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M - ENG - MSDS v1.2

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MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS

FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED


"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 21

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Tungsten carbide 12070-12-1 5mg/m3(as W) -
Copper 7440-50-8 0.2mg/m3 Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Zinc 7440-66-6 5mg/m3 Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limits for nickel is 1mg/m3 , which will
result in a significant reduction from the 5mg/m3 general fume level. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

Magna 21 Page 1
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Nickel

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more detail on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.

Magna 21 Page 2
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 21 Page 3
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 21 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Boric acid 10043-35-3 10mg/m3 * -
Borax 1303-96-4 10mg/m3 * -

SECTION II - PHYSICAL CHARACTERISTICS


Boiling Point N.A. Specific Gravity (H20 = 1) 1.32
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth white paste with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Acetic anhydride, elemental potassium.
Hazardous Decomposition or Products
None
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Nausea, vomiting and diarrhea.
Skin absorption: Not known as a skin absorbent.
Inhalation: Irritation to respiratory system. Sneezing and coughing.
Existing lung disorders may be aggravated.
Skin contact: Dermatitis. Existing skin disorders may be aggravated.
Eye contact: Irritation to eyes. Existing eye disorders may be
aggravated.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Magna 21 Flux Page 1
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Avoid breathing dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 21 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 24

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Silver 7440-22-4 0.1mg/m3 Fume
Phosphorus 7723-14-0 0.1mg/m3 -
Copper 7440-50-8 0.2mg/m3 Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:

Magna 24 Page 1
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more detail on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.

Magna 24 Page 2
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.
Notes: We believe the statements, technical information and
recommendations contained herein are reliable, but they are given
without warranty or guarantee of any kind, express or implied, and
we assume no responsibility for any loss, damage, or expense,
direct or consequential, arising out of their use.

Magna 24 Page 3
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 10/07/1998
MAGNA 24 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Potassium fluoborate 14075-53-7 2.5mg/m3 * -
Potassium tetraborate 1332-77-0 10mg/m3 ** -
Boric acid 10043-35-3 10mg/m3 ** -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point approx. 100C Specific Gravity (H20 = 1) 1.655
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth white paste with no noticeable odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or dry chemical.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Avoid splashing this material and solutions of it onto personnel.
Hydrofluoric acid solution may be formed within water runoff.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable Excessive heat may induce thermal decomposition.
Incompatibility (Materials to Avoid)
Acids, alkalis.
Hazardous Decomposition or Products
Hydrogen fluoride and caustic potash are expected.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Can cause damage to digestive system. Corrosive to mucous
membranes. May cause salivation, nausea, vomiting, diarrhea, and
abdominal pain. Potassium ion may cause lower blood pressure, death.
Fluoride ion can reduce serum calcium levels, possibly causing fatal
hypocalcemia. Systemic toxicity and shock. Do not aspirate into lungs.
Skin absorption: None currently known. Fumes may be penetrable.
Inhalation: Highly irritating to respiratory system. Coughing and
sneezing. Existing lung disorders will be aggravated. Inhalation may
yield: chills, labored breathing, fevers, and unproductive cough. The
fluoride ion may cause hypocalcemia - calcium deficiency in the blood.
Inflammation and necrosis of mucous membranes.
Magna 24 Flux Page 1
Skin contact: Severe dermatitis; possible burns and pustular
dermatitis, corrosive to skin. Existing disorders will be aggravated.
Hypocalcemia.
Eye contact: Strong irritation to eyes, tearing, burn of eye surfaces,
and corrosive to eyes. May cause blindness.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes, call physician immediately.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician immediately, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Prevent direct contact to skin, eyes, and clothes.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures, keep containers tightly closed
and away from foodstuffs.
No eating or smoking in work area.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical and acid impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as F
** as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are not given without warranty or
guarantee for any kind, express or implied, and we assume no responsibility
for any loss, damage, or expense, direct or consequential, arising out of
their use.

Magna 24 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 33 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Boric acid 10043-35-3 10mg/m3 * -
Borax 1303-96-4 10mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.32
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth white paste with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Acetic anhydride, elemental potassium.
Hazardous Decomposition or Products
None
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Nausea, vomiting and diarrhea.
Skin absorption: Not known as a skin absorbent.
Inhalation: Irritation to respiratory system. Sneezing and coughing.
Existing lung disorders may be aggravated.
Skin contact: Dermatitis. Existing skin disorders may be aggravated.
Eye contact: Irritation to eyes. Existing eye disorders may be
aggravated.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Magna 33 Page 1
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Avoid breathing dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no responsibility
for any loss, damage, or expense, direct or consequential, arising out of
their use.

Magna 33 Page 2
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/06/1998
Magna 33F-Flux coated
nickel/silver brazing rod.

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Copper 7440-50-8 0.2mg/m3 Fume
Zinc 7440-66-6 5mg/m3 Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Boron oxide 1303-86-2 10mg/m3 -
Acrylic polymer 9003-01-4 - -
Montmorillonite 1318-93-0 - -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for nickel is 1mg/m3, which will
result in a significant reduction from the 5mg/m3 general fume level. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders

Magna 33F Page 1


helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more detail on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial

Magna 33F Page 2


clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 33F Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 38

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Manganese 7439-96-5 1mg/m3 Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National StandardZ49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinatedhydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compoundsand not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for hexavalent chromium is 0.05mg/m3
and for nickel is 1mg/m3, which will result in a significant reduction from
the 5mg/m3 general fume level. Gaseous reaction products may include carbon
monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the
radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

Magna 38 Page 1
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE towelding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium, Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:

Magna 38 Page 2
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 38 Page 3
MATERIAL SAFETY DATA SHEET MAGNA ALLOYS DIVISION
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 45

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Boric acid 10043-35-3 10mg/m3 * -
Borax 1303-96-4 10mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.32
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth white paste with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Acetic anhydride, elemental potassium.
Hazardous Decomposition or Products
None
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Nausea, vomiting and diarrhea.
Skin absorption: Not known as a skin absorbent.
Inhalation: Irritation to respiratory system. Sneezing and coughing.
Existing lung disorders may be aggravated.
Skin contact: Dermatitis. Existing skin disorders may be aggravated.
Eye contact: Irritation to eyes. Existing eye disorders may be
aggravated.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Magna 45 Flux Page 1
Swallowing: Call a physician, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Avoid breathing dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.
SECTION VII - CONTROL MEASURES
Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no responsibility
for any loss, damage, or expense, direct or consequential, arising out of
their use.

Magna 45 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 45 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Boric acid 10043-35-3 10mg/m3 * -
Borax 1303-96-4 10mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.32
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth white paste with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Acetic anhydride, elemental potassium.
Hazardous Decomposition or Products
None
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Nausea, vomiting and diarrhea.
Skin absorption: Not known as a skin absorbent.
Inhalation: Irritation to respiratory system. Sneezing and coughing.
Existing lung disorders may be aggravated.
Skin contact: Dermatitis. Existing skin disorders may be aggravated.
Eye contact: Irritation to eyes. Existing eye disorders may be
aggravated.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Magna 45 Page 1
Swallowing: Call a physician, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Avoid breathing dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no responsibility
for any loss, damage, or expense, direct or consequential, arising out of
their use.

Magna 45 Page 2
MATERIAL SAFETY DATA SHEET MAGNA ALLOYS DIVISION
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG.
Standard must be consulted for specific
requirements. TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED : 04/10/1996
MAGNA 51

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity : Common Name (s)) CAS NO. TLV Recommended
Tin 7440-31-5 2mg/m3 * -
Zinc 7440-66-6 5mg/m3 * -
Cadmium 7440-43-9 0.05mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) N.A.
Vapor Pressure (- ) N.A. Melting Point 177-260C
Vapor Density (AIR = 1) N.A. Evaporation Rate (- ) N.A.
Solubility in Water Insoluble
Appearance and Odor Silver color with no odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
CO2 or dry chemical extinguisher. Do not use water on molten metal.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Finely divided dust may form explosive mixture with air. Should not be
heated to extremes beyond melting point.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Strong acids and alkalis.
Hazardous Decomposition or Products
At temperatures above melting range/temperature, oxide fumes may evolve.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Cadmium fume produces metal fume fever which may result in severe
tracheobronchitis, pneumonitus, pulmonary edema. Suspected acute inhalation
exposure to cadmium must be treated for pulmonary edema by physician. Delay
until onset of pulmonary involvement may result in death.
Excessive inhalation of zinc oxide fumes may produce symptoms known as zinc
shakes.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water for at
least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call physician.
Inhalation: Remove to fresh air, call physician.
Magna 51 Page 1
Ingestion: Consult physician. This product is non-edible-metal compound.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Vacuuming or washing down is recommended. Dry sweeping may result in high
concentrations of airborne dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before reuse.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where applicable limits
may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Heat resisting gloves Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* fume

We believe the statements, technical information and recommendations contained


herein are reliable, but they are given without warranty or guarantee for any
kind, express or implied, and we assume no responsibility for any loss,
damage, or expense, direct or consequential, arising out of their use.

Magna 51 Page 2
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 30/04/1998
MAGNA 51 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Aminoethylethanolamine 111-41-1 N.E. -
Triethanolamine 102-71-6 N.E. -
Zinc oxide 1314-13-2 5mg/m3 -
Ammonium fluoborate 13826-83-0 ** -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.30
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Soluble
Appearance and Odor Viscous amber liquid with strong ammonia odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
>135C In Air, % by vol 1.6 # 10.0 #
Extinguishing Media
Water, fog, foam, or dry chemical.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Avoid splashing this material and solutions of it onto personnel.
Hydrofluoric acid solution may be formed within water runoff.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable Excessive heat may induce thermal decomposition.
Incompatibility (Materials to Avoid)
Cyanides, sulfides, strong oxidants.
Hazardous Decomposition or Products
Toxic hydrofluoric acid, ammonia, and boron trifluoride are expected.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Can cause damage to digestive system. Corrosive to mucous
membranes. May cause salivation, nausea, vomiting, diarrhea and
abdominal pain. Fluoride ion can reduce serum calcium levels, possibly
causing fatal hypocalcemia. Systemic toxicity and shock. Do not
aspirate into lungs.
Skin absorption: None currently known. Fumes may be penetrable.
Inhalation: Highly irritating to respiratory system. Coughing and
sneezing.
Existing lung disorders will be aggravated. Inhalation may yield:
chills, labored breathing, fevers, and unproductive cough. The
Magna 51 Flux Page 1
fluoride ion may cause hypocalcemia - calcium deficiency in the blood.
Inflammation and necrosis of mucous membranes.
Skin contact: Severe dermatitis, possible burns and pustular
dermatitis, corrosive to skin. Existing disorders will be aggravated.
Hypocalcemia. Eye contact: Strong irritation to eyes, tearing, burn of
eye surface, corrosive to eyes. May cause blindness.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes, call physician immediately.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician immediately, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Prevent direct contact to skin, eyes, and clothes.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures, keep containers tightly closed
and away from foodstuffs.
No eating or smoking in work area.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical and acid impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
N.E. = Not Established
** 2.5mg/m3 as F; 10mg/m3 as B2O3
# estimated

