Jephias Gwamuri

This study investigates ultra-thin transparent conducting oxides (TCO) of indium tin oxide (ITO), aluminum-doped zinc oxide (AZO) and zinc oxide (ZnO) to determine their viability as candidate materials for use in plasmonic-enhanced thin-film amorphous silicon solar photovoltaic (PV) devices. First a sensitivity analysis of the optical absorption for the intrinsic layer of a nano-disk patterned thin-film amorphous silicon-based solar cell as a function of TCO thickness (10–50 nm) was performed by simulation. These simulation results were then used to guide the design of the experimental work which investigated both optical and electrical properties of ultra-thin (10 nm on average) films simultaneously deposited on both glass and silicon substrates using conventional rf sputtering. The effects of deposition and post-processing parameters on material properties of ITO, AZO and ZnO ultra-thin TCOs were probed and the suitability of TCOs for integration into plasmonic-enhanced thin-film solar PV devices was assessed. The results show that ultra-thin TCOs present a number of challenges for use as thin top contacts on plasmonic-enhanced PV devices: (1) optical and electrical parameters differ greatly from those of thicker (bulk) films deposited under the same conditions, (2) the films are delicate due to their thickness, requiring very long annealing times to prevent cracking, and (3) reactive gases require careful monitoring to maintain stoichiometry. The results presented here found a trade-off between conductivity and transparency of the deposited films. Although the sub 50 nm TCO films investigated exhibited desirable optical properties (transmittance greater than 80 %), their resistivity was too high to be considered as materials for the top contact of conventional PV devices. Future work is necessary to improve thin TCO properties, or alternative materials, and geometries are needed in plasmonic-based amorphous silicon solar cells. The stability of ultra-thin TCO films also needs to be experimentally investigated under normal device operating conditions.

The agglomeration/dewetting process of thin silver films provides a scalable method of obtaining self-assembled nanoparticles (SANPs) for plasmonics based thin-film solar photovoltaic (PV) devices. Here, we show the effect of annealing ambiance on silver SANP average size, particle/cluster finite shape, substrate area coverage/particle distribution and how these physical parameters influence optical properties and surface-enhanced Raman scattering (SERS) responses of SANPs. Statistical analysis performed indicates that generally Ag SANPs processed in the presence of a gas (Argon and Nitrogen) ambiance tend to have smaller average size particles compared to those processed under vacuum. Optical properties are observed to be highly dependent on particle size, separation distance as well as finite shape. The greatest SERS enhancement was observed for the argon processed samples. There is a correlation between simulation and experimental data that indicate argon processed AgNPs have a great potential to enhance light coupling when integrated to thin-film PV. 1 Introduction As-deposited thin metallic films are generally metastable or unstable and readily de-wet from a solid substrate when heated even well below their melting temperature 1-2. The process of agglomeration/de-wetting proceeds in two ways: nucleation and growth of holes, and spinodal dewetting 1, 3-5. This process is a relatively economical means of obtaining both simple and complex nano-structures from thin metal films 5-10 compared to traditional methods such as e-beam lithography. Whilst dewetting during film processing has been reported to have undesirable effects on micro-and nano-systems, agglomeration has become the method of choice for catalyzed growth of nanotubes/nanowires and electronic and photonic devices 3. Dewetting of thin metallic films (both liquid and solid) to obtain mono/multi-dispersed nanoparticles has been demonstrated with a range of metals including: gold (Au), silver (Ag), nickel (Ni), copper (Cu) and alumina (Al), among others 1, 3-4, 10-1. However, Ag film dewetting has been mostly investigated as candidate for plasmonic sensing 12-18 and plasmonics-enhanced solar photovoltaics (PV) devices 19-31 applications. This is because Ag is generally considered to have the most suitable optical properties for solar cell applications. Silver nanoparticles exhibit highly intense and localized surface plasmon resonances (LSPR) and low absorption in the visible and near

