Chemistry
Chemistry
Chemistry
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GUIDED BY :
YEAR : 2022-2023
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Certified to be the bonafide work done by
EXAMINER
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DATE : ___________
SEAL
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I would like to express my sincere
gratitude to my chemistry mentor
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PRAKASH , for his vital support, guidance
and encouragement - without which this
project would not have come forth. I
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would also like to express my gratitude
to my chemistry teacher Mr.
VENKATESHWAR RAO for his support
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The Objective of this project is
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to study GREEN CHEMISTRY-
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Bio diesel and Bio petrol also
study extraction process of Bio
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desial.
INTRODUCTION TO GREEN CHEMISTY
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One of the most
important new
aspects of
chemistry is the
development of
GreenChemistry.
Supported by the
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American
Chemical Society,
the USEPA and
other Federal
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agencies, Green
Chemistry has
emerged as an
important aspect
of all chemistry.
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Green Chemistry
is the design of
chemical products
and processes that
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reduce oreliminate
the use and
generation of
hazardous
substances.
Green Chemistry
is based on
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Twelve Principles
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Green chemistry is the branch of chemistry concerned
with developing processes and products to reduce or
eliminate hazardous substances. One of the goals of
green chemistry is to prevent pollution at its source, as
opposed to dealing with pollution after it has
occurred.
Principles of Green Chemistry
1.
Prevention
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has been created.
It is better to
2. prevent waste than to treat or clean up waste after it
Atom Economy
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product.
Synthetic methods should be designed to maximize the
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incorporation
3. of all materials used in the process into the final
Less Hazardous
use andChemical
generate Syntheses
substances that possess little or no toxicity to
human health and the environment.
4.
Designing Safer Chemicals
Chemical products should be designed to effect their desired
function while minimizing their toxicity.
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5.
Safer Solvents and Auxiliaries
6.
Design for Energy Efficiency
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Energy requirements of chemical processes should be recognized
for their environmental and economic impacts and should be
minimized. If possible, synthetic methods should be conducted at
ambient temperature and pressure.
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7.
Use of Renewable Feedstocks
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8.
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Reduce Derivatives
Unnecessary derivatization (use of blocking groups, protection/
deprotection,temporary modification of physical/chemical
processes) should be minimized or avoided if possible, because
such steps require additional reagents and can generate waste. 9.
Catalysis
10.
Design for Degradation
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Chemical products should be designed so that at the end of their
function they break down into innocuous degradation products
and do not persist in the environment.
11.
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Real-time analysis for Pollution Prevention
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Biodiesel: using renewable resources
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Introduction
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Bio-diesel is an eco-friendly, alternative diesel fuel prepared from domestic
renewable resources i.e. vegetable oils (edible or nonedible oil) and animal
fats. These natural oils and fats are made up mainly of triglycerides. These
triglycerides when rea w striking similarity to petroleum derived diesel
and are called "Biodiesel". As India is deficient in edible oils, non-edible
oil may be material of choice for producing bio diesel . For this purpose
Jatropha curcas considered as most potential source for it. Bio diesel is
produced by transesterification of oil obtains from the plant.
Jatropha Curcas has been identified for India as the most suitable Tree
Borne Oilseed (TBO) for production of bio-diesel both in view of the non-
edible oil available from it and its presence throughout the country. The
capacity of Jatropha Curcas to rehabilitate degraded or dry lands, from
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which the poor mostly derive their sustenance, by improving land's water
retention capacity, makes it additionally suitable for up-gradation of land
resources. Presently, in some Indian villages, farmers are extracting oil
from Jatropha and after settling and decanting it they are mixing the
filtered oil with diesel fuel. Although, so far the farmers have not observed
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any damage to their machinery, yet this remains to be tested and PCRA is
working on it. The fact remains that this oil needs to be converted to bio-
diesel through a chemical reaction - trans-esterification. This reaction is
relatively simple and does not require any exotic material. IOC (R&D) has
been using a laboratory scale plant of 100 kg/day capacity for trans-
esterification; designing of larger capacity plants is in the offing. These
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separate into two layers, with the biodiesel on the top. The biodiesel is
separated and washed, and is then ready for further experimentation.
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What you will need
Eye protection
Access to a top pan balance
One 250 cm3 conical flask
Two 100 cm3 beakers
One 100 cm3 measuring cylinder
Five plastic teat pipettes
Distilled or deionised water
100 cm3 vegetable-based cooking oil
15 cm3 methanol (highly flammable, toxic by inhalation, if swallowed,
and by skin absorption)
1 cm3 potassium hydroxide solution 50% (corrosive).