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 51 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 51NC

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Tin 7440-31-5 2mg/m3 * -
Zinc 7440-66-6 5mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) N.A.
Vapor Pressure (- ) N.A. Melting Point 199-316C
Vapor Density (AIR = 1) N.A. Evaporation Rate (- ) N.A.
Solubility in Water Insoluble
Appearance and Odor Silver color with no odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
CO2, dry chemical extinguisher. Do not use water on molten metal.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full
protective clothing if involved in fire.
Unusual Fire and Explosion Hazards
Finely divided dust may form explosive mixture with air. Should not be
heated to extremes beyond melting point.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Strong acids and alkalis.
Hazardous Decomposition or Products
At temperatures above melting range/temperature, oxide fumes may
evolve.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Excessive inhalation of zinc oxide fumes may produce symptoms known as
zinc shakes. It is unlikely that normal exposure to this material
would result in acute illness.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Ingestion: Consult physician. This product is non-edible-metal
compound.
Magna 51NC Page 1
SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to Be Taken In Case Material Is Released or Spilt
Vacuuming or washing down is recommended. Dry sweeping may result in
high concentrations of airborne dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before reuse.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Heat resisting gloves Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* fume

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 51NC Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO.LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 4 October 1996
Magna 55

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Aluminium 7429-90-5 5mg/m3 Fume
Silicon 7440-21-3 10mg/m3 Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise

Magna 55 Page 1
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:

Magna 55 Page 2
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 55 Page 3
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 55 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Zinc chloride 7646-85-7 1mg/m3 * -
Lithium fluoride 7789-24-4 2.5mg/m3 ** -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 2.152
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Slightly soluble
Appearance and Odor Yellow powder with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Strong acids, cyanides, and sulfides.
Hazardous Decomposition or Products
In presence of water and heat, HCl and HF may be produced.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Can cause damage to digestive system. May cause
salivation, nausea, vomiting, diarrhea and abdominal pain. Fluoride
ion can reduce serum calcium levels, possibly causing fatal
hypocalcemia. Systemic toxicity and shock. Do not aspirate into lungs.
Skin absorption: Not known as a skin absorbent.
Inhalation: Irritant to respiratory system. Lithium dust and fumes are
absorbed through the lungs. Lung damage. Existing lung disorders may
be aggravated. The fluoride ion may cause hypocalcemia - calcium
deficiency in the blood.
Skin contact: Dermatitis, possibly a chemical burns. Existing skin
disorders may be aggravated.
Eye contact: Irritation to eyes, and possible burn of eye surfaces.
Emergency & First Aid Procedures

Magna 55 Flux Page 1


Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician. Swallowing: Call a
physician, advise of Section I.
SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Avoid breathing dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.
SECTION VII - CONTROL MEASURES
Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* Corrosive
** as F

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 55 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 55 TIG

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Aluminium 7429-90-5 5mg/m3 Fume
Silicon 7440-21-3 10mg/m3 Dust
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise

Magna 55 T.I.G. Page 1


Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:

Magna 55 T.I.G. Page 2


Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 55 T.I.G. Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 66

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Silver 7440-22-4 0.1mg/m3 Fume
Zinc 7440-66-6 5mg/m3 Fume
Copper 7440-50-8 0.2mg/m3 Fume
Cadmium 7440-43-9 0.05mg/m3 Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA

Magna 66 Page 1
Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Cadmium as cadmium oxide.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.

Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:

Magna 66 Page 2
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 66 Page 3
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 10/07/1998
MAGNA 66 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Potassium fluoborate 14075-53-7 2.5mg/m3 * -
Potassium tetraborate 1332-77-0 10mg/m3 ** -
Boric acid 10043-35-3 10mg/m3 ** -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point approx. 100C Specific Gravity (H20 = 1) 1.655
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth black paste with no noticeable odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or dry chemical.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Avoid splashing this material and solutions of it onto personnel.
Hydrofluoric acid solution may be formed within water runoff.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable Excessive heat may induce thermal decomposition.
Incompatibility (Materials to Avoid)
Acids, alkalis.
Hazardous Decomposition or Products
Hydrogen fluoride and caustic potash are expected.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Can cause damage to digestive system. Corrosive to mucous
membranes. May cause salivation, nausea, vomiting, diarrhea, and
abdominal pain. Potassium ion may cause lower blood pressure, death.
Fluoride ion can be reduce serum calcium levels, possibly causing
fatal hypocalcemia. Systemic toxicity and shock. Do not aspirate into
lungs.
Skin absorption: None currently known. Fumes may be penetrable.
Inhalation: Highly irritating to respiratory system. Coughing and
sneezing. Existing lung disorders will be aggravated. Inhalation may
yield: chills, labored breathing, fevers, and unproductive cough. The
fluoride ion may cause hypocalcemia - calcium deficiency in the blood.
Magna 66 Flux Page 1
Inflammation and necrosis of mucous membranes.
Skin contact: Severe dermatitis; possible burns and pustular
dermatitis, corrosive to skin. Existing disorders will be aggravated.
Hpocalcemia. Eye contact: Strong irritation to eyes, tearing, burn of
eye surfaces, and corrosive to eyes. May cause blindness.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes, call physician immediately.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician immediately, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Prevent direct contact to skin, eyes, and clothes.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures, keep containers tightly closed
and away from foodstuffs.
No eating or smoking in work area.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical and acid impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as F
** as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 66 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 67F

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Zinc 7440-66-6 5mg/m3 Fume
Copper 7440-50-8 0.2mg/m3 Fume
Silver 7440-22-4 0.1mg/m3 Fume
Tin 7440-31-5 2mg/m3 Fume
Potassium oxide - - -
Hydrogen fluoride 7664-39-3 2.5mg/m3(as F) -
Boron trifluoride 7637-07-2 CL 1ppm -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National StandardZ49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for hexavalent chromium is 0.05mg/m3,
which will result in a significant reduction from the 5mg/m3 general fume
level. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the
arc.

One recommended way to determine the composition and quantity of fumes and

M-67F.1
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI – PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm

M-67F.2
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Remark:
CL = Ceiling Valve

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 67F Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 75F-Low fuming, flux
coated brazing rod.

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Copper 7440-50-8 0.2mg/m3(as Fe2O3) Fume
Zinc 7440-66-6 5mg/m3 Fume
Tin 7440-31-5 2mg/m3 Dust
Boron oxide 1303-86-2 10mg/m3 -
Potassium oxide - - -
Acrylic polymer 9003-01-4 - -
montomorillonite 1318-93-0 - -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of
welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components
are virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I.
Gaseous reaction products may include carbon monoxide and carbon dioxide.
Ozone and nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the
welders helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1,

Magna 75F Page 1


available from the American Welding Society, P.O. Box 351040, Miami, FL
33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA
should be used as guides in the control of health hazards and should not be
used as firm lines between safe and dangerous concentrations." See Section
IV for specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM
(CHRONIC) OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is
believed by some investigators to affect pulmonary function. ARC RAYS can
injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American Red
Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many
of the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general
area. Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide
protective screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to

Magna 75F Page 2


insulate himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty
or guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 75F Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 75 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Boric acid 10043-35-3 10mg/m3 * -
Borax 1303-96-4 10mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.625
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor White powder with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Zirconium metal.
Hazardous Decomposition or Products
None
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Nausea, vomiting, and diarrhea.
Skin absorption: Not known as a skin absorbent.
Inhalation: Irritant to respiratory system. Sneezing and coughing.
Existing lung disorders may be aggravated.
Skin contact: Mild dermatitis or irritation. Existing skin disorders
may be aggravated.
Eye contact: Irritation to eyes. Existing eye disorders may be
aggravated.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Magna 75 Flux Page 1
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Avoid breathing dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical and acid impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 75 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/06/1998
Magna 77F-Flux coated
nickel/silver brazing rod.

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Copper 7440-50-8 0.2mg/m3 Fume
Zinc 7440-66-8 5mg/m3 Fume
Nickel 7440-02-0 1mg/m3 (Metal) Fume
Boron Oxide 1303-86-2 10mg/m3 -
Acrylic polymer 9003-01-4 - -
Montmorillonite 1318-93-0 - -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of
welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components
are virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for nickel is 1mg/m3, which will
result in a significant reduction from the 5mg/m3 general fume level. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the
welders helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1,
available from the American Welding Society, P.O. Box 351040, Miami, FL
Magna 77F Page 1
33135.

SECTION V - HEALTH HAZARD DATA

Threshold Limit Value:


The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM
(CHRONIC) OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is
believed by some investigators to affect pulmonary function. ARC RAYS can
injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many
of the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general
area. Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide
protective screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.

Magna 77F Page 2


Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty
or guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 77F Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 77 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Boric acid 10043-35-3 10mg/m3 * -
Borax 1303-96-4 10mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.32
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth white paste with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Acetic anhydride, elemental potassium.
Hazardous Decomposition or Products
None
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Nausea, vomiting and diarrhea.
Skin absorption: Not known as a skin absorbent.
Inhalation: Irritation to respiratory system. Sneezing and coughing.
Existing lung disorders may be aggravated.
Skin contact: Dermatitis. Existing skin disorders may be aggravated.
Eye contact: Irritation to eyes. Existing eye disorders may be
aggravated.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Magna 77 Flux Page 1
Swallowing: Call a physician, advise of Section I.
SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Avoid breathing dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.
SECTION VII - CONTROL MEASURES
Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where applicable
limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 77 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 79

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Tin 7440-31-5 2mg/m3 * -
Lead 7439-92-1 0.05mg/m3 * -
Zinc 7440-66-6 5mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) N.A.
Vapor Pressure (- ) N.A. Melting Point **
Vapor Density (AIR = 1) N.A. Evaporation Rate (- ) N.A.
Solubility in Water Insoluble
Appearance and Odor Silver-grey color with no odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
CO2 or dry chemical extinguisher.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Finely divided dust may form explosive mixtures with air. When overheated,
lead fumes are toxic (NEVER exceed 500C).

