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Exothermic and
Endothermic
Reactions
Chemical Reactions
 All

chemical reactions involve bond breaking
and bond forming.
 Energy is needed to break bonds and
released when bonds are formed.
 Chemical reactions are accompanied by a
change in energy, mainly in the form of heat.
Exothermic and Endothermic
Reactions
 A reaction

in which heat is given out is
exothermic.

 A reaction

in which heat is taken in is
endothermic.
Combustion of Hydrocarbons
 When

hydrocarbons are burned carbon
dioxide, water vapour and large amounts of
heat are produced.
 Hydrocarbons (particularly alkanes) are
excellent fuels e.g. methane, propane,
butane and petrol.

Recommended for you

Classifications of Matter
Classifications of MatterClassifications of Matter
Classifications of Matter

This document defines the classification of matter. There are two main categories: pure substances and mixtures. Pure substances include elements, which are made of only one type of atom, and compounds, which are two or more elements chemically bonded together. Mixtures contain two or more pure substances mixed together without chemical bonding. Mixtures can be either heterogeneous, where the parts can be seen, or homogeneous, where the parts cannot be seen. Heterogeneous mixtures are less pure than homogeneous mixtures.

matterchemistryscience and technology
Chemical Reactions
Chemical ReactionsChemical Reactions
Chemical Reactions

A chemical reaction involves the transformation of reactants into different products through rearrangement of atoms. Chemical reactions conserve mass as atoms are not destroyed or created, but instead are reorganized into new substances. Balancing chemical equations ensures the same number and type of atoms are on both sides of the reaction.

Displacement reaction
Displacement reactionDisplacement reaction
Displacement reaction

1) Displacement reactions can be classified as metal-metal displacement reactions or metal-nonmetal displacement reactions. 2) In metal-metal displacement reactions, more reactive metals displace less reactive metals according to the reactivity series. For example, copper displaces iron when an iron bar is placed in copper sulfate solution. 3) In metal-nonmetal displacement reactions, metals can displace hydrogen from water, with more reactive metals like sodium displacing hydrogen even at room temperature, while less reactive metals like iron only displacing hydrogen when heated.

metal-metal displacementmetal-nonmetal displacement reaction
Heat of Reaction
 The

heat of reaction, ΔH, of a chemical
reaction is the heat in kilojoules released or
absorbed when the number of moles of
reactants indicated, in the balanced equation
describing the reaction, react completely.
 For an exothermic reaction ΔH is negative(-)
 For an endothermic reaction ΔH is positive(+)
Bond Energy
 Bond

energy is the amount of energy in
kilojoules needed to break one mole of
bonds of the same type, all species being in
the gaseous state.
 The average C-H bond energy in methane is
412kj mol-1 i.e. E(C-H) = 412kj mol-1 .
 The energy of a particular bond type can
vary.
 It is usual to quote the average bond
Heat of Combustion
 The

heat of combustion of a substance is the
heat change in kilojoules when one mole of
the substance is completely burned in
excess oxygen.
Bomb Calorimeter
 Used

to find accurate values for heats of
combustion.
 Sample is ignited using an electrically heated
wire.
 Excess oxygen ensures complete
combustion of the sample.
 Heat produced by the rapid and complete
combustion of the sample heats the water
and the temperature is recorded.

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Chemical reactions
Chemical reactionsChemical reactions
Chemical reactions

This document provides an overview of chemical reactions and energetics for a 10th grade IGCSE course. It discusses exothermic and endothermic reactions in relation to energy changes and temperature. It also covers the factors that affect reaction rates, including concentration, particle size, catalysis, and temperature. The document defines oxidation and reduction in terms of electron transfer and identifies redox reactions. It provides examples of exothermic and endothermic reactions and discusses how catalysts can lower the activation energy and increase reaction rates. Interactive links are included to illustrate and reinforce the concepts.

sciencesigcsechemistry
Moles and molar mass
Moles and molar massMoles and molar mass
Moles and molar mass

A mole is the standard unit used to measure very large quantities of small particles like atoms and molecules. It represents 6.02 x 1023 particles, which is an immense number that is difficult to comprehend. The molar mass of an element or compound is the mass in grams of one mole of that substance. To find molar mass, one does an atom inventory of the substance and multiplies the number of each type of atom by its atomic mass on the periodic table, then sums the results.

chemistry
types of chemical reaction
types of chemical reactiontypes of chemical reaction
types of chemical reaction

The document outlines 5 main types of chemical reactions: synthesis, decomposition, single replacement, double replacement, and combustion. It provides examples of each type of reaction and describes their key characteristics. Synthesis reactions combine two or more reactants to form one product. Decomposition reactions involve a single reactant breaking down into multiple products. Single replacement reactions involve one element replacing another in a compound. Double replacement reactions involve two compounds swapping parts to form two new compounds. Combustion reactions involve organic compounds burning in oxygen to produce carbon dioxide and water.