Safety
What to do
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1. Measure 100 cm3 of vegetable oil into the 250 cm3 flask. Weigh the flask
before and after to determine the mass of oil you used.
2. Carefully add 15 cm3 of methanol.
3. Slowly add 1 cm3 of 50% potassium hydroxide.
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6. Carefully remove the top layer (this is impure biodiesel) using a teat
pipette.
7. Wash the product by shaking it with 10 cm3 of distilled or deionised
water.
8. Allow the mixture to stand until it separates into two layers.
9. Carefully remove the top layer of biodiesel using a teat pipette.
10.Weigh the amount of biodiesel you have collected and compare it to the
amount of vegetable oil you started with.
Mineral wool
To filter pump
A solution of
2 cm3 of fuel universal soaked in mineral indicator
wool
Eye protection
Small glass funnel (approximately 7 cm diameter)
One 250 cm3 flask
Two boiling tubes
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One two-hole stopper to fit the boiling tubes
Filter pump
A piece of wide bore glass tubing approximately 10 cm long with two one-
hole stoppers to fit
A piece of vacuum tubing approximately 35 cm long
Two short pieces of glass tubing to fit the one-hole stoppers
5 cm glass bend to fit the two-hole stopper
90o glass bend to fit the two-hole stopper (one leg to extend to bottom
of flask)
Two stands and clamps
Two small metal sample dishes
A littlesodium hydroxide solution 0.1 mol dm-3 (irritant)
Universal indicator solution A little mineral wool.
Safety
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What to do
1. Pour 125 cm3 of distilled water into the 250 cm3 flask and add 10 cm3 of
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universal indicator. Add one drop of 0.1 mol dm-3 sodium hydroxide
solution and gently swirl the flask so that the colour of the solution is
violet or at the most basic end of the universal indicator colour range.
2. Place 10 cm3 of this solution into the boiling tube.
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5. Turn on the water tap so the filter pump pulls air through the flask and
ignite the biodiesel. Position the funnel directly over the burning fuel, so
as to capture the fumes from the burning fuel. Mark or note the position
of the tap handle so you can run the pump at the same flow rate later in
the experiment.
6. Allow the experiment to run until the universal indicator turns yellow
and time how long this takes.
7. Record what happens in the funnel and in the glass tube containing the
second piece of mineral wool.
8. Clean the apparatus, and repeat the experiment using 2 cm 3 of kerosene
(this is very similar to diesel fuel).
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Activity 3: Potential for biofuels
1.Technical Feasibility
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3.Advantages of Jatropha
Jatropha Curcas is a widely occurring variety of TBO
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It grows practically all over India under a variety of agro climatic
conditions.
Can be grown in arid zones (20 cm rainfall) as well as in higher rainfall
zones and even on the land with thin soil cover.
Its plantation can be taken up as a quick yielding plant even in adverse
land situations viz. degraded and barren lands under forest and non-
forest use, dry and drought prone areas, marginal lands, even on alkaline
soils and as agro-forestry crops.
It grows as a tree up to the height of 3 - 5 mt.
It is a good plantation for Eco-restoration in all types wasteland.
4.Agro Practices (as per NOVOD, Ministry of Agriculture, GOI)
Nursery raising
Nurseries may be raised in poly-bags filled with mixture of soil and farm
yard manure in the ratio of 4:1.
Two seeds are sown in each bag.
Plantation
30 cm x 30 cm x 30 cm pits are dug
Farm yard manure (2-3 kg), 20 gm urea, 12 gm Single Super
Phosphate (SSP) & 16 gm Mono Phosphate (MP)
Planting density
2500 plants / ha at 2m x 2m
Transplantation
It should be done during rainy reason.
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Fertilizer
From second year in the ratio of 40:60:20 Nitrogen Phosphorous and
Potassium (NPK) kg/ha
Irrigation
It is required only for the first two years
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Pruning
During first year when branches reach a height of 40-60 cms
Pest & Disease control
No disease or insects noticed to be harmful
Flowering and fruiting
Flowering: Sept.- Dec. & March- April
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Fruiting
After 2 months of flowering.
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7. Employment potential (as per Planning Commission report on bio-fuels,
2003))
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Likely demand of petro diesel by 2006-07 will be 52 MMT and by 2011-12 it
will increase to 67 MMT.
5% blend of Bio-diesel with petro diesel will require 2.6 MMT of Bio-diesel
in 2006-07
By 2011-12, for 20% blend with Petro-diesel, the likely demand will be
13.4 MMT.
To meet the requirement of 2.6 MMT of bio-diesel, plantation of Jatropha
should be done on 2.2 - 2.6 million ha area.