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Strong acids and alkalis.
Hazardous Decomposition or Products
At temperatures above melting range/temperature, oxide fumes may
evolve.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Chronic overexposure to high levels of airborne or ingested lead may
result in anemia, incomnia, weakness, constipation, nausea and
abdominal pain.
Prolonged overexposure may result in kidney and nervous system
involvement and reproductive effects. It is unlikely that exposure to
this material would result in an acute illness; however, if symptoms
are present, the individual should be removed from exposure and a
physician consulted.
Diseases of the blood and blood-forming organs, kidneys, nervous
system, and possibly reproductive systems may be aggravated by
Magna 79 Page 1
overexposure to lead. Exposure to lead may result in injury to a
developing fetus.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Induce vomiting in concious individual. Call physician.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Vacuuming or washing down is recommended. Dry sweeping may result in
high concentrations of airborne dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before reuse.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved lead dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Heat resisting gloves Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* fume
** Tin @232C & lead @327C

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 79 Page 2
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 79 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Zinc chloride 7646-85-7 1mg/m3 * -
Tin 7440-31-5 2mg/m3 ** -
Zinc 7440-66-6 5mg/m3 ** -
Lead 7439-92-1 0.05mg/m3 -
**
Zinc ammonium chloride 52628-25-8 1.68mg/m3 -
Sodium fluoride 7681-49-4 2.5mg/m3 # -
Iron oxide 1317-61-9 5mg/m3 ## -
Zinc oxide 1314-13-2 5mg/m3 -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 3.4
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (But-Acet=1) N.A.
Solubility in Water Insoluble
Appearance and Odor Fine, pink powder with no noticeable odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
CO2 or dry chemical extinguisher.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Dense smoke may be generated. When overheated lead fumes are toxic (NEVER
exceed 500C).

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Strong nitric, sulfuric acids, cyanide.
Hazardous Decomposition or Products
In presence of water and heat - HCl, zinc oxide and ammonia.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Can cause damage to digestive system. Corrosive to mucous
membranes. May cause salivation, nausea, vomiting, diarrhea and
abdominal pain. Fluoride ion can reduce serum calcium levels, possibly
causing fatal hypocalcemia. Systemic toxicity and shock. Do not
aspirate into lungs.
Magna 79 Flux Page 1
Skin absorption: None currently known. Fumes may be penetrable.
Inhalation: Highly irritating to respiratory system. Coughing and
sneezing.
Existing lung disorders will be aggravated. Inhalation may yield:
chills, labored breathing, fevers, and unproductive cough. The
fluoride ion may cause hypocalcemia - calcium deficiency in the blood.
Inflammable and necrosis of mucous membranes.
Skin contact: Severe dermatitis, possible burns and pustular
dermatitis, corrosive to skin. Existing disorders will be aggravated.
Hypocalcemia.
Eye contact: Strong irritating to eyes, tearing, burn of eye surfaces,
corrosive to eyes. May cause blindness.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes, call physician immediately.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician immediately, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Prevent direct contact to skin, eyes, and clothes.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures, keep containers tightly closed
and away from foodstuffs.
No eating or smoking in work area.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical and acid impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* Corrosive
** fume
# as F
## as Fe2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
Magna 79 Flux Page 2
consequential, arising out of their use.

Magna 79 Flux Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 88C

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Tin 7440-31-5 2mg/m3 * -
Silver 7440-22-4 0.1mg/m3 * -
Urea 57-13-6 5mg/m3 -
Ethylene Diamine Dihydrochloride 333-18-6 50ppm -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point 2219C Specific Gravity (H20 = 1) N.A.
Vapor Pressure (- ) N.A. Melting Point 215C
Vapor Density (AIR = 1) N.A. Evaporation Rate (- ) N.A.
Solubility in Water Wire: Insoluble; Core: Appreciable.
Appearance and Odor Silver, odorless wire with liquid core running through
centre.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water spray, CO2, alcohol foam.
Special Fire Fighting Procedures
When heated to point of vaporization, toxic fumes are emitted. Use NIOSH
approved self-contained breathing apparatus and full protective clothing if
involved in fire.
Unusual Fire and Explosion Hazards
Silver plus ammonia may produce fulminate-like compounds which may explode
when dried. Acetylene plus silver may form an insoluble, explosive acetylide.
SECTION IV - REACTIVITY DATA
Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Ammonia, acetylene, strong acids and alkalis.
Hazardous Decomposition or Products
At temperatures above melting range/temperature, oxide fumes may
evolve.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Argyria, a blue-grey discoloration of the skin, mucous membranes and
eyes may result from inhalation of silver. This discoloration may
become permanent.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Magna 88C Page 1
Inhalation: Remove to fresh air, call physician.
Swallowing: Induce vomiting in conscious individual. Call physician.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Vacuuming or washing down is recommended. Dry sweeping may result in
high concentrations of airborne dust.
Waste Disposal Method
Dispose of in accordance with Federal, State, and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperature. Crimp end of solder not in use to
prevent (flux) core leakage.
Other Precautions
Remove and professionally wash contaminated clothing before reuse.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Heat resisting gloves Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* fume

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 88C Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 88 FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Zinc chloride 7646-85-7 1mg/m3 * -
Ammonium chloride 12125-02-9 10mg/m3 -
Hydrochloric acid 7647-01-0 CL 5ppm * -
Methyl alcohol 67-56-1 260mg/m3 -
Boric acid 10043-35-3 10mg/m3 ** -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point 101C Specific Gravity (H20 = 1) 1.34
Vapor Pressure (mm Hg. ) 9.72 Melting Point N.A.
Vapor Density (AIR = 1) 0.48 Evaporation Rate (But-Acet=1) <1
Solubility in Water Slightly soluble
Appearance and Odor Clear, water-white liquid with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
May release toxic metal halide fumes, use approved apparatus.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
None
Hazardous Decomposition or Products
Hydrogen chloride, zinc oxide.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Can cause damage to digestive system. Corrosive to mucous
membranes. May cause salivation, nausea, vomiting diarrhea and
abdominal pain.
Skin absorption: Not known as a skin absorbent.
Inhalation: Highly irritating to respiratory system. Coughing and
sneezing.
Existing lung disorders will be aggravated. inhalation may yield:
chills, labored breathing, fevers, and unproductive cough.
Skin contact: Severe dermatitis, possible burns and pustular
dermatitis, corrosive to skin. Existing disorders will be aggravated.
Magna 88 Flux Page 1
Hypocalcemia. Eye contact: Strong irritating to eyes, tearing, burn of
eye surfaces, corrosive to eyes. May cause blindness.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes, call physician immediately.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician immediately, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Prevent direct contact to skin, eyes, and clothes.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures, keep containers tightly closed
and away from foodstuffs.
No eating or smoking in work area.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
CL = Ceiling value
* Corrosive
** as B2O3

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 88 Flux Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 89

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Tin 7440-31-5 2mg/m3 * -
Lead 7439-92-1 0.05mg/m3 * -
Zinc 7440-66-6 5mg/m3 * -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) N.A.
Vapor Pressure (- ) N.A. Melting Point **
Vapor Density (AIR = 1) N.A. Evaporation Rate (- ) N.A.
Solubility in Water Insoluble
Appearance and Odor Silver-grey color with no odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
CO2 or dry chemical extinguisher.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Finely divided dust may form explosive mixtures with air. When overheated
lead fumes are toxic (NEVER exceed 500C).

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
Strong acids and alkalis.
Hazardous Decomposition or Products
At temperatures above melting range/temperature, oxide fumes may
evolve.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Chronic overexposure to high levels of airborne or ingested lead may
result in anemia, incomnia, weakness, constipation, nausea and
abdominal pain.
Prolonged overexposure may result in kidney and nervous system
involvement and reproductive effects. It is unlikely that exposure to
this material would result in an acute illness; however, if symptoms
are present, the individual should be removed from exposure and a
physician consulted.
Diseases of the blood and blood-forming organs, kidneys, nervous
system, and possibly reproductive systems may be a aggravated by
Magna 89 Page 1
overexposure to lead. Exposure to lead may result in injury to a
developing fetus.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Induce vomiting in concious individual. Call physician.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Vacuuming or washing down is recommended. Dry sweeping may result in
high concentrations of airborne dust.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before reuse.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved lead dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Heat resisting gloves Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in soldering operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* fume
** Tin @232C & lead @327C

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 89 Page 2
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA Q FLUX

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Boric acid 10043-35-3 10mg/m3 * -
Potassium bifluoride 7789-29-9 2.5mg/m3 ** -
Lithium fluoride 7789-24-4 2.5mg/m3 ** -
Potassium tetraborate 1332-77-0 10mg/m3 * -
Zinc chloride 7646-85-7 1mg/m3 # -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point approx. 100C Specific Gravity (H20 = 1) 1.54
Vapor Pressure (mm Hg. ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (B.Acet=1) N.A.
Solubility in Water Moderate
Appearance and Odor Smooth blue paste, with no characteristic odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water, fog, foam or CO2.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
Avoid splashing this material and solution of it onto personnel.
Hydrofluoric acid solution may be formed within water runoff.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable Excessive heat may induce thermal decomposition.
Incompatibility (Materials to Avoid)
Acids, alkalis.
Hazardous Decomposition or Products
In presence of water and heat, HF and HCl may be produced.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Swallowing: Can cause damage to digestive system. Corrosive to mucous
membranes. May cause salivation, nausea, vomiting, diarrhea, and
abdominal pain. Potassium ion may cause lower blood pressure, death.
Fluoride ion can reduce serum calcium levels, possibly causing fatal
hypocalcemia. Systemic toxicity and shock. Do not aspirate into lungs.
Skin absorption: None currently known. Fumes may be penetrable.
Inhalation: Highly irritating to respiratory system. Coughing and
sneezing.
Existing lung disorders will be aggravated. Inhalation may yield:
chills, labored breathing, fevers, and unproductive cough. The
fluoride ion may cause hypocalcemia - calcium deficiency in the blood.
Inflammation and necrosis of mucous membranes.
Skin contact: Severe dermatitis; possible burns and pustular
dermatitis, corrosive to skin. Existing disorders will be aggravated.
Hypocalcemia.
Eye contact: Strong irritation to eyes, tearing, burn of eye surfaces,
and corrosive to eyes. May cause blindness.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes, call physician immediately.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Inhalation: Remove to fresh air, call physician.
Swallowing: Call a physician immediately, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Contain spill, absorb, sweep-up, dispose. Flush area with water to
chemical sewer. Prevent direct contact to skin, eyes, and clothes.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Avoid inhalation of dust or fumes in concentrations above OSHA limits.
Avoid accidental ingestion by using good personal hygiene practices.
Dry storage at ambient temperatures, keep containers tightly closed
and away from foodstuffs.
No eating or smoking in work area.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved dust/fume respirator should be worn where
applicable limits may be exceeded.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
Chemical impervious Chemical safety goggles
Other Protective Clothing or Equipment
Standard protective equipment used in braze/welding operations.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* as B2O3
** as F
# Corrosive

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.
MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 100

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe 2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Graphite 7782-42-5 2mg/m3 Dust
Cellulose 9004-34-6 10mg/m3 -
Potassium silicate 1312-76-1 5mg/m3 -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to American
National Standard Z49.1 for fire prevention during the use of welding and allied
procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of both
are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume and
gas decomposition products, not the ingredients in the electrode, are important.
Decomposition products include those originating from the volatilization,
reaction, or oxidation of the materials shown in Section I plus those from base
metal, coating, etc. as noted above. These components are virtually always
present as complex compounds and not as metals (Characterization of Arc Welding
Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and gases
to which workers are exposed is to take an air sample inside the welders helmet,

Magna 100 Page 1


if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available from the
American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should be
used as guides in the control of health hazards and should not be used as firm
lines between safe and dangerous concentrations." See Section IV for specific
fume constituents which may modify this TLV.

Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE) OVEREXPOSURE
to welding fumes may result in discomfort such as: dizziness, nausea, or dryness
or irritation of nose, throat, or eyes. LONG TERM (CHRONIC) OVEREXPOSURE may
cause lung fibrosis or pneumoconiosis and is believed by some investigators to
affect pulmonary function. ARC RAYS can injure eyes and burn skin. ELECTRIC
SHOCK can kill. See Section VI.

Emergency & First Aid Procedures:


Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary label
on this product. See American National Standard Z-49.1, Safety in Welding and
Cutting, published by the American Welding Society, P.O. Box 351040, Miami, FL
33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government Printing
Office, Washington, D.C. 20402 for more details on many of the following:

Ventilation:
Use enough ventilation, local exhaust at the arc, or bkth, to keep the fumes and
gases below the PLV's in the worker's breathing zone and the general area. Train
the welder to keep his head out of the fumes.

Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.

Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start with
a shade which is too dark to see the weld zone. Then go to the next lighter
shade which gives sufficient view of the weld zone. Provide protective screens
and flash goggles, if necessary, to shield others.

Protective Clothing:
Wear head, hand and body protection which help to prevent injury from radiation,
sparks and electrical shock. See ANSI Z-49.1. At a minimum, this includes
welder's gloves and protective face shield and may include arm protectors,
aprons, hats, shoulder protection, as well as dark substantial clothing. Train

Magna 100 Page 2


the welder not to touch live electrical parts and to insulate himself from work
and ground.

Procedure for Cleanup of Spills or Leaks:


Not applicable.

Waste Disposal Method:


Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable manner,
in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and


recommendations contained herein are reliable, but they are given
without warranty or guarantee of any kind, express or implied,
and we assume no responsibility for any loss, damage, or expense,
direct or consequential, arising out of their use.

Magna 100 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 150

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
3
Iron 7439-89-6 5mg/m (as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Magnesium carbonate 546-93-0 10mg/m3 -
Graphite 7782-42-5 2mg/m3 Dust
Potassium silicate 1312-76-1 5mg/m3 -
Sodium silicate 1344-09-8 5mg/m3 -
Cellulose 9004-34-6 10mg/m3 -
Silicon dioxide 14808-60-7 0.1mg/m3 Dust
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of
welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components
are virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Magna 100 Page 1


Reasonably expected decomposition products from normal use of this product
includes a complex of the oxides of the materials listed in Section I.
Gaseous reaction products may include carbon monoxide and carbon dioxide.
Ozone and nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the
welders helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1,
available from the American Welding Society, P.O. Box 351040, Miami, FL
33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.

Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM
(CHRONIC) OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is
believed by some investigators to affect pulmonary function. ARC RAYS can
injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VI.

Emergency & First Aid Procedures:


Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

- PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many
of the following:

Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general
area. Train the welder to keep his head out of the fumes.

Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.

Magna 100 Page 2


Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide
protective screens and flash goggles, if necessary, to shield others.

Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to
insulate himself from work and ground.

Procedure for Cleanup of Spills or Leaks:


Not applicable.

Waste Disposal Method:


Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no responsibility
for any loss, damage, or expense, direct or consequential, arising out of
their use.

Magna 100 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 210

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Copper 7440-50-8 0.2mg/m3 Fume
Tin 7440-31-5 2mg/m3 Fume
Calcium carbonate 1317-65-3 10mg/m3 Dust
Cryolite 15096-52-3 2.5mg/m3(as F) -
Silicon dioxide 14808-60-7 0.1mg/m3 Dust
Silicate binder 6834-92-0 10mg/m3 -
& 12627-14-4
& 10006-28-7
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer
to American National Standard Z49.1 for fire prevention during the use
of welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and
quantity of both are dependent upon the metal being welded, the
process, procedures and electrodes used. Other conditions which also
influence the composition and quantity of the fumes and gases to which
workers may be exposed include: coat ings on the metal being welded
(such as paint, plating, or galvanizing), number of welds and volume
of work area, quality and amount of ventilation, position of welder's
head with respect to the fume plume, as well as the presence of
contaminants in the atmosphere (such as chlorinated hydrocarbon vapors
from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition


products are different in percent and form from the ingredients listed
in Section I. Fume and gas decomposition products, not the ingredients
in the electrode, are important. Decomposition products include those
originating from the volatilization, reaction, or oxidation of the
materials shown in Section I plus those from base metal, coating, etc.
as noted above. These components are virtually always present as
complex compounds and not as metals (Characterization of Arc Welding
Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this


product includes a complex of the oxides of the materials listed in
Section I. Gaseous reaction products may include carbon monoxide and
carbon dioxide. Ozone and nitrogen oxides may be formed by the
radiation from the arc.

Magna 210 Page 1


One recommended way to determine the composition and quantity of fumes
and gases to which workers are exposed is to take an air sample inside
the welders helmet, if worn, or in the worker's breathing zone.
ANSI/AWS F1.1, available from the American Welding Society, P.O. Box
351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not
Otherwise Classified) is 5 mg/m3. The ACGIH 1984-85 preface states:
"The TLV-TWA should be used as guides in the control of health hazards
and should not be used as firm lines between safe and dangerous
concentrations." See Section IV for specific fume constituents which
may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as:
dizziness, nausea, or dryness or irritation of nose, throat, or eyes.
LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect
pulmonary function. ARC RAYS can injure eyes and burn skin. ELECTRIC
SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the
precautionary label on this product. See American National Standard Z-
49.1, Safety in Welding and Cutting, published by the American Welding
Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206
(29 C.F.R. 1910), U.S. Government Printing Office, Washington, D.C.
20402 for more details on many of the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the
fumes and gases below the TLV's in the worker's breathing zone and the
general area. Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding
in confined space or where local exhaust or ventilation does not keep
exposure below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb,
start with a shade which is too dark to see the weld zone. Then go to
the next lighter shade which gives sufficient view of the weld zone.
Provide protective screens and flash goggles, if necessary, to shield
others.

Magna 210 Page 2


Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum,
this includes welder's gloves and protective face shield and may
include arm protectors, aprons, hats, shoulder protection, as well as
dark substantial clothing. Train the welder not to touch live
electrical parts and to insulate himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

Notes: We believe the statements, technical information and


recommendations contained herein are reliable, but they are given
without warranty or guarantee of any kind, express or implied, and
we assume no responsibility for any loss, damage, or expense,
direct or consequential, arising out of their use.

Magna 210 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 303

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Nickel 7440-02-0 1mg/m3 Fume
Manganese 7439-96-5 1mg/m3 Fume
Calcium carbonate 1317-65-3 10mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Sodium silicate 1344-09-8 5mg/m3 -
Lithium aluminium silicate 12068-40-5 5mg/m3(as AI) -
Titanium dioxide 13463-67-7 10mg/m3 Dust
Potassium silicate 1312-76-1 5mg/m3 -
Lithium silicate 12627-14-4 N.A. -
Feldspar 68476-25-5 2mg/m3 -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer
to American National Standard Z49.1 for fire prevention during the use
of welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and
quantity of both are dependent upon the metal being welded, the
process, procedures and electrodes used. Other conditions which also
influence the composition and quantity of the fumes and gases to which
workers may be exposed include: coatings on the metal being welded
(such as paint, plating, or galvanizing), number of welds and volume
of work area, quality and amount of ventilation, position of welder's
head with respect to the fume plume, as well as the presence of
contaminants in the atmosphere (such as chlorinated hydrocarbon vapors
from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition


products are different in percent and form from the ingredients listed
in Section I. Fume and gas decomposition products, not the ingredients
in the electrode, are important. Decomposition products include those
originating from the volatilization, reaction, or oxidation of the
materials shown in Section I plus those from base metal, coating, etc.
as noted above. These components are virtually always present as
complex compounds and not as metals (Characterization of Arc Welding
Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this


product includes a complex of the oxides of the materials listed in

Magna 303 Page 1


Section I. The present OSHA permissible exposure limit for hexavalent
chromium is 0.05mg/m3, which will result in a significant reduction
from the 5mg/m3 general fume level. Gaseous reaction products may
include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides
may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes


and gases to which workers are exposed is to take an air sample inside
the welders helmet, if worn, or in the worker's breathing zone.
ANSI/AWS F1.1, available from the American Welding Society, P.O. Box
351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not
Otherwise Classified) is 5 mg/m3. The ACGIH 1984-85 preface states:
"The TLV-TWA should be used as guides in the control of health hazards
and should not be used as firm lines between safe and dangerous
concentrations." See Section IV for specific fume constituents which
may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as:
dizziness, nausea, or dryness or irritation of nose, throat, or eyes.
LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect
pulmonary function. ARC RAYS can injure eyes and burn skin. ELECTRIC
SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium, Nickcl

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the
precautionary label on this product. See American National Standard Z-
49.1, Safety in Welding and Cutting, published by the American Welding
Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206
(29 C.F.R. 1910), U.S. Government Printing Office, Washington, D.C.
20402 for more details on many of the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the
fumes and gases below the TLV's in the worker's breathing zone and the
general area. Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding
in confined space or where local exhaust or ventilation does not keep
exposure below TLV.

Magna 303 Page 2


Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb,
start with a shade which is too dark to see the weld zone. Then go to
the next lighter shade which gives sufficient view of the weld zone.
Provide protective screens and flash goggles, if necessary, to shield
others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum,
this includes welder's gloves and protective face shield and may
include arm protectors, aprons, hats, shoulder protection, as well as
dark substantial clothing. Train the welder not to touch live
electrical parts and to insulate himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 303 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 303 T.I.G.

