Safety data sheet

according to 29 CFR 1910.1200

E-9005

SECTION 1: IDENTIFICATION
1.1 GHS Product identifier: E-9005
Other means of identification:

1.2 Recommended use of the chemical and restrictions on use:

Relevant uses: Hardener for coatings. For professional users/industrial user only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party:
Roberlo S.A.U.
Ctra. Nacional II, Km. 706,5
17457 Riudellots de la Selva - Gerona - España
Phone: +34 972 478060 (8:00-12:45 / 14:15-17:30 h) ROBERLO (España) (GMT +1:00) - Fax: +34972477394
msds@roberlo.com
1.4 Emergency phone number: +34 972 478060 (8:00-12:45 / 14:15-17:30 h) ROBERLO (Spain) (GMT + 1:00)

SECTION 2: HAZARD(S) IDENTIFICATION

2.1 Classification of the substance or mixture:
NFPA:
Health Hazards: 2
Flammability Hazards: 3
Instability Hazards: 0
Special Hazards: Non-applicable
29 CFR 1910.1200:
Classification of this product has been carried out in accordance with paragraph (d) of § 1910.1200.
Acute Tox. 4: Acute inhalation toxicity, Category 4, H332
Eye Irrit. 2A: Eye irritation, Category 2A, H319
Flam. Liq. 3: Flammable liquids, Category 3, H226
Skin Irrit. 2: Skin irritation, Category 2, H315
Skin Sens. 1: Sensitisation, skin, Category 1, H317
STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373
STOT SE 3: Specific toxicity causing drowsiness and dizziness, single exposure, Category 3, H336
STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335
2.2 Label elements:
NFPA:

29 CFR 1910.1200:
Warning

Hazard statements:
H226 - Flammable liquid and vapour.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H335 - May cause respiratory irritation.
H336 - May cause drowsiness or dizziness.
H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements:

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 1/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 2: HAZARD(S) IDENTIFICATION (continued)

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P370+P378: In case of fire: Use ABC powder extinguisher to put it out.
P501: Dispose of contents and / or containers in accordance with regulations on hazardous waste or packaging and packaging
waste respectively.
2.3 Hazards not otherwise classified (HNOC):
Non-applicable

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances:
Non-applicable
3.2 Mixtures:
Chemical description: polyisocyanate
Components:
Remaining components are non-hazardous and/or present at amounts below reportable limits. The specific chemical identity
and/or exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of
§1910.1200.Therefore, in accordance with Appendix D to § 1910.1200, the product contains:
Identification Chemical name/Classification Concentration
Hexamethylene diisocyanate, oligomers (<0.1 % O=C=N-R-N=C=O)
CAS: 28182-81-2 25 - <50 %
Acute Tox. 4: H332; Skin Sens. 1: H317; STOT SE 3: H335 - Warning

Reaction mass of ethylbenzene and xylene

CAS: Non-applicable Acute Tox. 4: H312+H332; Asp. Tox. 1: H304; Eye Irrit. 2A: H319; Flam. Liq. 3: H226; Skin Irrit. 2: H315; STOT 25 - <50 %
RE 2: H373; STOT SE 3: H335 - Danger
N-butyl acetate
CAS: 123-86-4 25 - <50 %
Flam. Liq. 3: H226; STOT SE 3: H336 - Warning

Hydrocarbons, C9, aromatics

CAS: 64742-95-6 1 - <2,5 %
Asp. Tox. 1: H304; Flam. Liq. 3: H226; STOT SE 3: H335; STOT SE 3: H336 - Danger

To obtain more information on the hazards of the substances consult sections 11, 12 and 16.

SECTION 4: FIRST-AID MEASURES

4.1 Description of necessary measures:
The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for
direct exposure to the chemical product or persistent discomfort, showing the SDS of this product.
By inhalation:
Remove the person affected from the area of exposure, provide with fresh air and keep at rest. In serious cases such as
cardiorespiratory failure, artificial resuscitation techniques will be necessary (mouth to mouth resuscitation, cardiac massage,
oxygen supply, etc.) requiring immediate medical assistance.
By skin contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water
and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this
could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will
increase the risk of infection.
By eye contact:
Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes.
If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further
damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product.
By ingestion/aspiration:
Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse
out the mouth and throat, as they may have been affected during ingestion.
4.2 Most important symptoms/effects, acute and delayed:

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 2/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 4: FIRST-AID MEASURES (continued)

Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of immediate medical attention and special treatment needed, if necessary:
Non-applicable

SECTION 5: FIRE-FIGHTING MEASURES

5.1 Suitable (and unsuitable) extinguishing media:
Suitable extinguishing media:
If possible use polyvalent powder fire extinguishers (ABC powder), alternatively use foam or carbon dioxide extinguishers (CO₂).
Unsuitable extinguishing media:
IT IS RECOMMENDED NOT to use full jet water as an extinguishing agent.
5.2 Specific hazards arising from the chemical:
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and,
consequently, can present a serious health risk.
5.3 Special protective equipment and precautions for fire-fighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment.
Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...)
Additional provisions:
As in any fire, prevent human exposure to fire, smoke, fumes or products of combustion. Only properly trained personnel should
be involved in firefighting. Evacuate nonessential personnel from the fire area. Destroy any source of ignition. In case of fire,
refrigerate the storage containers and tanks for products susceptible to inflammation. Avoid spillage of the products used to
extinguish the fire into an aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
For non-emergency personnel:
Isolate leaks provided that there is no additional risk for the people performing this task. Evacuate the area and keep out those
without protection. Personal protection equipment must be used against potential contact with the spilt product (See section 8).
Above all prevent the formation of any vapour-air flammable mixtures, through either ventilation or the use of an inert medium.
Remove any source of ignition. Eliminate electrostatic charges by interconnecting all the conductive surfaces on which static
electricity could form, and also ensuring that all surfaces are connected to the ground.
For emergency responders:
Wear protective equipment. Keep unprotected persons away. See section 8.
6.2 Environmental precautions:
The characteristic of lgnitability per RCRA could apply to the unused product if it becomes a waste material. The EPA hazardous
waste number D001 could apply. It is the responsibility of the waste generator to evaluate whether his wastes are hazardous by
characteristics or listing.
6.3 Methods and materials for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
A.- General precautions for safe use
Comply with the current standards 29 CFR 1910 Occupational Safety and Health Standards. Keep containers hermetically
sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container.
Maintain order and cleanliness where dangerous products are used.

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 3/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 7: HANDLING AND STORAGE (continued)

B.- Technical recommendations for the prevention of fires and explosions
Because the product is a flammable liquid, storage should meet the requirement of 29 CFR 1910.106, Flammable and
Combustible Liquids Code. Transfer in well ventilated areas, preferably through localized extraction. Fully control sources of
ignition (mobile phones, sparks,…) and ventilate during cleaning operations. Avoid the existence of dangerous atmospheres
inside containers, applying inertization systems where possible. Transfer at a slow speed to avoid the creation of electrostatic
charges. Against the possibility of electrostatic charges: ensure a perfect equipotential connection, always use groundings, do
not wear work clothes made of acrylic fibres, preferably wearing cotton clothing and conductive footwear. Comply with the
essential security requirements for equipment and systems and with the minimum requirements for protecting the security
and health of workers. Consult section 10 for conditions and materials that should be avoided.
C.- Technical recommendations on general occupational hygiene
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 41 ºF
Maximum Temp.: 86 ºF
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the workplace:
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000):
Identification Occupational exposure limits
Reaction mass of ethylbenzene and xylene 8-hour TWA PEL 100 ppm 435 mg/m³
Ceiling Values - TWA
CAS: Non-applicable
PEL
N-butyl acetate 8-hour TWA PEL 150 ppm 710 mg/m³
Ceiling Values - TWA
CAS: 123-86-4
PEL

US. ACGIH Threshold Limit Values (2022):

Identification Occupational exposure limits
Reaction mass of ethylbenzene and xylene TLV-TWA 100 ppm
CAS: Non-applicable TLV-STEL 150 ppm
N-butyl acetate TLV-TWA 20 ppm
CAS: 123-86-4 TLV-STEL

CALIFORNIA- TABLE AC-1 PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS:

Identification Occupational exposure limits
Reaction mass of ethylbenzene and xylene PEL 100 ppm 435 mg/m³
CAS: Non-applicable STEL 150 ppm 655 mg/m³
N-butyl acetate PEL 150 ppm 710 mg/m³
CAS: 123-86-4 STEL 200 ppm 950 mg/m³

Biological limit values:

Biological Exposure Indices (BEIs®) - ACGIH
Identification BEIs® Determinant Sampling Time
Reaction mass of ethylbenzene and xylene Methylhippuric acids in
1500 mg/g (NULL) End of shift
CAS: Non-applicable urine