11.2 - 13.4 million ha of land should be covered by 2011 - 12 for
20% bio-diesel blending
It will generate following no. of jobs in following areas.
No. of jobs in Operation of BD
Year plantation In maintenance units
9. Trans-esterification Process
Catalyst(Sodium or Glycerin(Used
Vegetable Bio-
Alcohol Potassiu m for medicinal
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Oil Hydroxide) value) diesel
100 gm 12 gm1 gm 11 gm95 gm It is the displacement of alcohol from
an ester by another alcohol in a similar process to hydrolysis.
Vegetable Oil i.e. the triglyceride can be easily trans-esterified in the
presence of alkaline catalyst at atmospheric pressure and at temperature of
approximately 60 to 70oC with an excess of methanol.
If 100 gm of vegetable oil is taken, 1 gm of the alkaline catalyst
(Potassium Hydroxide), and 12 gm of Methanol would be required As a
first step, the alkaline catalyst is mixed with methanol and the mixture is
stirred for half an hour for its homogenization. This mixture is mixed with
vegetable oil and the resultant mixture is made to pass through reflux
condensation at 65oC.
The mixture at the end is allowed to settle.
The lower layer will be of glycerin and it is drain off. The upper
layer of bio-diesel (a methyl ester) is washed to remove entrained
glycerin.
The excess methanol recycled by distillation.
This reaction works well with high quality oil. If the oil contains 1% Free
Fatty Acid (FFA), then difficulty arises because of soap formation. If FFA
content is more than 2% the reaction becomes unworkable.
Methanol is inflammable and Potassium Hydroxide is caustic, hence proper
and safe handling of these chemicals are must.
10. Agencies & Institutes working in the field of bio-diesel
National Oil seeds and Vegetable Oil Board, Gurgaon
PCRA - Petroleum Conservation Research Association
(MOP&NG)
IOC (R&D) Centre, Faridabad
Delhi College of Engineering
IIT, Delhi
IIP, Dehradun
Downstream National Oil Companies
Indian Institute of Chemical Technology, Hyderabad
CSIR
Ministry of Non-conventional Energy Sources
Central Pollution Control Board
Bureau of Indian Standards
Indian Renewable Energy Development Agency
States, which have made some lead
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Uttranchal:
Uttaranchal Bio-fuel Board (UBB) has been constituted as a nodal agency
for bio-diesel promotion in the state.
Has undertaken Jatropha plantation in an area of 1 lakh hectare. UBB
has established Jatropha Gene Bank to preserve high yielding seed
varieties.
Has ambitious plan to produce 100 million liters of bio-diesel.
Andhra Pradesh:
Govt. of AP (GoAP) to encourage Jatropha plantation in 10 rain shadow
districts of AP
Task force for it has been constituted at district and state level GoAP
proposed Jatropha cultivation in 15 lakh acres in next 4 years
Initial target is 2 lakh acres
Irrigation to be dovetailed with Jatropha cultivation
90% drip subsidy is proposed
Jatropha cultivation to be taken up only in cultivable lands with existing
farmers.
Crop and yield insurance is proposed Chhattisgarh:
6 lakh saplings of Jatropha have been planted with the
involvement of State's Forest, Agriculture, Panchayat and Rural
Development Departments
As per the Deputy Chairman, State Planning Board, the state has the
target to cover 1 million ha of land under Jatropha plantation Ten reputed
bio-diesel companies, including the UK-based D1 Oils, have offered to set
up Jatropha oil-extraction units or to buy the produce from farmers in
Chhattisgarh.
Companies like Indian Oil, Indian Railways and Hindustan
Petroleum have each deposited Rs 10 lakh as security for future
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usage of Jatropha oil.
NGOs have also printed some booklets on Jatropha plantation.
12. Current usages of bio-diesel / Trials & testing of bio-diesel
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Usages of bio -diesel are similar to that of petro -diesel
Shatabadi Express was run on 5% blend of bio -diesel from Delhi
to Amritsar on 31st Dec. 2002 in association with IOC.
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Field trials of 10% bio -diesel blend were also done on Lucknow -
Allahabad Jan Shatabdi Express also through association with
IOC.
HPCL is also carrying out field trials in association with BEST
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BIO-PETROL
Introduction
The BioPetrol process begins with sewage sludge at 90% D.S. Sewage sludge
drying equipment is used commonly for the evaporative removal of interstitial
water from the sludge. Numerous drying technologies exist on the market.