The recent introduction of RepRap (self-replicating rapid prototyper) 3-D printers and the resultant open source technological improvements have resulted in affordable 3-D printing, enabling low-cost distributed manufacturing for individuals. This development and others such as the rise of open source-appropriate technology (OSAT) and solar powered 3-D printing are moving 3-D printing from an industry based technology to one that could be used in the developing world for sustainable development. In this paper, we explore some specific technological improvements and how distributed manufacturing with open-source 3-D printing can be used to provide open-source 3-D printable optics components for developing world communities through the ability to print less expensive and customized products. This paper presents an open-source low cost optical equipment library which enables relatively easily adapted customizable designs with the potential of changing the way optics is taught in resource constraint communities. The study shows that this method of scientific hardware development has a potential to enables a much broader audience to participate in optical experimentation both as research and teaching platforms. Conclusions on the technical viability of 3-D printing to assist in development and recommendations on how developing communities can fully exploit this technology to improve the learning of optics through hands-on methods have been outlined.

In this study applications and potential uses of 3D printing in the plastic thermoforming industry are studied. Additive manufacturing has revolutionized the modern manufacturing process and engineering design process. Thermoforming is widely used in plastic manufacturing industries to produce a range of polymer products such as products in the packaging industry. Thermoforming moulds are mostly produced using conventional mould building technologies and are made of steel. These mould are robust but only suitable for mass production and take some time to fabricate. 3D printing can find use in thermoforming industry in creating moulds this can produce the moulds quickly, economically as well as prototyping of the packaging material. 3D printing allows ease of production of personalised packaging. With 3D printing the structural design of the package could be customised on request. As more sustainable bioplastic filaments are innovated, the adoption of 3D printing in packaging manufacturing may help save the environment. 3D printing works well with Acrylonitrile Butadiene Styrene (ABS) and polypropylene. This paper looks at the different applications of 3D printing in the plastics thermoforming industry and looks at the viability of the use of this technology as well as the advantages in relation to conventional production technologies.

A source of large surface areas for solar photovoltaic (PV) farms that has been largely overlooked in the 13,000 United States of America (U.S.) airports. This paper hopes to enable PV deployments in most airports by providing an approach to overcome the three primary challenges identified by the Federal Aviation Administration (FAA): (1) reflectivity and glare; (2) radar interference; and (3) physical penetration of airspace. First, these challenges and precautions that must be adhered to for safe PV projects deployment at airports are reviewed and summarized. Since one of the core concerns for PV and airport symbiosis is solar panel reflectivity, and because this data is largely estimated, a controlled experiment is conducted to determine worst-case values of front panel surface reflectivity and compare them to theoretical calculations. Then a general approach to implement solar PV systems in an airport is outlined and this approach is applied to a case study airport. The available land was found to be over 570 acres, which would generate more than 39,000% of the actual annual power demand of the existing airport. The results are discussed while considering the scaling potential of airport-based PV systems throughout the U.S.

The study first uses numerical simulations of hexagonal triangle and sphere arrays to optimize the performance of hydrogenated amorphous silicon (a-Si:H) photovoltaic devices. The simulations indicated the potential for a sphere array to provide optical enhancement up to 7.4% compared to a standard cell using a nanosphere radius of 250nm and silver film thickness of 50nm. Next a detailed series of a-Si:H cells were fabricated and tested for quantum efficiency (QE) and characteristic and current-voltage (I-V) profiles using a solar simulator. Triangle and sphere array based cells, as well as the uncoated reference cells are analyzed and the results find that the simulation does not precisely predict the observed enhancement, but it forecasts a trend and can be used to guide fabrication. In general, the measured optical enhancement follows the simulated trend: 1) for triangular arrays no enhancement is observed and as the silver thickness increases the more degradation of the cell; 2) for annealed arrays both measured and simulated optical enhancement occur with the thinner silver thickness. Measured efficiency enhancement reached 20.2% and 10.9% for nanosphere diameter D = 500nm, silver thicknesses h = 50nm and 25nm, respectively. These values, which surpass simulation results, indicate that this method is worth additional investigation.

The recent introduction of RepRap (Self-Replicating Rapid Prototyper) 3-D printers and the resultant open source technological improvements have resulted in affordable 3-D printing, enabling low-cost distributed manufacturing for individuals. This development and others such as the rise of open source-appropriate technology (OSAT) and solar powered 3-D printing are moving 3-D printing from an industry specific technology to one that could be used in the developing world for sustainable development. In this paper, we explore some specific technological improvements and how distributed manufacturing with open-source 3-D printing can provide sustainable development by creating wealth for developing world communities through the ability to print less expensive and customized products. Conclusions on the technical viability of 3-D printing to assist in development and recommendations on how developing communities can fully exploit this technology have been outlined.