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Chromium 7440-47-3 0.5mg/m3 (Metal) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Manganese 7439-96-5 1mg/m3 Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer
to American National Standard Z49.1 for fire prevention during the use
of welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and
quantity of both are dependent upon the metal being welded, the
process, procedures and electrodes used. Other conditions which also
influence the composition and quantity of the fumes and gases to which
workers may be exposed include: coatings on the metal being welded
(such as paint, plating, or galvanizing), number of welds and volume
of work area, quality and amount of ventilation, position of welder's
head with respect to the fume plume, as well as the presence of
contaminants in the atmosphere (such as chlorinated hydrocarbon vapors
from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition


products are different in percent and form from the ingredients listed
in Section I. Fume and gas decomposition products, not the ingredients
in the electrode, are important. Decomposition products include those
originating from the volatilization, reaction, or oxidation of the
materials shown in Section I plus those from base metal, coating, etc.
as noted above. These components are virtually always present as
complex compounds and not as metals (Characterization of Arc Welding
Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this


product includes a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limit for hexavalent
chromium is 0.05mg/m3 and for nickel is 1mg/m3, which will result in a
significant reduction from the 5mg/m3 general fumes level. Gaseous
reaction products may include carbon monoxide and carbon dioxide.
Ozone and nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes


and gases to which workers are exposed is to take an air sample inside

Magna 303 T.I.G. Page 1


the welders helmet, if worn, or in the worker's breathing zone.
ANSI/AWS F1.1, available from the American Welding Society, P.O. Box
351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not
Otherwise Classified) is 5 mg/m3. The ACGIH 1984-85 preface states:
"The TLV-TWA should be used as guides in the control of health hazards
and should not be used as firm lines between safe and dangerous
concentrations." See Section IV for specific fume constituents which
may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as:
dizziness, nausea, or dryness or irritation of nose, throat, or eyes.
LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect
pulmonary function. ARC RAYS can injure eyes and burn skin. ELECTRIC
SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium, Nickcl

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the
precautionary label
on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O.
Box 351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R.
1910), U.S. Government Printing Office, Washington, D.C. 20402 for
more details on many of the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the
fumes and gases below the TLV's in the worker's breathing zone and the
general area. Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding
in confined space or where local exhaust or ventilation does not keep
exposure below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb,
start with a shade which is too dark to see the weld zone. Then go to
the next lighter shade which gives sufficient view of the weld zone.
Provide protective screens and flash goggles, if necessary, to shield
others.

Magna 303 T.I.G. Page 2


Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum,
this includes welder's gloves and protective face shield and may
include arm protectors, aprons, hats, shoulder protection, as well as
dark substantial clothing. Train the welder not to touch live
electrical parts and to insulate himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 303 T.I.G. Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 305

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Dust
Calcium carbonate 1317-65-3 10mg/m3 Dust
Titanium dioxide 13463-67-7 10mg/m3 -
Calcium fluoride 7789-75-5 2.5mg/m3(as F) Dust
Silicate dioxide 14808-60-7 0.1mg/m3 -
Silicate binder 6834-92-0 & 10mg/m3 -
12627-14-4 &
10006-28-7
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer
to American National Standard Z49.1 for fire prevention during the use
of welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and
quantity of both are dependent upon the metal being welded, the
process, procedures and electrodes used. Other conditions which also
influence the composition and quantity of the fumes and gases to which
workers may be exposed include: coat ings on the metal being welded
(such as paint, plating, or galvanizing), number of welds and volume
of work area, quality and amount of ventilation, position of welder's
head with respect to the fume plume, as well as the presence of
contaminants in the atmosphere (such as chlorinated hydrocarbon vapors
from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition


products are different in percent and form from the ingredients listed
in Section I. Fume and gas decomposition products, not the ingredients
in the electrode, are important. Decomposition products include those
originating from the volatilization, reaction, or oxidation of the
materials shown in Section I plus those from base metal, coating, etc.
as noted above. These components are virtually always present as
complex compounds and not as metals (Characterization of Arc Welding
Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this


product includes a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limit for hexavalent

Magna 305 Page 1


chromium is 0.05mg/m3 and for nickel is 1mg/m3, which will result in a
significant reduction from the 5mg/m3 general fumes level. Gaseous
reaction products may include carbon monoxide and carbon dioxide.
Ozone and nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes


and gases to which workers are exposed is to take an air sample inside
the welders helmet, if worn, or in the worker's breathing zone.
ANSI/AWS F1.1, available from the American Welding Society, P.O. Box
351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not
Otherwise Classified) is 5 mg/m3. The ACGIH 1984-85 preface states:
"The TLV-TWA should be used as guides in the control of health hazards
and should not be used as firm lines between safe and dangerous
concentrations." See Section IV for specific fume constituents which
may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as:
dizziness, nausea, or dryness or irritation of nose, throat, or eyes.
LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect
pulmonary function. ARC RAYS can injure eyes and burn skin. ELECTRIC
SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium, Nickcl

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the
precautionary label on this product. See American National Standard Z-
49.1, Safety in Welding and Cutting, published by the American Welding
Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206
(29 C.F.R. 1910), U.S. Government Printing Office, Washington, D.C.
20402 for more details on many of the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the
fumes and gases below the TLV's in the worker's breathing zone and the
general area. Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding
in confined space or where local exhaust or ventilation does not keep
exposure below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb,

Magna 305 Page 2


start with a shade which is too dark to see the weld zone. Then go to
the next lighter shade which gives sufficient view of the weld zone.
Provide protective screens and flash goggles, if necessary, to shield
others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum,
this includes welder's gloves and protective face shield and may
include arm protectors, aprons, hats, shoulder protection, as well as
dark substantial clothing. Train the welder not to touch live
electrical parts and to insulate himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty
or guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 305 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essen-tially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL:(852) 2577 5187
Form OSHA 20. FAX:(852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 305 T.I.G.
SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of
welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:

Welding fumes cannot be classified simply. The composition and quantity of


both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limits for hexavalent chromium is 0.05mg/m3
and for nickel is 1mg/m3, which will result in a significant reduction from
the 5mg/m3 general fume level. Gaseous reaction products may include carbon
monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the
radiation from the arc, in addition to the shielding gases like argon and
helium, whenever they are employed.

Magna 305 T.I.G. Page 1


One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m 3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity

OSHA regulated : Nickel, Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.

Magna 305 T.I.G. Page 2


Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 305 T.I.G. Page 3


MATERIAL SAFETY DATA SHEET MAGNA INDUSTRIAL CO. LIMITED
FILIER METALS AND WELDING ROD 18/F., GUARDIAN HOUSE, HONG KONG.
"Essentially Similar" to U.S. TEL : (852) 2577 5187
Department of Labor Form OSHA 20. FAX : (852) 2577 3190

IDENTITY(As Used on Label and List) LAST ACCESSED : 4 October 1996


Magna 307

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous Ingredients CAS NO. TLV Hazard

Iron 7439-89-6 5mg/m3(as Fe2O3) Fume

Potassium silicate 1312-76-1 5mg/m3 -

Feldspar 68476-25-5 2mg/m3 -

Titanium dioxide 13463-67-7 10mg/m3 Dust

Silicon dioxide 14808-60-7 0.1mg/m3 Dust

Cellulose 9004-34-6 10mg/m3 -


SECTION II - PHYSICAL DATA

N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA

Welding arc and sparks can ignite combustibles and flammables. Refer to American
National StandardZ49.1 for fire prevention during the use of welding and allied
procedures.

SECTION IV – REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS
Welding fumes cannot be classified simply. The composition and quantity of both are
dependent upon the metal being welded, the process, procedures and electrodes used. Other
conditions which also influence the composition and quantity of the fumes and gases to
which workers may be exposed include : coatings on the metal being welded (such as paint,
plating, or galvanizing), number of welds and volume of work area, quality and amount of
ventilation, position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from
cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are different in
percent and form from the ingredients listed in Section I. Fume and gas decomposition
products, not the ingredients in the electrode, are important. Decomposition products
include those originating from the volatilization, reaction, or oxidation of the materials

Magna 307 Page 1


shown in Section I plus those from base metal, coating, etc. as noted above. These
components are virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product includes a
complex of the oxides of the materials listed in Section I. Gaseous reaction products may
include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the
radiation from the arc.

One recommended way to determine the composition and quantity of fumes and gases to which
workers are exposed is to take an air sample inside the welders helmet, if worn, or in the
worker's breathing zone. ANSI/AWS F1.1, available from the American Welding Society, P.O.
Box 351040,Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise Classified) is 5
mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should be used as guides in the
control of health hazards and should not be used as firm lines between safe and dangerous
concentrations." See Section IV for specific fume constituents which may modify this TLV.

Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE) OVEREXPOSURE to welding
fumes may result in discomfort such as: dizziness, nausea, or dryness or irritation of
nose, throat, or eyes. LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect pulmonary function. ARC RAYS
can injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VI.

Emergency & First Aid Procedures:

Call for medical aid. Employ first aid techniques recommended by the American Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary label on this
product. See American National Standard Z-49.1, Safety in Welding and Cutting, published
by the American Welding Society, P.O.Box 351040, Miami, FL 33135 and OSHA Publication 2206
(29 C.F.R. 1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail
on many of the following:

Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes and gases
below the TLV's in the worker's breathing zone and the general area. Train the welder to
keep his head out of the fumes.

Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in confined space
or where local exhaust or ventilation does not keep exposure below TLV.

Magna 307 Page 2


Eye Protection:
Wear helmet or use face shield with filler lens. As a rule of thumb, start with a shade
which is too dark to see the weld zone. Then go to the next lighter shade which gives
sufficient view of the weld zone. Provide protective screens and flash goggles, if
necessary, to shield others.

Protective Clothing:
Wear head, hand and body protection which help to prevent injury from radiation, sparks
and electrical shock. See ANSI Z-49.1. At a minimum, this includes welder's gloves and a
protective face shield and may include arm protectors, aprons, hats, shoulder protection,
as well as dark substantial clothing. Train the welder not to touch live electrical parts
and to insulate himself from work and ground.

Procedure for Cleanup of Spills or Leaks:


Not applicable.

Waste Disposal Method:


Prevent waste from contaminating surrounding environment. Discard any product, residue,
disposable container, or liner in an environmentally acceptable manner, in full compliance
with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations contained


herein are reliable, but they are given without warranty or guarantee of any
kind, express or implied, and we assume no responsibility for any loss, damage,
or expense, direct or consequential, arising out of their use.

Magna 307 Page 3


MATERIAL SAFETY DATA SHEET MAGNA INDUSTRIAL CO. LIMITED
FILIER METALS AND WELDING ROD 18/F., GUARDIAN HOUSE, HONG KONG.
"Essentially Similar" to U.S. TEL : (852) 2577 5187
Department of Labor Form OSHA 20. FAX : (852) 2577 3190

IDENTITY(As Used on Label and List) LAST ACCESSED : 4 October 1996


Magna 393

SECTION I – HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Graphite 7782-42-5 2mg/m3 Dust
Titanium dioxide 13463-67-7 10mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
SECTION II – PHYSICAL DATA
N.A.

SECTION III – FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to American
National StandardZ49.1 for fire prevention during the use of welding and allied
procedures.