8.2 Appropriate engineering controls:

A.- Individual protection measures, such as personal protective equipment

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 4/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

Always provide effective general and, when necessary, local exhaust ventilation to maintain the ambient workplace
atmosphere below the exposure limits.. For more information on Personal Protection Equipment (storage, use, cleaning,
maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For additional information
see subsection 7.1. All information contained herein is a recommendation, the information on clothing performance must be
combined with professional judgment, and a clear understanding of the clothing application, to provide the best protection to
the worker. All chemical protective clothing use must be based on a hazard assessment to determine the risks for exposure to
chemicals and other hazards. Conduct hazard assessments in accordance with 29 CFR 1910.132.
B.- Respiratory protection
Pictogram PPE Remarks

Replace when there is a taste or smell of the contaminant inside the face mask. If
the contaminant comes with warnings it is recommended to use isolation
Filter mask for gases and vapours
equipment. Use respirator in accordance with manufacturer´s use limitations and
Mandatory OSHA standard 1910.134 (29CFR)
respiratory tract
protection
C.- Specific protection for the hands
Pictogram PPE Remarks

The Breakthrough Time indicated by the manufacturer must exceed the period
during which the product is being used. Do not use protective creams after the
NON-disposable chemical protective gloves
product has come into contact with skin. Use gloves in accordance with
Mandatory hand manufacturer´s use limitations and OSHA standard 1910.138 (29CFR)
protection
As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with
total reliability and has therefore to be checked prior to the application.
D.- Eye and face protection
Pictogram PPE Remarks

Clean daily and disinfect periodically according to the manufacturer´s instructions.

Face shield Use if there is a risk of splashing. Use this PPE in accordance with manufacturer´s
use limitations and OSHA standard 1910.133 (29CFR)
Mandatory face
protection
E.- Bodily protection
Pictogram PPE Remarks

Disposable clothing for protection against

For professional use only. Clean periodically according to the manufacturer´s
chemical risks, with antistatic and fireproof
instructions.
properties
Mandatory complete
body protection

Safety footwear for protection against chemical

Replace boots at any sign of deterioration.
risk, with antistatic and heat resistant properties
Mandatory foot
protection
F.- Additional emergency measures
Emergency measure Standards Emergency measure Standards

ANSI Z358-1 DIN 12 899

ISO 3864-1:2011, ISO 3864-4:2011 ISO 3864-1:2011, ISO 3864-4:2011
Emergency shower Eyewash stations

Environmental exposure controls:

In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental
spillage of both the product and its container. For additional information see subsection 7.1.D
40 CFR Part 59 (VOC):
V.O.C.(weight-percent): 62.04 % weight
V.O.C. at 68 ºF: 602.39 kg/m³ (602.39 g/L)
California Air Resources Board (CARB) - VOC Regulatory:

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 5/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

V.O.C.(weight-percent): 62.04 % weight
V.O.C. at 68 ºF: 602.39 kg/m³ (602.39 g/L)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:
For complete information see the product datasheet.
Appearance:
Physical state at 68 ºF: Liquid
Appearance: Fluid
Color: Colorless
Odor: Characteristic
Odour threshold: Non-applicable *
Volatility:
Boiling point at atmospheric pressure: 227 - 523 ºF
Vapour pressure at 68 ºF: 928 Pa
Vapour pressure at 122 ºF: 4831.41 Pa (4.83 kPa)
Evaporation rate at 68 ºF: Non-applicable *
Product description:
Density at 68 ºF: 971 kg/m³
Relative density at 68 ºF: Non-applicable *
Dynamic viscosity at 68 ºF: 26 cP
Kinematic viscosity at 68 ºF: 3138.49 mm²/s
Kinematic viscosity at 104 ºF: >20.5 mm²/s
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 68 ºF: Non-applicable *
Partition coefficient n-octanol/water 68 ºF: Non-applicable *
Solubility in water at 68 ºF: Non-applicable *
Solubility properties: Immiscible
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: 79 ºF
Flammability (solid, gas): Non-applicable *
Autoignition temperature: 790 ºF
Lower flammability limit: 1 % Volume
Upper flammability limit: 7.6 % Volume
Particle characteristics:
Median equivalent diameter: Non-applicable
9.2 Other information:
Information with regard to physical hazard classes:
Explosive properties: Non-applicable *
Oxidising properties: Non-applicable *
Corrosive to metals: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 6/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued)