Scientists have begun using self-replicating rapid prototyper (RepRap) 3-D printers to manufacture open source digital designs of scientific equipment. This approach is refined here to develop a novel instrument capable of performing automated large-area four-point probe measurements. The designs for conversion of a RepRap 3-D printer to a 2-D open source four-point probe (OS4PP) measurement device are detailed for the mechanical and electrical systems. Free and open source software and firmware are developed to operate the tool. The OS4PP was validated against a wide range of discrete resistors and indium tin oxide (ITO) samples of different thicknesses both pre-and post-annealing. The OS4PP was then compared to two commercial proprietary systems. Results of resistors from 10 to 1 MΩ show errors of less than 1% for the OS4PP. The 3-D mapping of sheet resistance of ITO samples successfully demonstrated the automated capability to measure non-uniformities in large-area samples. The results indicate that all measured values are within the same order of magnitude when compared to two proprietary measurement systems. In conclusion, the OS4PP system, which costs less than 70% of manual proprietary systems, is comparable electrically while offering automated 100 micron positional accuracy for measuring sheet resistance over larger areas.

Using metamaterial absorbers, we have shown that metallic layers in the absorbers do not necessarily constitute undesired resistive heating problem for photovoltaics. Tailoring the geometric skin depth of metals and employing the natural bulk absorbance characteristics of the semiconductors in those absorbers can enable the exchange of undesired resistive losses with the useful optical absorbance in the active semiconductors. Thus, Ohmic loss dominated metamaterial absorbers can be converted into photovoltaic near-perfect absorbers with the advantage of harvesting the full potential of light management offered by the metamaterial absorbers. Based on experimental permittivity data for indium gallium nitride, we have shown that between 75%–95% absorbance can be achieved in the semiconductor layers of the converted metamaterial absorbers. Besides other metamaterial and plasmonic devices, our results may also apply to photodectors and other metal or semiconductor based optical devices where resistive losses and power consumption are important pertaining to the device performance. I mprovements in optical enhancement for solar photovoltaic (PV) devices using conventional natural materials has begun to show diminishing returns, yet metamaterials, which are rationally designed geometries of optical materials that can be tuned to respond to any region of the electromagnetic spectrum offer an opportunity to continue to improve solar device performance 1. Historically, periodic structures with sub-wavelength features are used to construct a metamaterial for a given application. Designing and constructing a material in this way a metamaterial possesses optical properties that are not observed in their constituent materials enabling the properties to be determined from structure rather than merely composition. The advent of meta-materials has provided PV device designers among others with unprecedented flexibility in manipulating light and producing new functionalities 2. Metamaterials have already been proposed for super lenses that allow sub-wavelength resolution beyond the diffraction limit, and electromagnetic cloaks, which promise real physical invisibility 3. Another approach to optical enhancement of PV is to consider plasmonics, which is a rapidly growing field for the application of surface plasmons to device performance improvement. Surface-plasmon-based devices already proposed include not only PV but also light-emitting devices, data storage, biosensors, nano-imaging, wave-guides, perfect absorbers, and others 4–8. Surface plasmons are collective oscillations of surface electrons whereas surface plasmon polariton (SPP) describes a coupled state between a surface plasmon and a photon 9. On the other hand, localized surface plasmons (LSP) are confined to bounded geometries such as metallic nanoparticles or nanostrips of various topologies 10–12. The fluctuations of surface charge results in highly localized and significantly enhanced electromagnetic fields in the vicinity of metallic surfaces. Typically, surface plasmon resonances exhibit a strong relationship to the size, shape and the dielectric properties of the surrounding medium. The resonances of noble metals are mostly in the visible or infrared region of the electromagnetic spectrum, which is the range of interest for PV applications 13. For the application, we are considering here photons arriving at the metal surface produce surface waves in the form of SPP along the metal-semiconductor interface of the top layer of a PV device. This occurs when the photons interact with the collective oscillations of free electrons in the metal of the absorber. The metallic nanostructures have the ability to maintain SPPs, which provides electromagnetic field confinement and