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Market Analysis and Strategy
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Synthetic Crude Oil – Excess crude oil, beyond what is being
recirculated to run equipment A+B is about 30 kg per 1 ton sewage sludge
90% D.S. Oil energy = 8,900 Kcal/kg same as diesel oil used in heavy industry.
There are references in professional literature to numerous valuable chemicals
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in significant concentration that are present in pyrolysis oils.
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BioPetrol is seeking an investment of US$400,000 for the completion
o f the demonstration pilot. A business plan is available for further
details.
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Technology
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a process of high utilization of the organic matter that is in the sewage sludge
that produces oil and gas in larger quantities and of better quality.
Ethanol is part of a category of molecules called alcohol
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What is Ethanol?
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The simplest alcohol is called methanol and is very similar to a compound
called methane. Methane is a molecule composed of one carbon atom
surrounded by 4 hydrogen atoms. In methanol, one of these hydrogen atoms is
replaced with an oxygen atom with a hydrogen atom attached to it. This two
atom group, oxygen attached to a hydrogen, is called an alcohol group.
Any molecule that has an alcohol group attached to it can be called an alcohol.
To make it easier to talk about, chemists add an “ol” on the end of a chemicals
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name to indicate that it has an alcohol group. Therefore, methane with an
alcohol group attached is called methanol.
For ethanol, it is an ethane molecule –two carbon atoms, with six hydrogen
atoms surrounding them—with one hydrogen replaced by an alcohol group.
Then, the name ethane is changed to ethanol, to indicate that it is an alcohol.
Ethanol has been used by humans for thousands of years, in part because it is
easy to make. In fact, nature can make it for us in a process called
fermentation.
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Fermentation is a biochemical process carried out by microscopic organisms
called yeast. Yeast are anaerobic, meaning they can live and eat without
needing oxygen. Many living things eat sugar, and yeast eat sugar too. When
there is no oxygen, yeast chow down on sugar, but they can’t get all of the
energy that is available in sugar out of it. Instead they use it to get some
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energy, and in the process of digesting it, convert it into ethanol and carbon
dioxide Petrol.
Yeast are even used to make bread. When making bread, bakers use the yeasts
ability to make carbon dioxide Petrol to make the bread rise, making it
thicker. If it were not for yeast, pizza dough would be flatter than a pancake.
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Yeast only consume simple sugars, so only certain foods are good for putting
them to work making ethanol. Bakers use the sugar that you can find in your
kitchen. But it takes a lot of kitchen sugar to fill the tank of your car with
ethanol. Some countries, such as Brazil, that grow a lot of sugar use it to make
ethanol for cars. Brazil has been producing ethanol fuels for decades. The
United States does not have enough sugar cane plants to do this. Instead, the
U.S. has focused on using corn.
Corn has less sugar in it than sugar cane, requiring scientists to develop ways
to convert corn’s more complex sugars into simple sugars. Critics of using corn
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for fuel say that it takes more energy to make ethanol from corn than it takes
to make regular Petrololine.
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A new method is being developed that may be even more promising than using
corn or sugar cane as yeast food. All plants make a complex sugar called
cellulose and it is one of the most abundant plant materials on earth. Cotton is
almost all cellulose, and some forms of cellulose can be found in many of the
foods that we eat. Trees have it. Grass has it. Even corn stalks. But yeast don’t
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eat cellulose.
What makes this very interesting is that farms and other industries already
produce tons and tons of waste materials that contain cellulose. Just imagine,
all the sticks and grass clippings from your yard or playground could be
turned into fuel for your car. Farms can also grow plants for making ethanol.
President George W. Bush mentioned one of these, switch grass, in the 2006
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Therefore, farms or timber companies can convert their waste into ethanol.
There is also one additional benefit, and challenge to processing cellulose.
Cellulose is often stuck together with another plant compound called lignin.
Lignins are compounds that make plants strong, and they trap cellulose.
Lignins are one of the waste products of papermaking. But, lignin materials
extracted from waste materials used for making ethanol can be burned to
power the process, saving more fossil fuels.
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It’s not a question of if we will stop using oil but when. Soon, we will all have to
replace oil with a different, renewable source and ethanol may be the answer
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****THE END****
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CONCLUSION
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BIBLIOGRAPHY
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http://www.icbse.com
www.chemistry.org
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www.ott.doe.gov/biofuels/environment.html
www.pcra.org
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PETROLIAM CONSERVATION RESEARCH
ASSOSIATION (PCRA) national bio fuel
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center.
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