Heat of combustion: Non-applicable *
Aerosols-total percentage (by mass) of flammable Non-applicable *
components:
Other safety characteristics:
Surface tension at 68 ºF: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7.
10.2 Chemical stability:
Chemically stable under the indicated conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Risk of combustion Avoid direct impact Not applicable

10.5 Incompatible materials:

Acids Water Oxidising materials Combustible materials Others
Avoid strong acids Not applicable Avoid direct impact Not applicable Avoid alkalis or strong bases

10.6 Hazardous decomposition products:

See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO₂), carbon monoxide and other organic compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:

The experimental information related to the toxicological properties of the product itself is not available

Dangerous health implications:

In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure
limits, it may result in adverse effects on health depending on the means of exposure:
A- Ingestion (acute effect):

- Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified
as hazardous for consumption. For more information see section 3
- Corrosivity/Irritability: The consumption of a considerable dose can cause irritation in the throat, abdominal pain, nausea
and vomiting.
B- Inhalation (acute effect):

- Acute toxicity : Exposure in high concentration can cause a breakdown in the central nervous system causing headache,
dizziness, vertigo, nausea, vomiting, confusion, and in serious cases, loss of consciousness.
- Corrosivity/Irritability: Causes irritation in respiratory passages, which is normally reversible and limited to the upper
respiratory passages.
C- Contact with the skin and the eyes (acute effect):

- Contact with the skin: Produces skin inflammation.

- Contact with the eyes: Produces eye damage after contact.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 7/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 11: TOXICOLOGICAL INFORMATION (continued)

- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified
as hazardous for the effects mentioned. For more information see section 3.
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous for this effect. For more information see section 3.
- Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances
classified as hazardous for this effect. For more information see section 3.
E- Sensitizing effects:

- Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous with sensitising effects. For more information see section 3.
- Skin: Prolonged contact with the skin can result in episodes of allergic contact dermatitis.
F- Specific target organ toxicity (STOT) - single exposure:

Causes irritation in respiratory passages, which is normally reversible and limited to the upper respiratory passages.

G- Specific target organ toxicity (STOT)-repeated exposure:

- Specific target organ toxicity (STOT)-repeated exposure: Exposure in high concentration can cause a breakdown in the
central nervous system causing headache, dizziness, vertigo, nausea, vomiting, confusion, and in serious cases, loss of
consciousness.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous for this effect. For more information see section 3.
H- Aspiration hazard:

Based on available data, the classification criteria are not met. However, it does contain substances classified as hazardous
for this effect. For more information see section 3.
Other information:

Non-applicable

Specific toxicology information on the substances:

Identification Acute toxicity Genus

N-butyl acetate LD50 oral 12789 mg/kg Rat
CAS: 123-86-4 LD50 dermal 14112 mg/kg Rabbit
LC50 inhalation 23.4 mg/L (4 h) Rat
Hexamethylene diisocyanate, oligomers (<0.1 % O=C=N-R-N=C=O) LD50 oral 2660 mg/kg Rat
CAS: 28182-81-2 LD50 dermal >5000 mg/kg
LC50 inhalation 11 mg/L (ATEi)
Hydrocarbons, C9, aromatics LD50 oral >5000 mg/kg
CAS: 64742-95-6 LD50 dermal >5000 mg/kg
LC50 inhalation >20 mg/L
Reaction mass of ethylbenzene and xylene LD50 oral 2100 mg/kg Rat
CAS: Non-applicable LD50 dermal 1100 mg/kg Rat
LC50 inhalation 11 mg/L (4 h) Rat

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the eco-toxicological properties of the product itself is not available
12.1 Ecotoxicity (aquatic and terrestrial, where available):
Acute toxicity:
Identification Concentration Species Genus
Hexamethylene diisocyanate, oligomers (<0.1 % O=C=N-R-
LC50 Non-applicable
N=C=O)
CAS: 28182-81-2 EC50 Non-applicable
EC50 1000 mg/L (72 h) Scenedesmus subspicatus Algae
N-butyl acetate LC50 Non-applicable
CAS: 123-86-4 EC50 Non-applicable
EC50 675 mg/L (72 h) Scenedesmus subspicatus Algae

Chronic toxicity:

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 8/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 12: ECOLOGICAL INFORMATION (continued)

