CHEMICAL PROPER Abe Assignment-WPS Office
CHEMICAL PROPER Abe Assignment-WPS Office
CHEMICAL PROPER Abe Assignment-WPS Office
Water is a colourless, transparent, odourless liquid that forms the seas, lakes, rivers, and rain and is the
basis of the fluids of living organisms.
1. Surface Tension :
Besides mercury, water has the highest surface tension for all liquids. Water's high surface tension is
due to the hydrogen bonding in water molecules. Viscosity is the property of fluid having high resistance
to flow. We normally think of liquids like honey or motor oil being viscous, but when compared to other
substances with like structures, water is viscous. Liquids with stronger intermolecular interactions are
usually more viscous than liquids with weak intermolecular interactions. Cohesion is intermolecular
forces between like molecules; this is why water molecules are able to hold themselves together in a
drop. Water molecules are very cohesive because of the molecule's polarity. This is why you can fill a
glass of water just barely above the rim without it spilling.
2. Heat of Vaporization
Water also has an exceptionally high heat of vaporization. Vaporization occurs when a liquid changes to
a gas, which makes it an endothermic reaction. Water's heat of vaporization is 41 kJ/mol.
3. Vapor Pressure :
Vapor pressure is inversely related to intermolecular forces, so those with stronger intermolecular
forces have a lower vapor pressure. Water has very strong intermolecular forces, hence the low vapor
pressure, but it's even lower compared to larger molecules with low vapor pressures.
Because of water's polarity, it is able to dissolve or dissociate many particles. Oxygen has a slightly
negative charge, while the two hydrogens have a slightly positive charge. The slightly negative particles
of a compound will be attracted to water's hydrogen atoms, while the slightly positive particles will be
attracted to water's oxygen molecule; this causes the compound to dissociate. Besides the explanations
above, we can look to some attributes of a water molecule to provide some more reasons of water's
uniqueness:
Forgetting fluorine, oxygen is the most electronegative non-noble gas element, so while forming
a bond, the electrons are pulled towards the oxygen atom rather than the hydrogen. This
creates 2 polar bonds, which make the water molecule more polar than the bonds in the other
hydrides in the group.
A 104.5° bond angle creates a very strong dipole.
Water has hydrogen bonding which probably is a vital aspect in waters strong intermolecular
interaction.
If you look at the periodic table and locate tellurium (atomic number: 52), you find that the boiling
points of hydrides decrease as molecule size decreases. So the hydride for tellurium: H2Te (hydrogen
telluride) has a boiling point of -4°C. Moving up, the next hydride would be H2Se (hydrogen selenide)
with a boiling point of -42°C. One more up and you find that H2S (hydrogen sulfide) has a boiling point at
-62°C. The next hydride would be H2O (WATER!). And we all know that the boiling point of water is
100°C. So despite its small molecular weight, water has an incredibly big boiling point. This is because
water requires more energy to break its hydrogen bonds before it can then begin to boil. The same
concept is applied to freezing point as well, as seen in the table below. The boiling and freezing points of
water enable the molecules to be very slow to boil or freeze, this is important to the ecosystems living in
water. If water was very easy to freeze or boil, drastic changes in the environment and so in oceans or
lakes would cause all the organisms living in water to die. This is also why sweat is able to cool our
bodies.