Bomb Calorimeter

SCC Science Dept
Bomb Calorimeter
 The

apparatus is well insulated to prevent
heat loss.
 The amount of heat used to start burning can
be calculated and removed.
Heat of Combustion of Different
Fuels
 Methane

(natural gas)
 Propane (LPG)
 Hydrogen
 Petrol (octane)

-890 kj mol-1
-2219 kj mol-1
-286 kj mol-1
-5470 kj mol-1
Heat of Formation
 The

heat of formation is the heat change in
kilojoules, when one mole of a substance is
formed from its elements in their standard
state.

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Balancing Chemical Equations
Balancing Chemical EquationsBalancing Chemical Equations
Balancing Chemical Equations

1) A chemical equation is a symbolic representation of a chemical reaction using element symbols and formulas to show reactants and products. 2) Chemical equations must be balanced so that the same number of each type of atom is on both sides of the reaction arrow. 3) To balance equations, coefficients are placed in front of formulas to adjust the relative numbers of elements and compounds until both sides have equal quantities.

Types of Chemical Reactions
Types of Chemical ReactionsTypes of Chemical Reactions
Types of Chemical Reactions

The document describes the main types of chemical reactions: synthesis reactions where two or more reactants form one product, decomposition reactions where one reactant breaks down into multiple products, replacement reactions including single replacement where one element replaces another in a compound and double replacement where ions switch between compounds, and combustion reactions where a substance reacts with oxygen releasing energy.

Chapter 1 Rate of Reactions
Chapter 1 Rate of Reactions Chapter 1 Rate of Reactions
Chapter 1 Rate of Reactions

The document discusses rate of reaction and factors that affect it. It defines rate of reaction as the change in amount of reactants or products per unit time. It describes several factors that affect rate based on collision theory, including surface area, concentration, temperature, catalysts, and pressure. It gives examples of how scientific understanding of rate of reaction enhances quality of life, such as refrigeration, pressure cooking, cutting food into smaller pieces, making margarine, and burning coal.

Law of Conservation of Energy
 The

law of conservation of energy states that
energy cannot be created or destroyed, but
only changed from one form to another.
Hess’s Law
 Hess’s

Law states that the heat change of a
reaction depends only on the initial and final
states of the reaction and is independent of
the route by which the reaction may occur.
 for a reaction described by a given equation,
the heat of reaction equals the sum of the
heats of formation of the products of the
reaction less the sum of the heats of
formation of the reactants of the reaction.
 ΔH = ΔH (products) - ΔH (reactants)

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5.4 exothermic and endothermic reactions

  • 2. Chemical Reactions  All chemical reactions involve bond breaking and bond forming.  Energy is needed to break bonds and released when bonds are formed.  Chemical reactions are accompanied by a change in energy, mainly in the form of heat.
  • 3. Exothermic and Endothermic Reactions  A reaction in which heat is given out is exothermic.  A reaction in which heat is taken in is endothermic.
  • 4. Combustion of Hydrocarbons  When hydrocarbons are burned carbon dioxide, water vapour and large amounts of heat are produced.  Hydrocarbons (particularly alkanes) are excellent fuels e.g. methane, propane, butane and petrol.
  • 5. Heat of Reaction  The heat of reaction, ΔH, of a chemical reaction is the heat in kilojoules released or absorbed when the number of moles of reactants indicated, in the balanced equation describing the reaction, react completely.  For an exothermic reaction ΔH is negative(-)  For an endothermic reaction ΔH is positive(+)
  • 6. Bond Energy  Bond energy is the amount of energy in kilojoules needed to break one mole of bonds of the same type, all species being in the gaseous state.  The average C-H bond energy in methane is 412kj mol-1 i.e. E(C-H) = 412kj mol-1 .  The energy of a particular bond type can vary.  It is usual to quote the average bond
  • 7. Heat of Combustion  The heat of combustion of a substance is the heat change in kilojoules when one mole of the substance is completely burned in excess oxygen.
  • 8. Bomb Calorimeter  Used to find accurate values for heats of combustion.  Sample is ignited using an electrically heated wire.  Excess oxygen ensures complete combustion of the sample.  Heat produced by the rapid and complete combustion of the sample heats the water and the temperature is recorded.
  • 10. Bomb Calorimeter  The apparatus is well insulated to prevent heat loss.  The amount of heat used to start burning can be calculated and removed.
  • 11. Heat of Combustion of Different Fuels  Methane (natural gas)  Propane (LPG)  Hydrogen  Petrol (octane) -890 kj mol-1 -2219 kj mol-1 -286 kj mol-1 -5470 kj mol-1
  • 12. Heat of Formation  The heat of formation is the heat change in kilojoules, when one mole of a substance is formed from its elements in their standard state.
  • 13. Law of Conservation of Energy  The law of conservation of energy states that energy cannot be created or destroyed, but only changed from one form to another.
  • 14. Hess’s Law  Hess’s Law states that the heat change of a reaction depends only on the initial and final states of the reaction and is independent of the route by which the reaction may occur.  for a reaction described by a given equation, the heat of reaction equals the sum of the heats of formation of the products of the reaction less the sum of the heats of formation of the reactants of the reaction.  ΔH = ΔH (products) - ΔH (reactants)