Identification Concentration Species Genus

Reaction mass of ethylbenzene and xylene NOEC 1.3 mg/L Oncorhynchus mykiss Fish
CAS: Non-applicable NOEC 1.17 mg/L Ceriodaphnia dubia Crustacean
N-butyl acetate NOEC Non-applicable
CAS: 123-86-4 NOEC 23.2 mg/L Daphnia magna Crustacean
12.2 Persistence and degradability:
Substance-specific information:
Identification Degradability Biodegradability
N-butyl acetate BOD5 Non-applicable Concentration Non-applicable
CAS: 123-86-4 COD Non-applicable Period 5 days
BOD5/COD Non-applicable % Biodegradable 84 %
12.3 Bioaccumulative potential:
Substance-specific information:
Identification Bioaccumulation potential
Reaction mass of ethylbenzene and xylene BCF 9
CAS: Non-applicable Pow Log 2.77
Potential Low
N-butyl acetate BCF 4
CAS: 123-86-4 Pow Log 1.78
Potential Low
12.4 Mobility in soil:
Identification Absorption/desorption Volatility
N-butyl acetate Koc Non-applicable Henry Non-applicable
CAS: 123-86-4 Conclusion Non-applicable Dry soil Non-applicable
Surface tension 2.478E-2 N/m (77 ºF) Moist soil Non-applicable
12.5 Results of PBT and vPvB assessment:
Non-applicable
12.6 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Disposal methods:
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations. In case the container has been in
direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-
dangerous residue. Waste should not be disposed of to drains. See epigraph 6.2.
Regulations related to waste management:
Legislation related to waste management:
40 CFR Part 261- IDENTIFICATION AND LISTING OF HAZARDOUS WASTE

SECTION 14: TRANSPORT INFORMATION

Transport of dangerous goods by land:
With regard to 49 CFR on the Transport of Dangerous Goods:

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 9/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 14: TRANSPORT INFORMATION (continued)

14.1 UN number: UN1263

14.2 UN proper shipping name: PAINT RELATED MATERIAL
14.3 Transport hazard class(es): 3
Labels: 3
14.4 Packing group, if applicable: III
14.5 Marine pollutant: No
14.6 Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Physico-Chemical properties: see section 9
Limited quantities: 5L
14.7 Transport in bulk (according Non-applicable
to Annex II of MARPOL
73/78 and the IBC Code):
Transport of dangerous goods by sea:
With regard to IMDG 40-20:
14.1 UN number: UN1263
14.2 UN proper shipping name: PAINT RELATED MATERIAL
14.3 Transport hazard class(es): 3
Labels: 3
14.4 Packing group, if applicable: III
14.5 Marine pollutant: No
14.6 Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Special regulations: 163, 223, 955, 367
EmS Codes: F-E, S-E
Physico-Chemical properties: see section 9
Limited quantities: 5L
Segregation group: Non-applicable
14.7 Transport in bulk (according Non-applicable
to Annex II of MARPOL
73/78 and the IBC Code):
Transport of dangerous goods by air:
With regard to IATA/ICAO 2022:
14.1 UN number: UN1263
14.2 UN proper shipping name: PAINT RELATED MATERIAL
14.3 Transport hazard class(es): 3
Labels: 3
14.4 Packing group, if applicable: III
14.5 Marine pollutant: No
14.6 Special precautions which a user needs to be aware of, or needs to comply with, in
connection with transport or conveyance either within or outside their premises
Physico-Chemical properties: see section 9

14.7 Transport in bulk (according Non-applicable

to Annex II of MARPOL
73/78 and the IBC Code):

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations specific for the product in question:

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 10/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 15: REGULATORY INFORMATION (continued)

