c + log t )
c = 21.53 − 5.8 C
Notation:
P: Hollomon-Jaffe Parameter [K]
T: Tempering Temperature [K]
c: Constant Characteristic of the Steel Being Tempered
t: Soaking time under T [h]
C: Carbon Content [wt%]
Notes:
- Other values for the constant c were proposed by several authors for carbon, microalloyed and low alloy
steels:
. 18 (Grange & Baughman)
. 20 (Larson & Miller, Irvine et al., Thelning)
- This expression was also deduced by Larson & Miller, which applied it to the study of metal creep. In that case
c is equal to 20 and P is divided by 1000. Such relationship was also used for the study of hydrogen
resistance and HAZ hardness of steels.
Sources:
- HOLLOMON, J.H. & JAFFE, L.D. Time-Temperature Relations in Tempering Steel. Transactions of the AIME,
162, 1945, 223-249.
- LARSON, F.R. & MILLER, J. A Time-Temperature Relationship for Rupture and Creep Stresses. Transactions of
the American Society of Mechanical Engineers, 74, 1952, 765-775.
- GRANGE, R.A. & BAUGHMAN, R.W. Hardness of Tempered Martensite in Carbon and Low Alloy Steels.
Transactions of the American Society for Metals, 68, 1956, 165-197.
- THELNING, K.E.: Steel and its Heat Treatment – Bofors Handbook. Butterworths, London, 1981, 570 p.;
Gorni Steel Forming and Heat Treating Handbook 80
- IRVINE, K.J. et al. Grain-Refined C-Mn Steels. Journal of the Iron and Steel Institute, Feb. 1967, 161-182.
Gorni Steel Forming and Heat Treating Handbook 81
- Welding Effects
⎡ 2 ⎛ Mn ⎞ 2 ⎛ 3 Cr ⎞ ⎤
2
Feq = (C − 0.03) ⎢ Si + ⎜ ⎟ + (4 Al ) + ⎜
2
⎟ ⎥
⎣⎢ ⎝ 10 ⎠ ⎝ 2 ⎠ ⎦⎥
Notation:
Feq: Weld Interface Cracking Susceptibility during Flash Butt Welding (No Crack = Zero)
Alloy Content: [weight %]
Source: MIZUI, M. et al.: Application of High-Strength Steel Sheets to Automotive Wheels. Nippon Steel Technical
Report, 23, June 1984, 19-30.
⎛ Mn Si Cr V ⎞
TS eq = 52 ⎜ C + + + + ⎟ + 30
⎝ 5 7 9 2⎠
Notation:
TSeq: Tensile Strength After Flash Butt Welding [kgf/mm²]
Alloy Content: [weight %]
Source: MIZUI, M. et al.: Application of High-Strength Steel Sheets to Automotive Wheels. Nippon Steel Technical
Report, 23, June 1984, 19-30.
Gorni Steel Forming and Heat Treating Handbook 82
APENDIXES
USEFUL DATA AND CONSTANTS
- Density (Gas)
. Natural Gas: 0.81 kg/Nm³
. Butane: 2.44 kg/Nm³
. Propane: 1.85 kg/Nm³
. Liquified Petroleum Gas (LPG): 2.29 kg/Nm³
. Air: 1.27 kg/Nm³
- Density (Liquid)
. Butane: 0.58 kg/l
. Propane: 0.51 kg/l
. Liquified Petroleum Gas (LPG): 0.54 kg/Nm³
. Water: 1.00 kg/Nm³
Gas a b
C2H6 0.600 0.000540
C3H8 0.871 0.001226
CH4 0.380 0.000210
CO 0.302 0.000022
CO2 0.406 0.000090
Gorni Steel Forming and Heat Treating Handbook 83
H2 0.301 0.000200
N2 0.302 0.000022
O2 0.320 0.000059
Mathematical Constants
- e: 2.718281828
- Pi: 3.141592654
Physical Constants
- Densities:
. Bulk Steel: 7850 kg/m³
. Ferrite (Fe α): 7687 kg/m³
. Cementite (Fe3C): 7882 kg/m³
. NbC: 7790 kg/m³
. VC: 5700 kg/m³
- Electrical Resistivity at 15.6°C: 17 x 10-8 ohm.m
- Emissivity of Polished Metal Surface:
. 0.07 @ 38°C
. 0.10 @ 260°C
. 0.14 @ 540°C
- Emissivity of Oxidized Steel Plate at 15.6°C: 0.80
- Linear Coefficient of Thermal Expansion: 11.7 x 10-6 1/°C
- Melting Point: 1300 ~ 1450°C
- Modulus:
. Bulk: 159,000 MPa
Gorni Steel Forming and Heat Treating Handbook 86
Sources:
- ANON.: Practical Data for Metallurgists. The Timken Company, Canton, September 2006, 130 p.