SECTION IV – REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of both are
dependent upon the metal being welded, the process, procedures and electrodes used. Other
conditions which also influence the composition and quantity of the fumes and gases to
which workers may be exposed include : coatings on the metal being welded (such as paint,
plating, or galvanizing), number of welds and volume of work area, quality and amount of
ventilation, position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from
cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are different in
percent and form from the ingredients listed in Section I. Fume and gas decomposition
products, not the ingredients in the electrode, are important. Decomposition products
include those originating from the volatilization, reaction, or oxidation of the materials
shown in Section I plus those from base metal, coating, etc. as noted above. These
components are virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product includes
fluorides and a complex of the oxides of the materials listed in Section I. The present
OSHA permissible exposure limits for hexavalent chromium is 0.05mg/m3 and for nickel is

Magna 393 Page 1


1mg/m3, which will result in a significant reduction from the 5mg/m3 general fume level.
Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and gases to which
workers are exposed is to take an air sample inside the welders helmet, if worn, or in the
worker's breathing zone. ANSI/AWS F1.1, available from the American Welding Society, P.O.
Box 351040,Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise Classified) is 5
mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should be used as guides in the
control of health hazards and should not be used as firm lines between safe and dangerous
concentrations. "See Section IV for specific fume constituents which may modify this TLV.

Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE) OVEREXPOSURE to welding
fumes may result in discomfort such as: dizziness, nausea, or dryness ot irritation of
nose, throat, or eyes. LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect pulmonary function. ARC RAYS
can injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VI.

Emergency & First Aid Procedures:


Call for medical aid. Employ first aid techniques recommended by the American Red Cross.
Carcinogenicity
OSHA regulated : Nickel, Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary label on this
product. See American National Standard Z-49.1, Safety in Welding and Cutting, published
by the American Welding Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206
(29 C.F.R. 1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail
on many of the following:

Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes and gases
below the TLV's in the worker's breathing zone and the general area. Train the welder to
keep his head out of the fumes.

Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in confined space
or where local exhaust or ventilation does not keep exposure below TLV.

Eye Protection:
Wear helmet or use face shield with filler lens. As a rule of thumb, start with a shade
which is too dark to see the weld zone. Then go to the next lighter shade which gives
sufficient view of the weld zone. Provide protective screens and flash goggles, if
necessary, to shield others.

Magna 393 Page 2


Protective Clothing:
Wear head, hand and body protection which help to prevent injury from radiation, sparks
and electrical shock. See ANSI Z-49.1. At a minimum, this includes welder's gloves and a
protective face shield and may include arm protectors, aprons, hats, shoulder protection,
as well as dark substantial clothing. Train the welder not to touch live electrical parts
and to insulate himself from work and ground.

Procedure for Cleanup of Spills or Leaks:


Not applicable.

Waste Disposal Method:


Prevent waste from contaminating surrounding environment. Discard any product, residue,
disposable container, or liner in an environmentally acceptable manner, in full compliance
with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations contained


herein are reliable, but they are given without warranty or guarantee of any kind,
express or implied, and we assume no responsibility for any loss, damage, or
expense, direct or consequential, arising out of their use.

Magna 393 Page 3


MATERIAL SAFETY DATA SHEET MAGNA INDUSTRIAL CO. LIMITED
FILIER METALS AND WELDING ROD 18/F., GUARDIAN HOUSE, HONG KONG.
"Essentially Similar" to U.S. TEL : (852) 2577 5187
Department of Labor Form OSHA 20. FAX : (852) 2577 3190

IDENTITY(As Used on Label and List) LAST ACCESSED : 4 October 1996


Magna 395

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Silicon 7440-21-3 10mg/m3 Dust
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Graphite 7782-42-5 2mg/m3 Dust
Titanium dioxide 13463-67-7 10mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to American National
StandardZ49.1 for fire prevention during the use of welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of both are
dependent upon the metal being welded, the process, procedures and electrodes used. Other
conditions which also influence the composition and quantity of the fumes and gases to
which workers may be exposed include : coatings on the metal being welded (such as paint,
plating, or galvanizing), number of welds and volume of work area, quality and amount of
ventilation, position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from
cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are different in
percent and form from the ingredients listed in Section I. Fume and gas decomposition
products, not the ingredients in the electrode, are important. Decomposition products
include those originating from the volatilization, reaction, or oxidation of the materials
shown in Section I plus those from base metal, coating, etc. as noted above. These
components are virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product includes
fluorides and a complex of the oxides of the materials listed in Section I. The present
OSHA permissible exposure limits for hexavalent chromium is 0.05mg/m3 and for nickel is
1mg/m3, which will result in a significant reduction from the 5mg/m3 general fume level.

Magna 395 Page 1


Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and gases to which
workers are exposed is to take an air sample inside the welders helmet, if worn, or in the
worker's breathing zone. ANSI/AWS F1.1, available from the American Welding Society, P.O.
Box 351040,Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise Classified) is 5
mg/m3. The ACGIH 1984-85 preface states:" The TLV-TWA should be used as guides in the
control of health hazards and should not be used as firm lines between safe and dangerous
concentrations." See Section IV for specific fume constituents which may modify this TLV.

Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE) OVEREXPOSURE to welding
fumes may result in discomfort such as: dizziness, nausea, or dryness ot irritation of
nose, throat, or eyes. LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect pulmonary function. ARC RAYS
can injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VI.

Emergency & First Aid Procedures:

Call for medical aid. Employ first aid techniques recommended by the American Red Cross.
Carcinogenicity
OSHA regulated : Nickel, Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary label on this
product. See American National Standard Z-49.1, Safety in Welding and Cutting, published
by the American Welding Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206
(29 C.F.R. 1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail
on many of the following:

Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes and gases
below the TLV's in the worker's breathing zone and the general area. Train the welder to
keep his head out of the fumes.

Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in confined space
or where local exhaust or ventilation does not keep exposure below TLV.

Eye Protection:
Wear helmet or use face shield with filler lens. As a rule of thumb, start with a shade
which is too dark to see the weld zone. Then go to the next lighter shade which gives
sufficient view of the weld zone. Provide protective screens and flash goggles, if
necessary, to shield others.

Magna 395 Page 2


Protective Clothing:
Wear head, hand and body protection which help to prevent injury from radiation, sparks
and electrical shock. See ANSI Z-49.1. At a minimum, this includes welder's gloves and a
protective face shield and may include arm protectors, aprons, hats, shoulder protection,
as well as dark substantial clothing. Train the welder not to touch live electrical parts
and to insulate himself from work and ground.

Procedure for Cleanup of Spills or Leaks:


Not applicable.

Waste Disposal Method:


Prevent waste from contaminating surrounding environment. Discard any product, residue,
disposable container, or liner in an environmentally acceptable manner, in full compliance
with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations contained


herein are reliable, but they are given without warranty or guarantee of any kind,
express or implied, and we assume no responsibility for any loss, damage, or
expense, direct or consequential, arising out of their use.

Magna 395 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 400

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Silicon 7440-21-3 10mg/m3 Dust
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Titanium dioxide 13463-67-7 10mg/m3 Dust
Graphite 7782-42-5 2mg/m3 Dust
Calcium carbonate 1317-65-3 10mg/m3 Fume
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limits for hexavalent
chromium is 0.05mg/m3, which will result in a significant reduction from the
5mg/m3 general fume level. Gaseous reaction products may include carbon
monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the
radiation from the arc.

Magna 400 Page 1


One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from

Magna 400 Page 2


radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 400 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 401

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Titanium dioxide 13463-67-7 10mg/m3 Dust
Graphite 7782-42-5 2mgk/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Calcium carbonate 1317-65-3 10mg/m3 Dust
Silicate binder 6843-92-0 & 10mg/m3 -
12627-14-4 &
10006-28-7
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for hexavalent chromium is 0.05mg/m3 ,
which will result in a significant reduction from the 5mg/m3 general fume
level. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the

Magna 401 Page 1


arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:

Magna 401 Page 2


Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 401 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 402

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Titanium dioxide 13463-67-7 10mg/m3 Dust
Graphite 7782-42-5 2mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Calcium carbonate 1317-65-3 10mg/m3 Dust
Silicate binder 6834-92-0 & 10mg/m3 -
12627-14-4 &
1006-28-7
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limits for nickel is 1mg/m3, which will
result in a significant reduction from the 5mg/m3 general fume level. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

Magna 402 Page 1


One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from

Magna 402 Page 2


radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 402 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 403

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Titanium dioxide 13463-67-7 10mg/m3 Dust
Graphite 7782-42-5 2mg/m3 Dust
Calcium carbonate 1317-65-3 10mg/m3 Fume
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for hexavalent chromium is 0.05mg/m3,
which will result in a significant reduction from the 5mgk/m3 general fume
level. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the
arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders

Magna 403 Page 1


helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial

Magna 403 Page 2


clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 403 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 404

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 5mg/m3 Fume
Tungsten 7440-33-7 5mg/m3(Insoluble) -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. Gaseous
reaction products may include carbon monoxide and carbon dioxide. Ozone and
nitrogen oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:

Magna 404 Page 1


The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.

Magna 404 Page 2


Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.
Notes: We believe the statements, technical information and recommendations
contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 404 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to 18/F., GUARDIAN HOUSE, HONG KONG.
U.S.Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 405

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Titanium dioxide 13463-67-7 10mg/m3 Dust
Silicate binder 6834-92-0 & 10mg/m3 -
12627-14-4 & 10006-28-7
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Silicon dioxide 14808-60-7 0.1mg/m3 Dust
Calcium carbonate 1317-65-3 10mg/m3 Dust
Graphite 7782-42-5 2mg/m3 Dust
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of
welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Magna 405 Page 1


Reasonably expected decomposition products from normal use of this product
includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limits for hexavalent
chromium is 0.05mg/m3, which will result in a significant reduction from the
5mg/m3 general fume level. Gaseous reaction products may include carbon
monoxide and carbondioxide. Ozone and nitrogen oxides may be formed by the
radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA
should be used as guides in the control of health hazards and should
not be used as firm lines between safe and dangerous concentrations."
See Section IV for specific fume constituents which may modify this
TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as:
dizziness, nausea, or dryness or irritation of nose, throat, or eyes.
LONG TERM (CHRONIC) OVEREXPOSURE may cause lung fibrosis or
pneumoconiosis and is believed by some investigators to affect
pulmonary function. ARC RAYS can injure eyes and burn skin. ELECTRIC
SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in

Magna 405 Page 2


confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 405 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 440

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Vanadium 7440-62-2 0.05mg/m3(as V2O5) Fume
Silicon 7440-21-3 10mg/m3 Dust
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Tungsten 7440-33-7 5mg/m3(Insoluble) -
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Titanium dioxide 13463-67-7 10mg/m3 Dust
Potassium silicate 1312-76-1 5mg/m3 -
Sodium silicate 1344-09-8 5mg/m3 -
Zirconium silicate 14940-68-2 5mg/m3(as Zr) -
Potassium titanate 12030-97-6 10mg/m3 -
Calcium carbonate 1317-65-3 10mg/m3 Dust
Magnesite 546-93-0 10mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Silicon dioxide 14808-60-7 0.1mg/m3 Dust
Bentonite 70131-50-9 10mg/m3 -
Cellulose 9004-34-6 10mg/m3 -
Talc 14807-96-6 2mg/m3 -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals

Magna 440 Page 1


(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


fluorides and a complex of the oxides of the materials listed in Section I.
The present OSHA permissible exposure limit for hexavalent chromium is
0.05mg/m3, which will result in a significant reduction from the 5mg/m3
general fume level. Gaseous reaction products may include carbon monoxide and
carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from
the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.