A new method of preparing highly conductive ultra-thin indium tin oxide for plasmonic-enhanced thin film solar photovoltaic devices. Abstract Recent numerical modeling of plasmonic metallic nanostructures have shown great potential as a method of light management in thin-film nanodisc-patterned hydrogenated amorphous silicon (a-Si:H) solar photovoltaic (PV) cells. A significant design challenge for such plasmonic-enhanced PV devices is the requirement for ultra-thin transparent conducting oxides (TCOs) with high transmittance (low loss) and low enough resistivity to be used as device top contacts/electrodes. Most work on TCOs is on relatively thick layers and the few reported cases of thin TCO showed a marked decrease in conductivity. Recent work on ultra-thin TCOs of aluminum-doped zinc oxide, indium-doped tin oxide and zinc oxide revealed an unavoidable trade-off between transmittance and resistivity when fabricated with conventional growth methods. Ultra-thin films showed a tendency to be either amorphous and continuous or form as isolated islands. This results in poor electrical properties, which cannot be improved with annealing as the delicate thin films nucleate to form grain clusters. In order to overcome this challenge, this study investigates a novel method of producing ultra-thin (<40 nm) high quality TCOs. First, ~80nm ITO films are sputtered in various argon-oxygen atmospheres and annealed to increase conductivity. The most promising materials were then reduced in thickness with a controlled low-cost room-temperature cyclic wet chemical etching process to reach the desired thickness. The degradation in the electrical conductivity was tracked as a function of thickness. The sheet resistance of 36nm thin films was observed to be of the same order compared to the much thicker commercial ITO films currently used as transparent electrodes in PV and other opto-electronic devices. Experimental optical properties of the shaved films were then used in an optimized model of nano-disc plasmonic a-Si:H solar cells. Simulations indicate that optical enhancement greater than 21% are possible in the 300 – 730 nm wavelength range, when compared to the reference cell. Using the novel chemical shaving method described here, high-quality ultra-thin ITO films capable of improving the efficiency of thin film a-Si:H solar cells have been demonstrated. The methods employed in the optimization process are well established and economically viable, which provide the technical potential for commercialization of plasmonic based solar cells. A new method of preparing highly conductive ultra-thin indium tin oxide for plasmonic-enhanced thin film solar photovoltaic devices.

The opportunity for substantial efficiency enhancements of thin film hydrogenated amorphous silicon (a-Si:H) solar photovoltaic (PV) cells using plasmonic absorbers requires ultra-thin transparent conducting oxide top electrodes with low resistivity and high transmittances in the visible range of the electromagnetic spectrum. Fabricating ultra-thin indium tin oxide (ITO) films (sub-50 nm) using conventional methods has presented a number of challenges; however, a novel method involving chemical shaving of thicker (greater than 80 nm) RF sputter deposited high-quality ITO films has been demonstrated. This study investigates the effect of oxygen concentration on the etch rates of RF sputter deposited ITO films to provide a detailed understanding of the interaction of all critical experimental parameters to help create even thinner layers to allow for more finely tune plasmonic resonances. ITO films were deposited on silicon substrates with a 98-nm, thermally grown oxide using RF magnetron sputtering with oxygen concentrations of 0, 0.4 and 1.0 sccm and annealed at 300 °C air ambient. Then the films were etched using a combination of water and hydrochloric and nitric acids for 1, 3, 5 and 8 min at room temperature. In-between each etching process cycle, the films were characterized by X-ray diffraction, atomic force microscopy, Raman Spectroscopy, 4-point probe (electrical conductivity), and variable angle spectroscopic ellipsometry. All the films were polycrystalline in nature and highly oriented along the (222) reflection. Ultra-thin ITO films with record low resistivity values (as low as 5.83 × 10−4 Ω·cm) were obtained and high optical transparency is exhibited in the 300–1000 nm wavelength region for all the ITO films. The etch rate, preferred crystal lattice growth plane, d-spacing and lattice distortion were also observed to be highly dependent on the nature of growth environment for RF sputter deposited ITO films. The structural, electrical, and optical properties of the ITO films are discussed with respect to the oxygen ambient nature and etching time in detail to provide guidance for plasmonic enhanced a-Si:H solar PV cell fabrication.