- CALIFORNIA LABOR CODE - The Hazardous Substances List: Reaction mass of ethylbenzene and xylene (Non-applicable) ;
N-butyl acetate (123-86-4)
- California Proposition 65 (the Safe Drinking Water and Toxic Enforcement Act of 1986) - Birth defects or other reproductive
harm: Non-applicable
- California Proposition 65 (the Safe Drinking Water and Toxic Enforcement Act of 1986) - Cancer: Non-applicable
- CANADA-Domestic Substances List (DSL): Hexamethylene diisocyanate, oligomers (<0.1 % O=C=N-R-N=C=O) (28182-81-2) ;
N-butyl acetate (123-86-4)
- CANADA-Non-Domestic Substances List (NDSL): Non-applicable
- Hazardous Air Pollutants (Clean Air Act): Non-applicable
- Massachusetts RTK - Substance List: Hexamethylene diisocyanate, oligomers (<0.1 % O=C=N-R-N=C=O) (28182-81-2) ;
Reaction mass of ethylbenzene and xylene (Non-applicable) ; N-butyl acetate (123-86-4)
- Minnesota - Hazardous substances ERTK: Reaction mass of ethylbenzene and xylene (Non-applicable) ; N-butyl acetate
(123-86-4)
- New Jersey Worker and Community Right-to-Know Act: Reaction mass of ethylbenzene and xylene (Non-applicable) ; N-butyl
acetate (123-86-4)
- New York RTK - Substance list: Reaction mass of ethylbenzene and xylene (Non-applicable) ; N-butyl acetate (123-86-4)
- NTP (National Toxicology Program): Non-applicable
- OSHA Specifically Regulated Substances (29 CFR 1910.1001-1096): Non-applicable
- Pennsylvania Worker and Community Right-to-Know Law: N-butyl acetate (123-86-4)
- Rhode Island - Hazardous substances RTK: N-butyl acetate (123-86-4)
- The Toxic Substances Control Act (TSCA) : Hexamethylene diisocyanate, oligomers (<0.1 % O=C=N-R-N=C=O) (28182-81-2) ;
N-butyl acetate (123-86-4)
- Toxic chemical release reporting under EPCRA section 313 (40 CFR Part 372): Non-applicable
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantities: N-butyl acetate
(5000 pounds)
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local
circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this
product.
Other legislation:
Take into consideration other applicable federal, state, and local laws and local regulations.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with Appendix d to §1910.1200 - Safety data sheets
Texts of the legislative phrases mentioned in section 2:
H336: May cause drowsiness or dizziness.
H335: May cause respiratory irritation.
H317: May cause an allergic skin reaction.
H315: Causes skin irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
H332: Harmful if inhaled.
H226: Flammable liquid and vapour.
H319: Causes serious eye irritation.
Texts of the legislative phrases mentioned in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the
individual components which appear in section 3
29 CFR 1910.1200:
Acute Tox. 4: H312+H332 - Harmful in contact with skin or if inhaled.
Acute Tox. 4: H332 - Harmful if inhaled.
Asp. Tox. 1: H304 - May be fatal if swallowed and enters airways.
Eye Irrit. 2A: H319 - Causes serious eye irritation.
Flam. Liq. 3: H226 - Flammable liquid and vapour.
Skin Irrit. 2: H315 - Causes skin irritation.
Skin Sens. 1: H317 - May cause an allergic skin reaction.
STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure.
STOT SE 3: H335 - May cause respiratory irritation.
STOT SE 3: H336 - May cause drowsiness or dizziness.
Advice related to training:

- CONTINUED ON NEXT PAGE -

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 11/12

 Safety data sheet
according to 29 CFR 1910.1200

E-9005

SECTION 16: OTHER INFORMATION (continued)

Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension
and interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
Occupational Safety & Health Administration (OSHA).
Abbreviations and acronyms:
IMDG: International maritime dangerous goods code
IATA: International Air Transport Association
ICAO: International Civil Aviation Organisation
COD: Chemical Oxygen Demand
BOD5: 5-day biochemical oxygen demand
BCF: Bioconcentration factor
LD50: Lethal Dose 50
CL50: Lethal Concentration 50
EC50: Effective concentration 50
Log-POW: Octanol-water partition coefficient
Koc: Partition coefficient of organic carbon
IARC: International Agency for Research on Cancer
Date of compilation: 12/21/2021
Revised: 6/3/2022

Manufacturer Disclaimer: The information contained in this safety date sheet (“SDS”) is based on sources, technical knowledge and current legislation. Furthermore, is based on data believed to
be accurate; thus, the company does not assume any liability for its accuracy. The information provided herein cannot be considered a guarantee of the properties of this product and the same is
simply a description of the security requirements. The use, occupational methodology and/or conditions for users of this product are not within our awareness or control. It is ultimately the
responsibility of the user(s) to take the necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information of this
SDS only refers to this product, which should not be used for purposes other than those specified. Finally, the manner in which this product is used and whether there is any infringement of
patents is the sole responsibility of the user(s).

END OF SAFETY DATA SHEET

Date of compilation: 12/21/2021 Revised: 6/3/2022 Version: 2 (Replaced 1) Page 12/12