- HEIDEMANN, M. Fours Pits - Établissement de Bilans Thermiques Globaux et Étages dans les Temps. Rapport
IRSID 77-02, Saint-Germain-en-Laye, Juillet 1976, 15 p.
- METNUS, G.E. et al. Comparing CO2 Emissions and Energy Demands for Alternative Ironmaking Routes.
Steel Times International, March 2006, 32-36.
- WILSON, A.D. Guidelines for Fabricating and Processing Plate Steel. Bethlehem-Lukens Plate Report, Burns
Harbor, 2000, 97 p.
Gorni Steel Forming and Heat Treating Handbook 87
UNIT CONVERSIONS
From Multiply by To From Multiply by To
A 10-10 m kgf/mm² 9.80665 MPa
bar 1.019716 kg/cm² kN 224.8 lbf
BTU 1058.201058 J kN/mm 5.71 x 103 lbf/ft
cal 4.184 J ksi 6.894757 MPa
F 5/9 (°F-32) °C ksi 1000 psi
ft 12 inch Ksi.√in 1.098901099 MPa.√m
ft 0.30485126 m kW 1.341022 HP
ft.lb 1.356 J ou N.m lb 0.4535924 kg
ft.lb 0.324 cal lb.in 0.1129815 J ou N.m
ft.lb 1.355748373 J lb/ft³ 0.016020506 g/cm³
ft.lb/s 1.355380862 W lb/in³ 27.67783006 g/cm³
ft.lbf 1.355818 J ou N.m lbf 4.448222 N
ft.lbf 0.1382 kg lbf/in² 1 psi
ft² 92.90 x 10-3 m² long ton 1016.047 kg
ft³ 0.02831685 m³ M 1010 A
HP 0.7456999 kW m 3.281 ft
HP 745,7121551 W m² 10.76 ft²
in 25.4 mm mm 0.0394 in
in² 645.2 mm² mm² 1.550 x 10³ in²
in³ 16387.064 mm³ MPa 1 N/mm²
inch 25.4 mm MPa 0.145 ksi
J 9.45 x 10-4 BTU MPa 145 lbf/in²
J 0.2390 cal MPa√m 0,920 ksi√in
J 0.7376 ft.lb N.m 1 J
kg 2.205 lb oz 0.028352707 kg
kgf 9.80665 N Pa 1 N/m²
kgf.m 9.80665 J Pa 1,449 x 10-4 Psi
Gorni Steel Forming and Heat Treating Handbook 88
- Correlation Coefficient
_
Σ (Yest − Y ) 2
r=± _
Σ (Y − Y ) 2
Notation:
r: Correlation Coefficient
Y: Raw Data
Yest: Estimated Data Calculated by the Fitted Equation
_
Y : Mean of the Raw Data
Source: SPIEGEL, M.R. Estatística, Editora McGraw-Hill do Brasil Ltda., São Paulo, 1976, 580 p.
_
Σ (Yest − Y ) 2
σ=
n
Notation:
σ: Standard Error of Estimation
Yest: Estimated Data Calculated by the Fitted Equation
Gorni Steel Forming and Heat Treating Handbook 90
_
Y : Mean of the Raw Data
n: Number of Points of Data
Source: SPIEGEL, M.R. Estatística, Editora McGraw-Hill do Brasil Ltda., São Paulo, 1976, 580 p.