The opportunity for substantial efficiency enhancements of thin film hydrogenated amorphous silicon (a-Si:H) solar photovoltaic (PV) cells using plasmonic absorbers requires ultra-thin transparent conducting oxide top electrodes with low resistivity and high transmittances in the visible range of the electromagnetic spectrum. Fabricating ultra-thin indium tin oxide (ITO) films (sub-50 nm) using conventional methods has presented a number of challenges; however, a novel method involving chemical shaving of thicker (greater than 80 nm) RF sputter deposited high-quality ITO films has been demonstrated. This study investigates the effect of oxygen concentration on the etch rates of RF sputter deposited ITO films to provide a detailed understanding of the interaction of all critical experimental parameters to help create even thinner layers to allow for more finely tune plasmonic resonances. ITO films were deposited on silicon substrates with a 98-nm, thermally grown oxide using RF magnetron sputtering with oxygen concentrations of 0, 0.4 and 1.0 sccm and annealed at 300 °C air ambient. Then the films were etched using a combination of water and hydrochloric and nitric acids for 1, 3, 5 and 8 min at room temperature. In-between each etching process cycle, the films were characterized by X-ray diffraction, atomic force microscopy, Raman Spectroscopy, 4-point probe (electrical conductivity), and variable angle spectroscopic ellipsometry. All the films were polycrystalline in nature and highly oriented along the (222) reflection. Ultra-thin ITO films with record low resistivity values (as low as 5.83 × 10−4 Ω·cm) were obtained and high optical transparency is exhibited in the 300–1000 nm wavelength region for all the ITO films. The etch rate, preferred crystal lattice growth plane, d-spacing and lattice distortion were also observed to be highly dependent on the nature of growth environment for RF sputter deposited ITO films. The structural, electrical, and optical properties of the ITO films are discussed with respect to the oxygen ambient nature and etching time in detail to provide guidance for plasmonic enhanced a-Si:H solar PV cell fabrication.

The release of the open source 3-D printer known as the RepRap (a self-Replicating Rapid prototyper) resulted in the potential for distributed manufacturing of products for significantly lower costs than conventional manufacturing. This development, coupled with open source-appropriate technology (OSAT), has enabled the opportunity for 3-D printers to be used for sustainable development. In this context, OSAT provides the opportunity to modify and improve the physical designs of their printers and desired digitally-shared objects. However, these 3-D printers require electricity while more than a billion people still lack electricity. To enable the utilization of RepRaps in off-grid communities, solar photovoltaic (PV)-powered mobile systems have been developed, but recent improvements in novel delta-style 3-D printer designs allows for reduced costs and improved performance. This study builds on these innovations to develop and experimentally validate a mobile solar-PV-powered delta 3-D printer system. It is designed to run the RepRap 3-D printer regardless of solar flux. The electrical system design is tested outdoors for operating conditions: (1) PV charging battery and running 3-D printer; (2) printing under low insolation; (3) battery powering the 3-D printer alone; (4) PV charging the battery only; and (5) battery fully charged with PV-powered 3-D printing. The results show the system performed as required under all conditions providing feasibility for adoption in off-grid rural communities. 3-D printers powered by affordable mobile PV solar systems have a great potential to reduce poverty through employment creation, as well as ensuring a constant supply of scarce products for isolated communities.