Magna 440 Page 2


Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.

Waste Disposal Method:


Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 440 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 440 T.I.G.

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Vanadium 7440-62-2 0.05mg/m3(as V2O5) Fume
Silicon 7440-21-3 10mg/m3 Dust
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Tungsten 7440-33-7 5mg/m3(Insoluble) -
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for hexavalent chromium is 0.05mg/m3,
which will result in a significant reduction from the 5mg/m3 general fume
level. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the
arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders

Magna 440 T.I.G. Page 1


helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial

Magna 440 T.I.G. Page 2


clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 440 T.I.G. Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL : (852) 2577 5187
Form OSHA 20. FAX : (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED: 04/10/1996
Magna 480

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Silicon 7440-21-3 10mg/m3 Dust
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Tungsten 7440-33-7 5mg/m3(Insoluble) -
Vanadium 7440-62-2 0.05mg/m3(as V2O5) Fume
Calcium carbonate 1317-65-3 10mg/m3 Dust
Barium carbonate 513-77-9 0.5mg/m3(as Ba) -
Titanium dioxide 13463-67-7 10mg/m3 Dust
Potassium oxalate 6487-48-5 5mg/m3 -
Sodium silicate 1344-09-8 5mg/m3 -
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition product from normal use of this product


includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limit for hexavalent chromium

Magna 480 Page 1


is 0.05mg/m3, which will result in a significant reduction from the 5mg/m3
general fume level. Gaseous reaction products may include carbon monoxide and
carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from
the arc in welding.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective

Magna 480 Page 2


screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 480 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL : (852) 2577 5187
Form OSHA 20. FAX : (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED : 04/10/1996
Magna 480 T.I.G.

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Tungsten 7440-33-7 5mg/m3(Insoluble) -
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Silicon 7440-21-3 10mg/m3 Dust
Vanadium 7440-62-2 0.05mg/m3(as V2O5) Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both
are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limit for hexavalent chromium is 0.05mg/m3,
which will result in a significant reduction from the hmg/m3 general fume
level. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc
in welding.

Magna 480 T.I.G. Page 1


One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first and techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Chromium.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this

Magna 480 T.I.G. Page 2


includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 480 T.I.G. Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentailly Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL : (852) 2577 5187
Form OSHA 20. FAX : (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED : 04/10/1996
Magna 505

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Aluminium 7429-90-5 5mg/m3 Fume
Silicon 7440-21-3 10mg/m3 Dust
Aluminium fluoride 7784-18-1 2.5mg/m3(as F) -
Lithium fluoride 7789-24-4 2.5mg/m3(as F) -
Magnesium fluoride 7783-40-6 2.5mg/m3(as F) -
Potassium chloride 7447-40-7 - -
Sodium chloride 7647-14-5 - -
Cryolite 15096-52-3 2.5mg/m3(as F) -
Potassium hydroxide 1310-58-3 2mg/m3(CL) Corrosiv
e
Lithium chloride 7447-41-8 - -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes fluorides, chlorides and a complex of the oxides of the materials
listed in Section I. Gaseous reaction products may include carbon monoxide and
carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from

Magna 505 Page 1


the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
None

SECTION VI – PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:

Magna 505 Page 2


Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.
Remark:
CL = Ceiling value

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume to
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 505 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILIER METALS AND WELDING ROD MAGNA WELDING ALLOYS
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL : (852) 2577 5187
Form OSHA 20. FAX : (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED : 4 October 1996
Magna 711

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Copper 7440-50-8 0.2mg/m3 Fume
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Titanium dioxide 13463-67-7 10mg/m3 Dust
Calcium carbonate 1317-65-3 10mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Silicon dioxide 14808-60-7 0.1mg/m3 Dust
Silicate binder 6834-92-0 & 10mg/m3 -
12627-14-4 & 10006-28-7
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinatedhydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important Decomposition products include those originating from the
volatilization reaction, or oxidation of the materials shown in Section I plus
those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limits for hexavalent
chromium is 0.05mg/m3Z and for nickel 1mg/m3, which will result in a

Magna 711 Page 1


significant reduction from the 5mg/m3 general fume level. Gaseous reaction
products may include carbon monoxide and carbon dioxide. Ozone and nitrogen
oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity
OSHA regulated: Chromium, Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more detail on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filler lens. As a rule of thumb, start
with shade which is too dark to see the weld zone. Then go to the next lighter
shade which gives sufficient view of the weld zone. Provide protective screens
and flash goggles, if necessary, to shield others.
Protective Clothing:

Magna 711 Page 2


Wear head, hand and body protection which help to prevent injury from
radiation sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
include welder's gloves and a protective face shield and may include arm
protectors aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product
residue, disposable container, or liner in an environmentally acceptable
manner in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage or expense, direct or consequential,
arising out of their use.

Magna 711 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED : 04/10/1996
Magna 720

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Aluminium 7429-90-5 5mg/m3 Fume
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Manganese 7439-96-5 1mg/m3 Fume
Sodium silicate 1344-09-8 5mg/m3 -
Graphite 7782-42-5 2mg/m3 Dust
Calcium carbonate 1317-65-3 10mg/m3 Dust
Barium carbonate 513-77-9 0.5mg/m3(as Ba) -
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes fluorides and a complex of the oxides of the materials listed in
Section I. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the
arc.

One recommended way to determine the composition and quantity of fumes and

Magna 720 Page 1


gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O.Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "ThE TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity
None

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial

Magna 720 Page 2


clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 720 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED : 04/10/1996
Magna 770

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Graphite 7782-42-5 2mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Strontium carbonate 1633-05-2 10mg/m3 -
Silicate binder 6834-92-0 & 10mg/m3 -
12627-14-4 & 10006-28-7
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of
welding and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or
galvanizing), number of welds and volume of work area, quality and amount
of ventilation, position of welder's head with respect to the fume plume,
as well as the presence of contaminants in the atmosphere (such as
chlorinated hydrocarbon vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I.
Fume and gas decomposition products, not the ingredients in the electrode,
are important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components
are virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limit for nickel is 1mg/m3,
which will result in a significant reduction from the 5mg/m3 general fume
level. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the
arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the
welders helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1,
available from the American Welding Society, P.O.Box 351040, Miami, FL
33135.

Magna 770 Page 1


SECTION V - HEALTH HAZARD DATA
Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "ThE TLV-TWA
should be used as guides in the control of health hazards and should not be
used as firm lines between safe and dangerous concentrations." See Section
IV for specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM
(CHRONIC) OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is
believed by some investigators to affect pulmonary function. ARC RAYS can
injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the
American Red Cross.
Carcinogenicity
OSHA regulated: Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL


MEASURES
Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many
of the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the
fumes and gases below the TLV's in the worker's breathing zone and the
general area. Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide
protective screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to
insulate himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:

Magna 770 Page 2


Prevent waste from contaminating surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local
regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty
or guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 770 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE , HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY (As Used on Label and List) LAST ACCESSED : 04/10/1996
Magna 777

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Calcium carbonate 1317-65-3 10mg/m3 Dust
Barium carbonate 513-77-9 0.5mg/m3(as Ba) -
Graphite 7782-42-5 2mg/m3 Dust
Potassium silicate 1312-76-1 5mg/m3 -
Sodium silicate 1344-09-8 5mg/m3 -
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Iron oxide 1317-61-9 5mg/m3(as Fe2O3) Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limit for nickel is 1mg/m3,
which will result in a significant reduction from the 5mg/m3 general fume
level. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the

Magna 777 Page 1


arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "ThE TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity
OSHA regulated: Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from

Magna 777 Page 2


radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 777 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILIER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL : (852) 2577 5187
Form OSHA 20. FAX : (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED : 4 October 1996
Magna 8N12

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Manganese 7439-96-5 1mg/m3 Fume
Columbium 7440-03-1 5mg/m3 Fume
Barium carbonate 513-77-9 0.5mg/m3(as Ba) -
Silicon dioxide 14808-60-7 0.1mg/m3 Dust
Calcium fluoride 7789-75-5 2.5mg/m3(as F) -
Titanium dioxide 13463-67-7 10mg/m3 Dust
Sodium titanate 12034-34-2 10mg/m3 -
Potassium titanate 12030-97-6 10mg/m3 -
Aluminium oxide 1344-28-1 10mg/m3 -
Calcium carbonate 1317-65-3 10mg/m3 Dust
Cryolite 15096-52-3 2.5mg/m3(as F) -
Silicate binder 6834-92-0 & 10mg/m3 -
12627-14-4 & 10006-28-7
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

M-8N12.1
Reasonably expected decomposition products from normal use of this product
includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limits for hexavalent
chromium is 0.05mg/m3 and for nickel is 1mg/m3, which will result in a
significant reduction from the 5mg/m3 general fume level. Gaseous reaction
products may include carbon monoxide and carbon dioxide. Ozone and nitrogen
oxides may be formed by the radiation from the arc.

One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O. Box
51040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity
OSHA regulated: Chromium, Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train
the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.

Magna 8N12 Page 2


Eye Protection:
Wear helmet or use face shield with filler lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from wourk and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Note: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 8N12 Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED : 04/10/1996
Magna 8N12T.I.G.

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Manganese 7439-96-5 1mg/m3 Fume
Columbium 7440-03-1 5mg/m3 Fume
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes a complex of the oxides of the materials listed in Section I. The
present OSHA permissible exposure limits for hexavalent chromium is 0.05mg/m3
and for nickel is 1mg/m3, which will result in a significant reduction from
the 5mg/m3 general fume level. Gaseous reaction products may include carbon
monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the
radiation.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:

Magna 8N12 T.I.G. Page 1


The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface states: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity
OSHA regulated: Chromium, Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read the understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this
includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:

Magna 8N12 T.I.G. Page 2


Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 8N12 T.I.G. Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
FILLER METALS AND WELDING ROD MAGNA INDUSTRIAL CO. LIMITED
"Essentially Similar" to U.S. 18/F., GUARDIAN HOUSE, HONG KONG.
Department of Labor TEL: (852) 2577 5187
Form OSHA 20. FAX: (852) 2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED : 04/10/1996
Magna Alloy C

SECTION I - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION


Hazardous Ingredients CAS NO. TLV Hazard
Chromium 7440-47-3 0.5mg/m3(Metal) Fume
Molybdenum 7439-98-7 10mg/m3(Metal) Fume
Tungsten 7440-33-7 5mg/m3(Insoluble) -
Cobalt 7440-48-4 0.05mg/m3 Fume
Iron 7439-89-6 5mg/m3(as Fe2O3) Fume
Nickel 7440-02-0 1mg/m3(Metal) Fume
Sodium fluoride 7681-49-4 2.5mg/m3(as F) -
Potassium fluoride 7789-23-3 2.5mg/m3(as F) -
Manganese oxide 1317-35-7 1mg/m3 -
SECTION II - PHYSICAL DATA
N.A.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Welding arc and sparks can ignite combustibles and flammables. Refer to
American National Standard Z49.1 for fire prevention during the use of welding
and allied procedures.