Assessing snow-related energy losses is necessary for accurate predictions of photovoltaic (PV) performance. A PV test platform with seven portrait-oriented modules placed at four tilt angles (0°, 15°, 30°, and 45°) was installed in Calumet, MI, USA, to measure the energy loss in this snowy climate. As a best-case snow-shedding configuration, similar to a carport or a plain sloped roof, three of the test modules were rack-mounted high enough to prevent surface interference. The opposite effect of maximum surface interference, similar to many commercial rooftops, was introduced by mounting the other four modules at grade. The platform was monitored for one year beginning in October 2013. The snowfall that winter was normal: 5.3 m (209 in). Snow-related annual energy losses ranged from 5% to 12% for the elevated unobstructed modules, with the steepest tilt angle experiencing the least amount of energy loss. For the obstructed modules, there was little angular dependence on lost energy, with annual energy losses ranging from 29% to 34%. This relative three- to sixfold increase in lost energy when ground interference is present points out the importance of minimizing obstructions and prompt snow clearing for portrait-oriented PV. Depending on the breadth of an inverter's operating voltage limits, these results suggest that landscape-oriented array layouts and perhaps snow-clearing mechanisms may be advantageous in snowy climates.

We study polarization independent improved light trapping in commercial thin film hydrogenated amorphous silicon (a-Si:H) solar photovoltaic cells using a three-dimensional silver array of multi-resonant nano-disk structures embedded in a silicon nitride anti-reflection coating to enhance optical absorption in the intrinsic layer (i-a-Si:H) for the visible spectrum for any polarization angle. Predicted total optical enhancement (OE) in absorption in the i-a-Si:H for AM-1.5 solar spectrum is 18.51% as compared to the reference, and producing a 19.65% improvement in short-circuit current density (JSC) over 11.7 mA/cm2 for a reference cell. The JSC in the nano-disk patterned solar cell (NDPSC) was found to be higher than the commercial reference structure for any incident angle. The NDPSC has a multi-resonant optical response for the visible spectrum and the associated mechanism for OE in i-a-Si:H layer is excitation of Fabry-Perot resonance facilitated by surface plasmon resonances. The detrimental Staebler-Wronski effect in a-Si:H solar cell can be minimized by the additional OE in the NDPSC and self-annealing of defect states by additional heat generation, thus likely improving the overall stabilized characteristics of a-Si:H solar cells.

Assessing snow-related energy losses is necessary for accurate predictions of photovoltaic (PV) performance. A PV test platform with seven portrait-oriented modules placed at four tilt angles (0°, 15°, 30°, and 45°) was installed in Calumet, MI, USA, to measure the energy loss in this snowy climate. As a best-case snow-shedding configuration, similar to a carport or a plain sloped roof, three of the test modules were rack-mounted high enough to prevent surface interference. The opposite effect of maximum surface interference, similar to many commercial rooftops, was introduced by mounting the other four modules at grade. The platform was monitored for one year beginning in October 2013. The snowfall that winter was normal: 5.3 m (209 in). Snow-related annual energy losses ranged from 5% to 12% for the elevated unobstructed modules, with the steepest tilt angle experiencing the least amount of energy loss. For the obstructed modules, there was little angular dependence on lost energy, with annual energy losses ranging from 29% to 34%. This relative three- to sixfold increase in lost energy when ground interference is present points out the importance of minimizing obstructions and prompt snow clearing for portrait-oriented PV. Depending on the breadth of an inverter's operating voltage limits, these results suggest that landscape-oriented array layouts and perhaps snow-clearing mechanisms may be advantageous in snowy climates.

ABSTRACT The unrestrained combustion of fossil fuels has resulted in vast pollution at the local scale throughout the world, while contributing to global warming at a rate that seriously threatens the stability of many of the world&amp;#39;s ecosystems. Solar photovoltaic (PV) technology is a clean, sustainable and renewable energy conversion technology that can help meet the energy demands of the world’s growing population. Although PV technology is mature with commercial modules obtaining over 20% conversion efficiency there remains considerable opportunities to improve performance. The nearly global access to the solar resource coupled to nanotechnology innovation-driven decreases in the costs of PV, provides a path for a renewable energy source to significantly reduce the adverse anthropogenic impacts of energy use by replacing fossil fuels. This study explores several approaches to improving indium gallium nitride-based PV efficiency with nanotechnology: optical enhancement, microstructural optimization for electronic material quality and increasing the spectral response via bandgap engineering. The results showing multibandgap engineering with InGaN and impediments to widespread deployment and commercialization are discussed including technical viability, intellectual property laws and licensing, material resource scarcities, and economics. Future work is outlined and conclusions are drawn to overcome these limitations and improve PV device performance using methods that can scale to the necessary terawatt level.