SECTION IV - REACTIVITY DATA


HAZARDOUS DECOMPOSITION PRODUCTS:
Welding fumes cannot be classified simply. The composition and quantity of
both are dependent upon the metal being welded, the process, procedures and
electrodes used. Other conditions which also influence the composition and
quantity of the fumes and gases to which workers may be exposed include:
coatings on the metal being welded (such as paint, plating, or galvanizing),
number of welds and volume of work area, quality and amount of ventilation,
position of welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon
vapors from cleaning and degreasing activities).

When the electrode is consumed, the fume and gas decomposition products are
different in percent and form from the ingredients listed in Section I. Fume
and gas decomposition products, not the ingredients in the electrode, are
important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the materials shown in Section I
plus those from base metal, coating, etc. as noted above. These components are
virtually always present as complex compounds and not as metals
(Characterization of Arc Welding Fume: American Welding Society).

Reasonably expected decomposition products from normal use of this product


includes fluorides and a complex of the oxides of the materials listed in
Section I. The present OSHA permissible exposure limits for hexavalent
chromium is 0.05mg/m3 and for nickel is 1mg/m3, which will result in a
significant reduction from the 5mg/m3 general fume level. Gaseous reaction
products may include carbon monoxide and carbon dioxide. Ozone and nitrogen
oxides may be formed by the radiation from the arc.

Magna Alloy C Page 1


One recommended way to determine the composition and quantity of fumes and
gases to which workers are exposed is to take an air sample inside the welders
helmet, if worn, or in the worker's breathing zone. ANSI/AWS F1.1, available
from the American Welding Society, P.O.Box 351040, Miami, FL 33135.

SECTION V - HEALTH HAZARD DATA


Threshold Limit Value:
The ACGIH recommended general limit for welding fume NOC (Not Otherwise
Classified) is 5 mg/m3. The ACGIH 1984-85 preface States: "The TLV-TWA should
be used as guides in the control of health hazards and should not be used as
firm lines between safe and dangerous concentrations." See Section IV for
specific fume constituents which may modify this TLV.
Effects of Overexposure:
FUMES AND GASES can be dangerous to your health. SHORT-TERM (ACUTE)
OVEREXPOSURE to welding fumes may result in discomfort such as: dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. LONG TERM (CHRONIC)
OVEREXPOSURE may cause lung fibrosis or pneumoconiosis and is believed by some
investigators to affect pulmonary function. ARC RAYS can injure eyes and burn
skin. ELECTRIC SHOCK can kill. See Section VI.
Emergency & First Aid Procedures:
Call for medical aid. Employ first aid techniques recommended by the American
Red Cross.
Carcinogenicity
OSHA Regulated: Chromium, Nickel.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES


Read and understand the manufacturer's instructions and the precautionary
label on this product. See American National Standard Z-49.1, Safety in
Welding and Cutting, published by the American Welding Society, P.O. Box
351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U.S.
Government Printing Office, Washington, D.C. 20402 for more details on many of
the following:
Ventilation:
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes
and gases below the TLV's in the worker's breathing zone and the general area.
Train the welder to keep his head out of the fumes.
Respiratory Protection:
Use respirable fume respirator or air supplies respirator when welding in
confined space or where local exhaust or ventilation does not keep exposure
below TLV.
Eye Protection:
Wear helmet or use face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the weld zone. Then go to the next
lighter shade which gives sufficient view of the weld zone. Provide protective
screens and flash goggles, if necessary, to shield others.
Protective Clothing:
Wear head, hand and body protection which help to prevent injury from
radiation, sparks and electrical shock. See ANSI Z-49.1. At a minimum, this

Magna Alloy C Page 2


includes welder's gloves and a protective face shield and may include arm
protectors, aprons, hats, shoulder protection, as well as dark substantial
clothing. Train the welder not to touch live electrical parts and to insulate
himself from work and ground.
Procedure for Cleanup of Spills or Leaks:
Not applicable.
Waste Disposal Method:
Prevent waste from contaminating surrounding environment. Discard any product,
residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with Federal, State and Local regulations.

Notes: We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee of any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna Alloy C Page 3


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 904

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Sodium metasilicate 6834-92-0 - *
Bentonite 1302-78-9 - -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.65
Vapor Pressure (mm Hg. ) 8.0 Melting Point N.A.
Vapor Density (AIR = 1) 1.0 Evaporation Rate (B.Acet=1) <1
Solubility in Water Dispersible
Appearance and Odor Apple green paste.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
N.A.
Special Fire Fighting Procedures
N.A.
Unusual Fire and Explosion Hazards
N.A.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
None
Hazardous Decomposition or Products
None
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
May have mild irritation effect in case of eye contact.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Wipe up, rinse contaminated area with water.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Dry storage at ambient temperatures, keep containers tightly closed
and away from foodstuffs. Keep from freezing.
Other Precautions
Keep out of reach of children.
Magna 904 Page 1
SECTION VII - CONTROL MEASURES
Respiratory Protection (Specify Type)
None required in normal use.
Ventilation Local Exhaust Special
N.A. N.A.
Mechanical (General) Other
N.A. N.A.
Protective Gloves Eye Protection
None required in normal use. None required in normal use.
Other Protective Clothing or Equipment
N.A.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* orl-rat LD50: 1280mg/kg

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 904 Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 940

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
2,4,6, Tri (dimethylaminomethyl) 90-72-2 - -
Phenol
Epoxy Resin (Diglycidyl Ether of 25068-38-6 * -
Bisphenol A)
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point N.A. Specific Gravity (H20 = 1) 1.9
Vapor Pressure (- ) N.A. Melting Point N.A.
Vapor Density (AIR = 1) N.A. Evaporation Rate (- ) N.A.
Solubility in Water Insoluble
Appearance and Odor Brown stick with white core. No special odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
Water spray, foam, CO2 or dry chemicals.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
May generate toxic or irritating combustion products.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable None
Incompatibility (Materials to Avoid)
None
Hazardous Decomposition or Products
Aldehydes, acids, oxides of sulphur and nitrogen by pyrolysis.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Possible sensitizer on skin contact. Possible sensitizer on eye
contact.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.
Swallowing: Induce vomiting. Call a physician, advise of Section I.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt

Magna 940 Page 1


N.A.
Waste Disposal Method
Dispose of in accordance with Federal, State and local regulations.
Precautions to Be Taken in Handling and Storing
Dry storage at ambient temperatures.
Other Precautions
Remove and professionally wash contaminated clothing before re-use.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
None reguired for normal use.
Ventilation Local Exhaust Special
Necessary only if heated above 38C. -
Mechanical (General) Other
- -
Protective Gloves Eye Protection
Polyethylene gloves for prolonged use Chemical safety goggles
Other Protective Clothing or Equipment
N.A.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* orl-rat LD50: 20g/kg

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 940 Page 2


MATERIAL SAFETY DATA SHEET MAGNA WELDING ALLOYS
May be used to comply with OSHA's Hazard MAGNA INDUSTRIAL CO. LIMITED
Communication Standard, 29 CFR 1910. 1200, 18/F, GUARDIAN HOUSE, HONG KONG
Standard must be consulted for specific
requirements TEL: (852)2577 5187
FAX: (852)2577 3190
IDENTITY(As Used on Label and List) LAST ACCESSED: 04/10/1996
MAGNA 990

SECTION I - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION


Hazardous Components Other Limits
(Specific Chemical Identity: Common Name(s)) CAS NO. TLV Recommended
Trichloroethylene 79-01-6 50ppm -
SECTION II - PHYSICAL CHARACTERISTICS
Boiling Point 86C Specific Gravity (H20 = 1) 1.46
Vapor Pressure (Psig ) 52+-5 * Melting Point -
Vapor Density (AIR = 1) >1 Evaporation Rate (Ether=1) <1
Solubility in Water Insoluble
Appearance and Odor Colorless, volatile liquid with chlorinated hydrocarbon odor.

SECTION III - FIRE AND EXPLOSION HAZARD DATA


Flash Point (Method Used) Flammable Limits LEL UEL
None N.A. N.A.
Extinguishing Media
CO2, dry chemicals or foam.
Special Fire Fighting Procedures
Use NIOSH approved self-contained breathing apparatus and full protective
clothing if involved in fire.
Unusual Fire and Explosion Hazards
At elevated temperature (over 50C) cans may burst, vent or rupture.

SECTION IV - REACTIVITY DATA


Stability Conditions to Avoid
Stable High heat may induce thermal decomposition.
Incompatibility (Materials to Avoid)
Water (Slow hydrolysis produces corrosive acid)
Hazardous Decomposition or Products
By open flame: Carbon dioxide, carbon dioxide, hydrogen chloride and
phosgene.
Hazardous Conditions to Avoid
Polymerization None
Will Not Occur
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value
See Section I hazardous ingredients.
Effects of Overexposure
Anesthetic effects - may occur in the range of 500 to 1000ppm.
Emergency & First Aid Procedures
Eye contact: Remove from exposure, wash eye thoroughly with cool water
for at least 15 minutes; consult physician.
Skin contact: Wash and rinse thoroughly. If symptoms develop, call
physician.

SECTION VI - PRECAUTIONS FOR SAFE HANDLING AND USE


Steps to Be Taken In Case Material Is Released or Spilt
Remove all sources of ignition. Ventilate and remove with inert
absorbent.
Waste Disposal Method
Do not puncture or incinerate containers. Give to a disposal service
Magna 990 Page 1
equipped to safely handle and dispose of pressurized containers.
Precautions to Be Taken in Handling and Storing
Do not store above 50C. Keep at room temperature as exposure to direct
sunlight may cause bursting.
Other Precautions
Keep out of reach of children. Do not spray near fire or open flame.
Do not puncture or incinerate. Read entire label before using.

SECTION VII - CONTROL MEASURES


Respiratory Protection (Specify Type)
Use NIOSH approved self-contained breathing apparatus if above TLV
limit exceeding.
Ventilation Local Exhaust Special
Adequate ventilation -
Mechanical (General) Other
Required -
Protective Gloves Eye Protection
None required in normal use Chemical safety goggles
Other Protective Clothing or Equipment
N.A.
Work/Hygienic Practices
Wash exposed areas with soap and water before eating.
Remarks
* In container

We believe the statements, technical information and recommendations


contained herein are reliable, but they are given without warranty or
guarantee for any kind, express or implied, and we assume no
responsibility for any loss, damage, or expense, direct or
consequential, arising out of their use.

Magna 990 Page 2

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